Patents Assigned to Shoei Chemicals Inc.
  • Patent number: 11066332
    Abstract: According to the present invention, a dielectric ceramic composition, which can be fired in a reducing atmosphere, has a high dielectric constant, has an electrostatic capacity exhibiting little change, when used as a dielectric layer of a ceramic electronic component such as a laminated ceramic capacitor even under a condition of 150 to 200° C., and has small dielectric losses at 25° C. and 200° C., can be provided.
    Type: Grant
    Filed: October 11, 2017
    Date of Patent: July 20, 2021
    Assignee: SHOEI CHEMICAL INC.
    Inventors: Takeshi Nomura, Atsushi Nemoto, Yukari Sasaki, Kazuhiko Takemoto, Naomi Kinoshita, Yumi Takahashi
  • Patent number: 10804003
    Abstract: Provided is a conductive paste for forming a solar cell electrode containing a glass frit component (A) as glass frit (II), the glass frit component (A) containing the following in the content ratio to the total molar number in terms of oxide: (a) 30 to 70 mol % of tellurium element, (b) 18 to 30 mol % of tungsten element, (c) 5 to 30 mol % of zinc element, (d) 1 to 15 mol % of boron element, (e) 0.3 to 5 mol % of aluminum element, (f) 0.3 to 7 mol % of one or more selected from rare earth elements in terms of oxide, and (g) 0.1 to 7 mol % of one or more selected from the group consisting of tin, lithium, and barium elements in terms of oxide. The conductive paste may have better electric characteristics and a small variation in the characteristics even at a relatively low firing temperature (for example, 760° C.).
    Type: Grant
    Filed: September 26, 2018
    Date of Patent: October 13, 2020
    Assignee: SHOEI CHEMICAL INC.
    Inventors: Masayuki Kurahashi, Naoto Shindo, Kosuke Nishimura
  • Patent number: 10745822
    Abstract: A method for producing metal oxide nanocrystals, according to the embodiment of the present invention, includes: continuously flowing, into a continuous flow path, one or a plurality of nanocrystal precursor solutions each comprising one or more nanocrystal precursors dissolved in a non-polar solvent; directing a segmenting gas into the continuous flow path to create a segmented reaction flow; flowing the segmented reaction flow into a thermal processor; heating the segmented reaction flow in the thermal processor to create a product flow; and collecting metal oxide nanocrystals from the product flow.
    Type: Grant
    Filed: July 22, 2016
    Date of Patent: August 18, 2020
    Assignee: SHOEI CHEMICAL INC.
    Inventors: Thomas E. Novet, Yukihisa Okawa, Masahito Igari, David M. Schut
  • Patent number: 10640882
    Abstract: A method for producing a metal oxide nanocrystals according to the embodiment of the present invention comprises continuously flowing a nanocrystal precursor solution comprising a nanocrystal precursor into a continuous flow path and heating the nanocrystal precursor solution in the continuous flow path to create nanocrystals, comprising: providing a nanocrystal precursor solution supply unit that is connected to the continuous flow path and comprises a first vessel and a second vessel; delivering a nanocrystal precursor solution in the second vessel to the continuous low path; and creating a nanocrystal precursor solution in the first vessel as a different batch from the nanocrystal precursor solution in the second vessel.
    Type: Grant
    Filed: July 22, 2016
    Date of Patent: May 5, 2020
    Assignee: SHOEI CHEMICAL INC.
    Inventors: Thomas E. Novet, Yukihisa Okawa, Masahito Igari, David M. Schut
  • Patent number: 10636541
    Abstract: A conductive paste including a conductive powder, a glass frit, and an organic vehicle, wherein the conductive powder includes copper and/or nickel as a main component(s), and the glass frit is substantially free of Pb, Cd, and Bi, comprises 40 to 65% by mass of BaO, 15 to 23% by mass of B2O3, 2 to 12% by mass of Al2O3, 4 to 8% by mass of SiO2, 0 to 5% by mass of ZnO, 0.5 to 7% by mass of TiO2, 3 to 7.5% by mass of CaO, and comprises any one or more of MnO2, CuO, and CoO in the ranges of 0 to 7% by mass of MnO2, 0 to 16% by mass of CuO, and 0 to 5% by mass of CoO, in terms of oxide.
    Type: Grant
    Filed: September 26, 2016
    Date of Patent: April 28, 2020
    Assignee: SHOEI CHEMICAL INC.
