Patents Assigned to Showa Shell Sekiyu Kabushiki Kaisha
  • Patent number: 5972242
    Abstract: A liquid crystal cell which minimizes disordered orientation occurring with temperature changes even across a wide range, to exhibit good contrast and high reliability, as well as a smectic liquid crystal composition for use the liquid crystal cell are provided. In smectic liquid crystal compositions having a layer construction in the liquid crystal molecular arrangement, it was found that antiferroelectric liquid crystal compositions resistant to variation in the layer spacing of the smectic phase due to temperature changes are resistant to disordered orientation. Specifically, if the antiferroelectric liquid crystal composition contains at lest 45 wt % of an antiferroelectric liquid crystal compound with roughly constant layer spacing in a temperature range from the temperature t.sub.1 which gives the minimum value for the layer spacing of the smectic C.sub.A * phase to -20.degree. C., no disordered liquid crystal orientation results even after cold/hot temperature cycles.
    Type: Grant
    Filed: June 3, 1997
    Date of Patent: October 26, 1999
    Assignees: Denso Corporation, Showa Shell Sekiyu Kabushiki Kaisha
    Inventors: Kenji Takigawa, Toshio Yamamoto, Yuichiro Yamada, Yoshihiko Aihara, Shigeharu Hashimoto, Yoshiichi Suzuki
  • Patent number: 5891359
    Abstract: The novel liquid crystal compounds of the present invention are represented by the following formulas ?I!-?II! and have tristable molecular orientation states and can be used for display devices and electrooptical devices. ##STR1## wherein R.sub.1 represents an alkyl group of 5-18 carbon atoms; R.sub.2 represents an alkyl group of 6-16 carbon atoms; R.sub.3 represents an alkyl group of 8-18 carbon atoms; R.sub.4 represents an alkyl group of 6-14 carbon atoms; Y represents ##STR2## and * indicates an optically active center.
    Type: Grant
    Filed: June 16, 1992
    Date of Patent: April 6, 1999
    Assignee: Showa Shell Sekiyu Kabushiki Kaisha
    Inventors: Yoshihiko Aihara, Tadaaki Isozaki, Noriko Yamakawa, Ichiro Kawamura
  • Patent number: 5464772
    Abstract: A process for producing an optically active halogen-containing alcohol having a high optical purity and represented by the following formula [I] ##STR1## wherein R.sup.1 is a halogen substituted alkyl group, R.sup.2 is a group selected from the group consisting of a substituted or unsubstituted alkyl group, alkene group, or alkyne group, and a substituted or unsubstituted phenyl group, and C having an asterisk indicates an asymmetric atom,is disclosed which process comprises subjecting a halogenated alkyl ester of a carboxylic acid represented by the following formula [II] ##STR2## wherein R.sup.1 and R.sup.2 are the same as mentioned above and R.sup.3 is a group selected from the group consisting of a substituted or unsubstituted alkyl group or alkene group, and a substituted or unsabstituted phenyl group,to asymmetric hydrolysis with an enzyme in an aqueous solution system, and the aqueous solution system may contain buffer solution and/or organic solvent.
    Type: Grant
    Filed: April 14, 1993
    Date of Patent: November 7, 1995
    Assignee: Showa Shell Sekiyu Kabushiki Kaisha
    Inventors: Katutoshi Hirose, Yoshihiro Takagi, Toshihiko Otomatsu, Yoshiichi Suzuki
  • Patent number: 5451339
    Abstract: The present invention is to provide a liquid crystal monomeric compound where a liquid crystal phase readily appears, which is excellent in alignment control, film-formability, durability, heat-stability and compatibility, and is able to be applied to electro-optical liquid crystal elements and recording elements; and a side-chain liquid crystal polymer compound modified with such a monomeric compound.The liquid crystal monomeric compound is represented by the following formula:CH.sub.2 .dbd.CH--(CH.sub.2).sub.m --R [1]wherein m is an integer of 2 to 20 and R is a group selected from the group consisting of ##STR1## wherein p is 1 or 2, Rf is CF.sub.3 or CF.sub.2 F.sub.5, R.sup.1 is an alkyl group having 3-18 carbon atoms, * means an optically active carbon atom, (A) and (B) each is a group independently selected from the group consisting of ##STR2## which may be substituted with one or more halogen atoms, and X is --O--, --COO--or a direct linkage, and ##STR3## wherein p, Rf, R.sup.
    Type: Grant
    Filed: May 19, 1993
    Date of Patent: September 19, 1995
    Assignee: Showa Shell Sekiyu Kabushiki Kaisha
    Inventors: Yoshiichi Suzuki, Yoshio Imai, Masaaki Kakimoto
  • Patent number: 5436037
    Abstract: A liquid crystal orientation controlling membrane, characterized by the polyimide membrane comprising the repeating unit represented by the formula: ##STR1## wherein Ar.sub.1 represents a diamine moiety which is selected from the group consisting of ##STR2## Ar.sub.2 represents tetravalent carboxylic acid moiety which is selected from the group consisting of ##STR3## Another invention is a ferroelectric liquid crystal element or an antiferroelectric liquid crystal element using the polyimide orientation controlling membrane mentioned above. The present liquid crystal element is used to a large picture display with high resolution, a TV picture display with wide viewing angle and a liquid crystal optical shutter.
