Patents Assigned to Shanghai Institute of Ceramics, Chinese Academy of Sciences
  • Patent number: 12230766
    Abstract: A lithium-metal battery, includes: a substrate; a cathode disposed on the substrate; a garnet solid-state electrolyte disposed on the cathode; and a lithium anode disposed on the garnet solid-state electrolyte, such that a modification layer is disposed at an interface of the lithium anode and garnet solid-state electrolyte, the modification layer includes: a first portion; and a second portion, such that the first portion has a lithium component and the second portion has a garnet component. A method of forming a lithium-metal battery, includes: stacking a garnet source with at least one lithium source; and heating the stack at a temperature of at least 300° C. for a time in a range of 1 sec to 20 min to form a modification layer, such that the modification layer is disposed at an interface of the garnet source and the lithium source.
    Type: Grant
    Filed: February 15, 2023
    Date of Patent: February 18, 2025
    Assignees: CORNING INCORPORATED, Shanghai Institute of Ceramics Chinese Academy Sciences
    Inventors: Michael Edward Badding, Jun Jin, Zhen Song, Jianmeng Su, Zhaoyin Wen, Tongping Xiu
  • Patent number: 12074282
    Abstract: A composite ceramic including: a lithium garnet major phase; and a grain growth inhibitor minor phase, as defined herein. Also disclosed is a method of making composite ceramic, pellets and tapes thereof, a solid electrolyte, and an electrochemical device including the solid electrolyte, as defined herein.
    Type: Grant
    Filed: July 25, 2023
    Date of Patent: August 27, 2024
    Assignees: CORNING INCORPORATED, Shanghai Institute of Ceramic Chinese Academy of Sciences
    Inventors: Michael Edward Badding, Yinghong Chen, Xiao Huang, Cai Liu, Xinyuan Liu, Yanxia Ann Lu, Zhen Song, Zhaoyin Wen, Tongping Xiu, Nathan Michael Zink
  • Patent number: 12037248
    Abstract: Disclosed herein are methods for forming a graphene film on a substrate, the methods comprising depositing graphene on a surface of the substrate by a first vapor deposition step to form a discontinuous graphene crystal layer; depositing a graphene oxide layer on the discontinuous graphene crystal layer to form a composite layer; and depositing graphene on the composite layer by a second vapor deposition step, wherein the graphene oxide layer is substantially reduced to a graphene layer during the second vapor deposition step. Transparent coated substrates comprising such graphene films are also disclosed herein, wherein the graphene films have a resistance of less than about 10 K?/sq.
    Type: Grant
    Filed: June 20, 2023
    Date of Patent: July 16, 2024
    Assignees: Corning Incorporated, Shanghai Institute of Ceramics, Chinese Academy of Sciences
    Inventors: Hui Bi, Fuqiang Huang, Xinyuan Liu, Zhen Song, Yufeng Tang, Tongping Xiu
  • Patent number: 12034152
    Abstract: A cathode for a lithium-sulfur battery includes a sulfur-based composite layer having a porosity in a range of 60% to 99%; and a conductive polymer disposed atop the composite layer and within pores of the composite layer. Moreover, a method of forming a cathode for a lithium-sulfur battery includes providing a substrate; disposing a sulfur-based slurry layer on the substrate; freeze-drying the slurry layer to form a sulfur-based composite layer having a porosity in a range of 60% to 99%; and disposing a conductive polymer atop the composite layer and within pores of the composite layer.
    Type: Grant
    Filed: June 20, 2019
    Date of Patent: July 9, 2024
    Assignees: CORNING INCORPORATED, Shanghai Institute of Ceramics, Chinese Academy of Sciences
    Inventors: Michael Edward Badding, Jun Jin, Yang Lu, Zhen Song, Zhaoyin Wen, Tongping Xiu
  • Patent number: 11963447
    Abstract: The present invention relates to a method for preparing a thermoelectric thick film. The method includes: determining a brittle-to-ductile transition temperature of a thermoelectric material; rolling the blocky thermoelectric material within a temperature range above the brittle-to-ductile transition temperature and below a melting point; parameters of the rolling being as follows: a linear speed of rollers is 0.01 mm/s to 10 mm/s, preferably 0.1 mm/s to 5 mm/s, and an amount of pressing each time of the rollers is controlled at 0.0005 mm to 0.1 mm, preferably 0.001 mm to 0.05 mm; repeating the rolling until a thermoelectric thick film with a specified thickness is obtained; and annealing the obtained thermoelectric thick film; a temperature of the annealing being 100° C. to 800° C., preferably 300° C. to 500° C., and a duration of the annealing being 10 to 500 hours, preferably 100 to 300 hours.