    Inventors: Kousuke Nishimura, Naoto Shindo, Nobuo Nishioka
  • Patent number: 10569333
    Abstract: A carbon-coated metal powder having few impurities, a narrower particle size distribution, and sintering properties is particularly suitable as a conductive powder of a conductive paste for forming internal conductors in a ceramic multilayer electronic component obtained by co-firing multilayered ceramic sheets and internal conductor layers; a conductive paste containing the carbon-coated metal powder; a multilayer electronic component using the conductive paste; and a method for manufacturing the carbon-coated metal powder. The carbon-coated metal powder has specific properties in TMA or ESCA measurements. The carbon-coated metal powder can be obtained by melting and vaporizing a metallic raw material in a reaction vessel, conveying the generated metal vapor into a cooling tube and rapidly cooling the metal vapor by endothermically decomposing a carbon source supplied into the cooling tube, and forming a carbon coating film on metal nuclei surfaces in parallel with generation of the metal nuclei.
    Type: Grant
    Filed: February 26, 2018
    Date of Patent: February 25, 2020
    Assignee: SHOEI CHEMICAL INC.
    Inventors: Yuji Akimoto, Hideki Tanaka, Mineto Iwasaki, Akiko Matsuo
  • Patent number: 10446290
    Abstract: A resistive composition that can form a thick film resistor excluding a toxic lead component from a conductive component and glass and having characteristics equivalent to or superior to conventional resistors in terms of, in a wide resistance range, resistance values, TCR characteristics, current noise characteristics, withstand voltage characteristics and the like. The resistive composition of the present invention includes: ruthenium-based conductive particles including ruthenium dioxide; a glass frit that is essentially free of a lead component; and an organic vehicle, wherein the glass frit is a glass frit which is constituted such that in a case where a fired product of a mixture of the glass frit and the ruthenium dioxide has in a range of 1 k?/? to 1 M?/?, the fired product exhibits a temperature coefficient of resistance in a plus range.
    Type: Grant
    Filed: September 28, 2017
    Date of Patent: October 15, 2019
    Assignee: SHOEI CHEMICAL INC.
    Inventors: Hiroshi Mashima, Yukari Morofuji
  • Patent number: 10403421
    Abstract: A thick film resistor excluding a toxic lead component from a conductive component and glass and having characteristics equivalent to or superior to conventional resistors in terms of, in a wide resistance range, resistance values, TCR characteristics, current noise characteristics, withstand voltage characteristics and the like. The thick film resistor is formed of a fired product of a resistive composition, wherein the thick film resistor contains ruthenium-based conductive particles containing ruthenium dioxide and a glass component essentially free of a lead component and has a resistance value in the range of 100 ?/? to 10 M?/? and a temperature coefficient of resistance within ±100 ppm/° C.
    Type: Grant
    Filed: December 14, 2017
    Date of Patent: September 3, 2019
    Assignee: SHOEI CHEMICAL INC.
    Inventors: Hiroshi Mashima, Yukari Morofuji
  • Patent number: 10392535
    Abstract: A binder resin for an inorganic particle-dispersed paste that excels in both printability and adhesiveness and such an inorganic particle-dispersed paste are provided. The resin includes a mixture in which a polyvinyl acetal and a cellulose derivative are mixed so as to satisfy 0.2?X/(X+Y)?0.8, where X and Y stand for parts by mass of the polyvinyl acetal and the cellulose derivative, respectively. When a paste is formulated by mixing and kneading the resin with spherical nickel particles with an average particle diameter of 0.3 ?m, barium titanate particles with an average particle diameter of 0.05 ?m, a nonionic surfactant, dihydroterpineol, and mineral spirit at the prescribed mixing ratio, the paste has prescribed rheological characteristics.
    Type: Grant
    Filed: July 22, 2016
    Date of Patent: August 27, 2019
    Assignee: SHOEI CHEMICAL INC.
    Inventors: Takamasa Imai, Seiyu Teruya, Kousuke Nishimura
  • Patent number: 10347787
    Abstract: A conductive paste for forming a solar cell electrode, including: a conductive powder containing silver as a main component; glass frit; and an organic vehicle, wherein the glass frit contains tellurium glass frit having tellurium oxide as a network-forming component. The conductive paste of the present invention makes it possible to form a solar cell electrode having a low dependence on firing temperature without causing problems due to fire-through into the substrate, and to thereby obtain a solar cell having good solar cell characteristics.