    Type: Grant
    Filed: September 16, 1992
    Date of Patent: July 25, 1995
    Assignee: Showa Shell Sekiyu Kabushiki Kaisha
    Inventors: Nobuhiro Okabe, Yuvraj S. Negi, Ichiro Kawamura, Tohru Ohode, Norio Yamamoto, Yuichiro Yamada
  • Patent number: 5433887
    Abstract: The invention discloses optically active liquid crystal compounds represented by the formulas [I], [II] and [III]: ##STR1## wherein R.sub.1 and R.sub.2 each represents an alkyl group of 4-18 carbon atoms, X represents O, COO or a single bond, and (A), (B), (C), (D) and (E) each represents ##STR2## in which l represents a halogen. The invention further discloses optically active liquid crystal compounds which are able to exhibit tristable states, represented by the formulas [IV], [V] and [VI]: ##STR3## wherein R.sub.1 ' and R.sub.2 ' each represents a straight chain alkyl group of 5-16 carbon atoms, X' represents O or COO and (A), (B), (C), (D) and (E), and l each has the same meaning as above.
    Type: Grant
    Filed: May 28, 1992
    Date of Patent: July 18, 1995
    Assignee: Showa Shell Sekiyu Kabushiki Kaisha
    Inventors: Tadaaki Isozaki, Hiroyuki Mogamiya, Shigenori Sakuma, Noriko Yamakawa
  • Patent number: 5417885
    Abstract: An antiferroelectric liquid crystal compound of the following formulae: ##STR1## wherein R.sup.1 and R.sup.2 each is an alkyl group of C.sub.4 - C.sub.18, Rf is CF.sub.3 or C.sub.2 F.sub.5, X is O, COO, or a single bond, and * shows an optically active carbon atom.
    Type: Grant
    Filed: August 3, 1993
    Date of Patent: May 23, 1995
    Assignee: Showa Shell Sekiyu Kabushiki Kaisha
    Inventors: Yoshiichi Suzuki, Takashi Hagiwara, Ichiro Kawamura
  • Patent number: 5364561
    Abstract: A liquid crystal compound represented by the following formula; ##STR1## wherein R.sup.1 and R.sup.2 each represents an alkyl group having 3-20 carbon atoms, and X represents a group ##STR2## or --O--, or a single bond, and a liquid crystal composition exhibiting optically tristable states comprising the liquid crystal compound represented by the above formula and an antiferroelectric liquid crystal compound.
    Type: Grant
    Filed: April 27, 1993
    Date of Patent: November 15, 1994
    Assignee: Showa Shell Sekiyu Kabushiki Kaisha
    Inventors: Tadaaki Isozaki, Hiroyuki Mogamiya, Yoshihiko Aihara, Takashi Hagiwara
  • Patent number: 5346648
    Abstract: An antiferroelectric liquid crystal compound represented by the following general formula (I): ##STR1## wherein R.sup.1 and R.sup.2 are each independently selected from the group consisting of alkyl groups having from 3 to 18 carbon atoms, Rf is a lower alkyl group or a fluorinated lower alkyl group, (A) and (B) are each independently selected from the group consisting of 1,4-phenylene, 4,4'-biphenylene, and 2,6-naphthalene which may be substituted at least with a halogen atom, and * shows an asymmetric carbon atom.
    Type: Grant
    Filed: September 29, 1993
    Date of Patent: September 13, 1994
    Assignee: Showa Shell Sekiyu Kabushiki Kaisha
    Inventors: Yasuhiro Koide, Hiroyuki Mogamiya, Yoshiichi Suzuki
  • Patent number: 5330563
    Abstract: A process is disclosed for recovering a volatile organic compound at a recovery of 90 to 96% by volume from a gas generated from gasoline, kerosine, benzene, and alcohol discharged from storage tanks, tank trucks, and tank lorries. In the process comprising absorption stages followed by desorption stages for the volatile organic compound, the pressure at the desorption stages is controlled within the area below, for instance, curves C' and B in FIG. 1 of the drawings according to the concentration of the volatile organic compound in the gas to be fed to a first absorption stage.