    Type: Grant
    Filed: May 6, 2020
    Date of Patent: April 16, 2024
    Assignee: SHANGHAI INSTITUTE OF CERAMICS, CHINESE ACADEMY OF SCIENCES
    Inventors: Xun Shi, Pengfei Qiu, Zhiqiang Gao, Lidong Chen, Shiqi Yang, Qingyu Yang
  • Publication number: 20240116821
    Abstract: A preparation method of a high-thermal-conductivity and net-size silicon nitride ceramic substrate includes the following steps: (1) mixing an original powder, a sintering aid, a dispersant, a defoamer, a binder, and a plasticizer in a protective atmosphere to allow vacuum degassing to obtain a mixed slurry; (2) subjecting the mixed slurry to tape casting and drying in a nitrogen atmosphere to obtain a first green body; (3) subjecting the first green body to shaping pretreatment to obtain a second green body; (4) subjecting the second green body to debonding at 500° C. to 900° C. to obtain a third green body; and (5) subjecting the third green body to gas pressure sintering in a nitrogen atmosphere at 1,800° C. to 2,000° C. to obtain the high-thermal-conductivity and net-size silicon nitride ceramic substrate.
    Type: Application
    Filed: January 17, 2022
    Publication date: April 11, 2024
    Applicant: SHANGHAI INSTITUTE OF CERAMICS, CHINESE ACADEMY OF SCIENCES
    Inventors: Hui ZHANG, Xuejian LIU, Jindi JIANG, Xiumin YAO, Zhengren HUANG, Zhongming CHEN
  • Patent number: 11858854
    Abstract: A sintered composite ceramic includes: a lithium-garnet major phase; and a lithium-rich minor phase, such that the lithium-rich minor phase has LixTiO(x+4)/2, with 0.66?x?4. The sintered composite ceramic may exhibit a relative density of at least 90% of a theoretical maximum density of the ceramic, an ionic conductivity of at least 0.35 mS·cm?1, or a critical current density (CCD) of at least 1.0 mA·cm?2.
    Type: Grant
    Filed: May 5, 2021
    Date of Patent: January 2, 2024
    Assignees: CORNING INCORPORATED, Shanghai Institute of Ceramics Chinese Academy of Sciences
    Inventors: Michael Edward Badding, Jun Jin, Zhen Song, Jianmeng Su, Zhaoyin Wen, Tongping Xiu, Chujun Zheng
  • Patent number: 11777139
    Abstract: A modified garnet-type solid electrolyte, includes: a garnet-type solid electrolyte; a modification layer, such that the modification layer is formed on at least one side of the garnet-type solid electrolyte, and possesses a three-dimensional crosslinking structure comprising at least one strongly acidic lithium salt and at least one weakly acidic lithium salt. A method of forming a modified garnet-type solid electrolyte, includes: exposing a garnet-type solid electrolyte in air to form a pre-passivation layer; mixing solutions of strong acid and weakly acidic salt to form a mixed solution; chemically treating at least one side of the garnet-type solid electrolyte with the mixed solution; and forming a modification layer on the at least one side of the garnet-type solid electrolyte.
    Type: Grant
    Filed: November 23, 2020
    Date of Patent: October 3, 2023
    Assignees: CORNING INCORPORATED, Shanghai Institute of Ceramics Chinese Academy of Sciences
    Inventors: Jun Jin, Yadong Ruan, Zhaoyin Wen
  • Patent number: 11777145
    Abstract: A battery includes a substrate; a composite cathode disposed on the substrate; a solid-state electrolyte disposed on the composite cathode; and a lithium anode disposed on the solid-state electrolyte, such that the composite cathode comprises a gel polymer electrolyte layer and a porous cathode active material layer. A method of forming a cathode for a solid-state battery includes mixing an active cathode material, at least one of a conductive carbon component and an electronic conductive component, and a polymer binder to form a slurry; immersing the slurry in an alcohol reagent to form a porous disc structure by phase conversion; and immersing the porous disc structure in a liquid electrolyte to form the cathode.
    Type: Grant
    Filed: June 24, 2021
    Date of Patent: October 3, 2023
    Assignees: CORNING INCORPORATED, Shanghai Institute of Ceramics Chinese Academy of Sciences
    Inventors: Michael Edward Badding, Mingli Cai, Jun Jin, Zhen Song, Zhaoyin Wen, Tongping Xiu, Liu Yao
  • Patent number: 11749836
    Abstract: A composite ceramic including: a lithium garnet major phase; and a grain growth inhibitor minor phase, as defined herein. Also disclosed is a method of making composite ceramic, pellets and tapes thereof, a solid electrolyte, and an electrochemical device including the solid electrolyte, as defined herein.