    Type: Grant
    Filed: August 24, 2017
    Date of Patent: July 9, 2019
    Assignees: Shoei Chemical Inc., Heraeus Precious Metals North American Conshohocken LLC
    Inventors: Masami Nakamura, Naoto Shindo, Tadashi Kanasaku
  • Patent number: 10249774
    Abstract: A conductive paste for forming solar cell electrodes that obtains favorable electrical characteristics and sufficient adhesion strength to a substrate. The conductive paste for forming a solar cell electrode includes the following: a tellurium-based glass frit containing 30-70 mol % of tellurium, 15-40 mol % of tungsten, 5-30 mol % of zinc, 0-20 mol % of boron, and 0-10 mol % of zirconium (where a total content of boron and zirconium is greater than 0 mol %) in terms of oxides; a conductive powder having silver as a main component and specific surface area of 0.4 m2/g or more; and an organic vehicle.
    Type: Grant
    Filed: March 2, 2016
    Date of Patent: April 2, 2019
    Assignee: SHOEI CHEMICAL INC.
    Inventors: Tadashi Kanasaku, Kousuke Nishimura, Masayuki Kurahashi
  • Publication number: 20190032241
    Abstract: A method for producing a metal oxide nanocrystals according to the embodiment of the present invention comprises continuously flowing a nanocrystal precursor solution comprising a nanocrystal precursor into a continuous flow path and heating the nanocrystal precursor solution in the continuous flow path to create nanocrystals, comprising: providing a nanocrystal precursor solution supply unit that is connected to the continuous flow path and comprises a first vessel and a second vessel; delivering a nanocrystal precursor solution in the second vessel to the continuous low path; and creating a nanocrystal precursor solution in the first vessel as a different batch from the nanocrystal precursor solution in the second vessel.
    Type: Application
    Filed: July 22, 2016
    Publication date: January 31, 2019
    Applicant: Shoei Chemical Inc.
    Inventors: Thomas E. Novet, Yukihisa Okawa, Masahito Igari, David M. Schut
  • Publication number: 20180371638
    Abstract: A method for producing metal oxide nanocrystals, according to the embodiment of the present invention, includes: continuously flowing, into a continuous flow path, one or a plurality of nanocrystal precursor solutions each comprising one or more nanocrystal precursors dissolved in a non-polar solvent; directing a segmenting gas into the continuous flow path to create a segmented reaction flow; flowing the segmented reaction flow into a thermal processor; heating the segmented reaction flow in the thermal processor to create a product flow; and collecting metal oxide nanocrystals from the product flow.
    Type: Application
    Filed: July 22, 2016
    Publication date: December 27, 2018
    Applicant: Shoei Chemical Inc.
    Inventors: Thomas E. Novet, Yukihisa Okawa, Masahito Igari, David M. Schut
  • Patent number: 10084100
    Abstract: A solar cell element containing: a semiconductor substrate; an antireflection film disposed in a first region on one main surface of the semiconductor substrate; and a front surface electrode disposed in a second region on the one main surface of the semiconductor substrate and containing silver as a main component and a tellurium-based glass containing tellurium, tungsten, and bismuth. The solar cell element is manufactured by forming the antireflection film on the one main substrate surface; printing on the antireflection film a conductive paste containing a conductive powder mainly containing silver, a tellurium-based glass frit containing tellurium, tungsten, and bismuth, and an organic vehicle; and disposing the antireflection film in the first region and forming the front surface electrode in the second region, by firing the paste and eliminating the antireflection film positioned under the paste.
    Type: Grant
    Filed: October 4, 2011
    Date of Patent: September 25, 2018
    Assignees: SHOEI CHEMICAL INC., KYOCERA CORPORATION
    Inventors: Masami Nakamura, Naoto Shindo, Tadashi Kanasaku, Junichi Atobe
  • Patent number: 9943909
    Abstract: A carbon-coated metal powder having few impurities, a narrower particle size distribution, and sintering properties is particularly suitable as a conductive powder of a conductive paste for forming internal conductors in a ceramic multilayer electronic component obtained by co-firing multilayered ceramic sheets and internal conductor layers; a conductive paste containing the carbon-coated metal powder; a multilayer electronic component using the conductive paste; and a method for manufacturing the carbon-coated metal powder. The carbon-coated metal powder has specific properties in TMA or ESCA measurements. The carbon-coated metal powder can be obtained by melting and vaporizing a metallic raw material in a reaction vessel, conveying the generated metal vapor into a cooling tube and rapidly cooling the metal vapor by endothermically decomposing a carbon source supplied into the cooling tube, and forming a carbon coating film on metal nuclei surfaces in parallel with generation of the metal nuclei.
