Abstract: An experimental method for coal desulfurization and deashing using permeation and solvating power of a supercritical fluid includes the following steps. The coal sample is ground and loaded into an extraction kettle with a cover. An inlet valve and an outlet valve of the extraction kettle are opened to circulate the supercritical CO2 fluid in the extraction kettle. The extraction kettle is sealed. By adjusting a temperature and a pressure in the extraction kettle, the supercritical CO2 fluid is kept at its critical point and permeates the coal sample to dissolve organic sulfur, inorganic sulfur and ash in the coal sample. The extraction kettle is depressurized, and the temperature in the extraction kettle is adjusted to gasify the supercritical CO2 fluid. The organic sulfur, the inorganic sulfur and part of the ash are separated from the supercritical CO2 fluid and precipitated at a bottom of the extraction kettle.