    Type: Grant
    Filed: February 28, 2022
    Date of Patent: September 5, 2023
    Assignees: CORNING INCORPORATED, Shanghai Institute of Ceramics, Chinese Academy of Sciences
    Inventors: Michael Edward Badding, Yinghong Chen, Xiao Huang, Cai Liu, Xinyuan Liu, Yanxia Ann Lu, Zhen Song, Zhaoyin Wen, Tongping Xiu, Nathan Michael Zink
  • Patent number: 11708271
    Abstract: Disclosed herein are methods for forming a graphene film on a substrate, the methods comprising depositing graphene on a surface of the substrate by a first vapor deposition step to form a discontinuous graphene crystal layer; depositing a graphene oxide layer on the discontinuous graphene crystal layer to form a composite layer; and depositing graphene on the composite layer by a second vapor deposition step, wherein the graphene oxide layer is substantially reduced to a graphene layer during the second vapor deposition step. Transparent coated substrates comprising such graphene films are also disclosed herein, wherein the graphene films have a resistance of less than about 10 K?/sq.
    Type: Grant
    Filed: December 9, 2016
    Date of Patent: July 25, 2023
    Assignees: Corning Incorporated, Shanghai Institute of Ceramics, Chinese Academy of Sciences
    Inventors: Hui Bi, Fuqiang Huang, Xinyuan Liu, Zhen Song, Yufeng Tang, Tongping Xiu
  • Patent number: 11572317
    Abstract: The present application discloses a dense lead metaniobate piezoelectric ceramic and a preparation method therefor. The chemical composition of the lead metaniobate piezoelectric ceramic is Pb1-xNb2O6, wherein x represents the Pb vacancy concentration of A sites in a tungsten bronze crystal structure, and x is greater than 0.00 and smaller than or equal to 0.20.
    Type: Grant
    Filed: December 4, 2020
    Date of Patent: February 7, 2023
    Assignee: SHANGHAI INSTITUTE OF CERAMICS, CHINESE ACADEMY OF SCIENCES
    Inventors: Zhiyong Zhou, Yuchen Li, Xianlin Dong
  • Patent number: 11567223
    Abstract: The invention relates to a scintillation material of rare earth orthosilicate doped with a strong electron-affinitive element and its preparation method and application thereof. The chemical formula of the scintillation material of rare earth orthosilicate doped with the strong electron-affinitive element is: RE2(1?x?y+?/2)Ce2xM(2y??)Si(1??)M?O5. In the formula, RE is rare earth ions and M is strong electron-affinitive doping elements; the value of x is 0<x?0.05, the value of y is 0<y?0.015, and the value of ? is 0???10?4; and M is selected from at least one of tungsten, lead, molybdenum, tellurium, antimony, bismuth, mercury, silver, nickel, indium, thallium, niobium, titanium, tantalum, tin, cadmium, technetium, zirconium, rhenium, and gallium Ga.
    Type: Grant
    Filed: November 12, 2021
    Date of Patent: January 31, 2023
    Assignee: SHANGHAI INSTITUTE OF CERAMICS, CHINESE ACADEMY OF SCIENCES
    Inventors: Dongzhou Ding, Shuwen Zhao, Fan Yang, Junjie Shi, Chen Yuan, Linwei Wang, Zhongjun Xue
  • Patent number: 11299427
    Abstract: The present application relates to a magnesium oxide based dielectric ceramics with ultrahigh dielectric breakdown strength and a preparation method thereof. The composition of the magnesium oxide based dielectric ceramic material comprises: (1?x)MgO—xAl2O3, wherein 0<x?0.12 and x is a mole percentage. The material has a specific composite structure with magnesium aluminate spinel acting as a second phase surrounding a principal crystalline phase, MgO.
    Type: Grant
    Filed: March 18, 2020
    Date of Patent: April 12, 2022
    Assignee: SHANGHAI INSTITUTE OF CERAMICS, CHINESE ACADEMY OF SCIENCES
    Inventors: Xianlin Dong, Chi Zhang, Ying Chen
  • Patent number: 11292747
    Abstract: The present application relates to a barium strontium titanate-based dielectric ceramic material, a preparation method, and application thereof. The composition of the barium strontium titanate-based dielectric ceramic material comprises: aBaTiO3+bSrTiO3+cTiO2+dBi2O3+eMgO+fAl2O3+gCaO+hSiO2, wherein a, b, c, d, e, f, g, and h are the molar percentage of each component, 20?a?50 mol %, 15?b?30 mol %, 10?c?20 mol %, 0?d?10 mol %, 0?e?35 mol %, 0?f?6 mol %, 0?g?6 mol %, 0?h?1 mol %, and a+b+c+d+e+f+g+h=100 mol %.