    Type: Grant
    Filed: June 17, 2015
    Date of Patent: April 17, 2018
    Assignee: SHOEI CHEMICAL INC.
    Inventors: Yuji Akimoto, Hideki Tanaka, Mineto Iwasaki, Akiko Matsuo
  • Patent number: 9892828
    Abstract: A thick film resistor excluding a toxic lead component from a conductive component and glass and having characteristics equivalent to or superior to conventional resistors in terms of, in a wide resistance range, resistance values, TCR characteristics, current noise characteristics, withstand voltage characteristics and the like. The thick film resistor is formed of a fired product of a resistive composition, wherein the thick film resistor contains ruthenium-based conductive particles containing ruthenium dioxide and a glass component essentially free of a lead component and has a resistance value in the range of 100?/? to 10 M?/? and a temperature coefficient of resistance within ±100 ppm/° C.
    Type: Grant
    Filed: August 20, 2015
    Date of Patent: February 13, 2018
    Assignee: SHOEI CHEMICAL INC.
    Inventors: Hiroshi Mashima, Yukari Morofuji
  • Patent number: 9845397
    Abstract: A method for producing a binder resin by a reaction of a cellulose derivative, a polyvinyl acetal, and a bonding agent that has in the molecule at least two functional groups that can react to hydroxyl groups in the polyvinyl acetal and the cellulose derivative. In the production method, the content of the bonding agent is at least double the molar quantity of whichever has the greater number of moles between the polyvinyl acetal and the cellulose derivative. The produced binder resin is favorable in a coating paste such as a conductive paste, and causes an improvement in film quality such as the smoothness and denseness of a coating film formed by the paste.
    Type: Grant
    Filed: December 11, 2014
    Date of Patent: December 19, 2017
    Assignee: SHOEI CHEMICAL INC.
    Inventors: Ryojiro Akashi, Tomoko Uchida
  • Publication number: 20170352773
    Abstract: A conductive paste for forming a solar cell electrode, including: a conductive powder containing silver as a main component; glass frit; and an organic vehicle, wherein the glass frit contains tellurium glass frit having tellurium oxide as a network-forming component. The conductive paste of the present invention makes it possible to form a solar cell electrode having a low dependence on firing temperature without causing problems due to fire-through into the substrate, and to thereby obtain a solar cell having good solar cell characteristics.
    Type: Application
    Filed: August 24, 2017
    Publication date: December 7, 2017
    Applicants: SHOEI CHEMICAL INC., HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC
    Inventors: Masami NAKAMURA, Naoto SHINDO, Tadashi KANASAKU
  • Patent number: 9805839
    Abstract: An object of the present invention is to provide a resistive composition that can form a thick film resistor excluding a toxic lead component from a conductive component and glass and having characteristics equivalent to or superior to conventional resistors in terms of, in a wide resistance range, resistance values, TCR characteristics, current noise characteristics, withstand voltage characteristics and the like. The resistive composition of the present invention includes: ruthenium-based conductive particles including ruthenium dioxide; a glass frit that is essentially free of a lead component; and an organic vehicle, wherein the glass frit is a glass frit which is constituted such that in a case where a fired product of a mixture of the glass frit and the ruthenium dioxide has in a range of 1 k?/? to 1 M?/?, the fired product exhibits a temperature coefficient of resistance in a plus range.
    Type: Grant
    Filed: August 20, 2015
    Date of Patent: October 31, 2017
    Assignee: SHOEI CHEMICAL INC.
    Inventors: Hiroshi Mashima, Yukari Morofuji
  • Patent number: 9561543
    Abstract: A method for manufacturing metal powder includes: melting at least a portion of a metal starting material in a reaction vessel by utilizing plasma so as to form molten metal; evaporating the molten metal so as to produce a metal vapor; and transferring the metal vapor from the reaction vessel to a cooling tube together with a carrier gas supplied into the reaction vessel so as to cool the metal vapor, and condensing the metal vapor in the cooling tube, thereby producing metal powder. The method further includes supplying an oxygen gas into the reaction vessel.
    Type: Grant
    Filed: April 10, 2013
    Date of Patent: February 7, 2017
    Assignee: SHOEI CHEMICAL INC.
    Inventors: Fumiyuki Shimizu, Masayuki Maekawa, Tomotaka Nishikawa