Abstract: The invention discloses multilayer allochroic pigments having angle dependence of the interference colors and the production processes thereof, in which a synthetic flake of silicate is used as the substrate, and a metal oxide coating with refractive index of more than 1.8 and an oxide coating with refractive index of less than 1.8 are deposited alternately on a surface of the flake of silicate, the number of the coatings is at least three, and said oxide coating with refractive index of less than 1.8 always lies between two metal oxide coatings with refractive index of more than 1.8. The processes involve a wet chemical hydrolysis step to alternately deposit said oxide coating with high refractive index and said oxide coating with high refractive index on the surface of the flake of silicate. The present pigments, which exhibit different strong interference colors as observed at different view angles, could be produced at a low cost and by a simple process.