    Type: Grant
    Filed: March 26, 2020
    Date of Patent: April 5, 2022
    Assignee: SHANGHAI INSTITUTE OF CERAMICS, CHINESE ACADEMY OF SCIENCES
    Inventors: Ying Chen, Xianlin Dong, Xin Li, Feng Jiang, Yongjian Wang
  • Patent number: 11296355
    Abstract: A composite ceramic including: a lithium garnet major phase; and a grain growth inhibitor minor phase, as defined herein. Also disclosed is a method of making composite ceramic, pellets and tapes thereof, a solid electrolyte, and an electrochemical device including the solid electrolyte, as defined herein.
    Type: Grant
    Filed: April 13, 2018
    Date of Patent: April 5, 2022
    Assignees: Corning Incorporated, Shanghai Institute of Ceramics, Chinese Academy of Sciences
    Inventors: Michael Edward Badding, Yinghong Chen, Xiao Huang, Cai Liu, Xinyuan Liu, Yanxia Ann Lu, Zhen Song, Zhaoyin Wen, Tongping Xiu, Nathan Michael Zink
  • Patent number: 11142689
    Abstract: Disclosed are a yttrium-doped barium fluoride crystal and a preparation method and the use thereof, wherein the yttrium-doped barium fluoride crystal has a chemical composition of Ba(1?x)YxF2+x, in which 0.01?x?0.50. The yttrium-doped BaF2 crystal of the present invention has improved scintillation performance. The yttrium doping may greatly suppress the slow luminescence component of the BaF2 crystal and has an excellent fast/slow scintillation component ratio. The doped crystal is coupled to an optical detector to obtain a scintillation probe which is applicable to the fields of high time resolved measurement radiation such as high-energy physics, nuclear physics, ultrafast imaging and nuclear medicine imaging.
    Type: Grant
    Filed: April 13, 2018
    Date of Patent: October 12, 2021
    Assignees: SHANGHAI INSTITUTE OF CERAMICS, CHINESE ACADEMY OF SCIENCES, R&D CENTER, SHANGHAI INSTITUTE OF CERAMICS
    Inventors: Junfeng Chen, Yong Du, Shaohua Wang, Shiyun Sun, Xuenong Zhou, Xiang Li
  • Patent number: 11136692
    Abstract: Disclosed is a plastic semiconductor material and a preparation method thereof. The semiconductor material comprises an argentite-based compound represented by the following formula (I): Ag2-?X?S1-?Y?(I), in which 0??<0.5, 0??<0.5, X is at least one of Cu, Au, Fe, Co, Ni, Zn, Ti, or V, and Y is at least one of N, P, As, Sb, Se, Te, O, Br, Cl, I, or F. The material can withstand certain deformations, similar to organic materials, and has excellent semiconductor properties with adjustable electrical properties, thereby enabling the preparation of high-performance flexible semiconductor devices.
    Type: Grant
    Filed: February 12, 2018
    Date of Patent: October 5, 2021
    Assignee: SHANGHAI INSTITUTE OF CERAMICS, CHINESE ACADEMY OF SCIENCES
    Inventors: Xun Shi, Ruiheng Liu, Feng Hao, Tuo Wang
  • Patent number: 10934408
    Abstract: The present invention relates to a surface modification method for a polyether-ether-ketone material. The method combines physical and chemical methods, and comprises the steps of performing plasma immersion ion implantation on the surface of the polyether-ether-ketone material with argon as an ion source, and then, soaking the polyether-ether-ketone material treated by plasma immersion ion implantation in a hydrogen peroxide aqueous solution, hydrofluoric acid aqueous solution, or ammonia water to make the surface of the modified polyether-ether-ketone material have nanoparticles, shallow nanoporous structures, and/or ravined nanostructures.
    Type: Grant
    Filed: March 18, 2015
    Date of Patent: March 2, 2021
    Assignee: SHANGHAI INSTITUTE OF CERAMICS, CHINESE ACADEMY OF SCIENCES
    Inventors: Xuanyong Liu, Tao Lu, Heying Wang, Fanhao Meng
  • Patent number: 10759704
    Abstract: The present application relates to a large-size, high-dielectric breakdown strength titanium oxide based dielectric ceramic material, a preparation method and application thereof. The composition of the titanium oxide based dielectric ceramic material comprises: a CaTiO3+b SrTiO3+c TiO2+d Al2TiO5+e SiO2, wherein a, b, c, d, and e are the mole percentage of each component, 15?a?35 mol %, 0?b?2 mol %, 30?c?84 mol %, 0.5?d?25 mol %, 0.5?e?15 mol %, and a+b+c+d+e=100 mol %.
    Type: Grant
    Filed: December 18, 2018
    Date of Patent: September 1, 2020
    Assignee: SHANGHAI INSTITUTE OF CERAMICS, CHINESE ACADEMY OF SCIENCES
    Inventors: Ying Chen, Xianlin Dong, Wenbin Zhang, Xin Li, Feng Jiang, Ye Huang