Abstract: Process for the preparation of polysulfide of formula (I) HS—(CH2)n—O—(CH2)m—O—(CH2)p—[S—S—CH2)nO—(CH2)m—O—(CH2)p]q—SH (I) wherein m is an integer in the range 1 to 4, n and p are integers in the range 1-10, and q is an integer in the range 1-60, by oxidizing a bismercaptodiether compound of formula (II) HS—(CH2)n—O—(CH2)m—O—(CH2)p—SH (II) with elemental sulfur in the presence of a base and a protic solvent. This process has a high selectivity towards linear disulfides.
Type:
Grant
Filed:
April 10, 2012
Date of Patent:
July 14, 2015
Assignees:
SHANGHAI ICI RESEARCH & DEVELOPMENT & MANAGEMENT CO. LTD., AKZO NOBEL CHEMICALS INTERNATIONAL B.V.