Abstract: The present invention provides a biodegradable master batch and a preparation method thereof. The biodegradable master batch is prepared by in-situ polymerization of the components in the following formula in weight parts: 10-80 parts of biodegradable monomer or prepolymer, 0.01-5 parts of catalyst, 0.05-5 parts of reaction activator, 0.1-5 parts of thermal stabilizer, 0-80 parts of flame retardant, 0-80 parts of filler, 0-80 parts of antistatic agent, 0-80 parts of pigment, 0-80 parts of foaming agent, and 0-5 parts of surface coupling agent. Provided in the present invention are the biodegradable polymer master batch having good dispersion effect and excellent interface bonding property, and the preparation method thereof.

Abstract: A thermoplastic starch (TPS) comprises (in weight parts) 20-80 parts of starch, 5-40 parts of biodegradable polyester prepolymer, 0.01-10 parts of reaction activator, 0.01-1.0 part of catalytic deactivator, 0.01-1.0 part of antioxidant, and 5-50 parts of auxiliary agents. The said prepolymer has a molecular weight of 10,000-100,000 Daltons, a viscosity range of 0.30-1.2 dL/g, which is measured by Ubbelohde viscometer method, and a melting point range of 60-180° C. The terminal reactive group content of the prepolymer is 1.0-20.0 meq/Kg, which is measured by a terminal group titration process. A polyester/starch composite material comprising the TPS and its preparation method are also provided.