    Type: Grant
    Filed: March 19, 1993
    Date of Patent: July 19, 1994
    Assignee: Showa Shell Sekiyu Kabushiki Kaisha
    Inventors: Osamu Yamase, Yasuyuki Makita, Kazuyoshi Jajima
  • Patent number: 5330678
    Abstract: Disclosed are novel liquid crystal compounds containing a naphthalene ring, having an excellent light leaking ratio at tristable states, and represented by the following formula: ##STR1## wherein R.sub.1 is a C.sub.6 -C.sub.16 linear alkyl group or C.sub.6 -C.sub.16 linear alkoxy group, R.sub.2 is a C.sub.4 -C.sub.12 linear alkyl group, R.sub.3 is a C.sub.1 -C.sub.3 alkyl group or C.sub.1 -C.sub.3 haloalkyl group, and C having an asterisk indicates an asymmetric atom.The liquid crystal compounds are expected to find their applications in electrooptical devices and liquid crystal displays utilizing a S*.sub.(3) liquid crystal phase which shows tristable states.
    Type: Grant
    Filed: May 25, 1993
    Date of Patent: July 19, 1994
    Assignee: Showa Shell Sekiyu Kabushiki Kaisha
    Inventors: Nobuhiro Okabe, Hiroyuki Mogamiya, Noriko Yamakawa
  • Patent number: 5328641
    Abstract: Liquid crystal compound of the formula ##STR1## wherein R.sub.1 and R.sub.2 each is a C.sub.1-18 alkyl group or an aralkyl group, R' is haloalkyl group, X is --O--, --CO--, --COO-- or direct bond, Y is --COO--, --OCO-- or --CH.sub.2 O--, (A) and (B) each is ##STR2## and p and l each is zero or one.
    Type: Grant
    Filed: October 13, 1992
    Date of Patent: July 12, 1994
    Assignee: Showa Shell Sekiyu Kabushiki Kaisha
    Inventors: Yoshihiko Aihara, Tadaaki Isozaki, Hioyuki Mogamiya, Yuvraj Negi, Toru Ooide
  • Patent number: 5320776
    Abstract: A novel antiferroelectric liquid crystal compound is disclosed which is represented by the following formula: ##STR1## wherein R.sup.1 and R.sup.2 are independently selected from C.sub.3 -C.sub.18 alkyl groups, respectively, Rf is a lower fluoroalkyl group, X is a group selected from the group consisting of --O--, --COO--, --OOC--, and --CO--, or a single bond, (A) and (B) each is independently a group selected from the group consisting of phenyl, biphenyl, and naphthalene group which may be substituted with a halogen atom, and C having an asterisk indicates an asymmetric carbon atom.
    Type: Grant
    Filed: May 19, 1993
    Date of Patent: June 14, 1994
    Assignee: Showa Shell Sekiyu Kabushiki Kaisha
    Inventors: Yoshiichi Suzuki, Toru Ohde
  • Patent number: 5310500
    Abstract: Antiferroelectric liquid crystal compounds are provided which have the formula ##STR1## wherein R.sub.1 represents an alkyl group having 5-18 carbon atoms,R.sub.
    Type: Grant
    Filed: June 5, 1992
    Date of Patent: May 10, 1994
    Assignee: Showa Shell Sekiyu Kabushiki Kaisha
    Inventors: Yoshihiko Aihara, Tadaaki Isozaki, Toru Ooide, Noriko Yamakawa
  • Patent number: 5284717
    Abstract: The present invention provides a method for producing raw materials for a reformer by cracking and desulfurizing petroleum fuels, characterized by cracking and desulfurizing petroleum fuels in a desulfurizer in the fuel cell electricity generation process at a temperature of 300.degree.-600.degree. C., preferably 350.degree.-500.degree. C., a pressure of 1-10 kg/cm.sup.2, an H.sub.2 /oil of 500-2000, preferably 800-1000, and an SV of 0.5-4 hr.sup.-1 using a zeolite catalyst such as Y-type zeolite or a metallosilicate catalyst such as one having an Si/Me atomic ratio of 40-3200 where Me is Al, Ni, Co, Mo, W, Fe, Cr or Ga.
    Type: Grant
    Filed: February 25, 1993
    Date of Patent: February 8, 1994
    Assignees: Petroleum Energy Center, Showa Shell Sekiyu Kabushiki Kaisha
    Inventors: Osamu Yamase, Tadayuki Miura, Hajime Kubota
  • Patent number: 5262086
    Abstract: (R)- and (S)-enantiomer composition represented by the formula (I) having sufficient high optical purity for exhibiting optically tristable states in S*(3) phase; ##STR1## wherein Ra means a C.sub.5 -C.sub.14 alkyl group or a C.sub.5 -C.sub.14 alkoxy group, preferably a C.sub.5 -C.sub.14 alkyl group, Rb means a C.sub.4 -C.sub.12 normal alkyl group or a C.sub.4 -C.sub.12 branched alkyl group, X means a ##STR2## group or a ##STR3## group, Z means a fluorine containing alkyl group, preferably a trifluoromethyl group and * shows an optically active carbon.
    Type: Grant
    Filed: June 26, 1992
    Date of Patent: November 16, 1993
    Assignee: Showa Shell Sekiyu Kabushiki Kaisha
    Inventors: Yoshiichi Suzuki, Horiyuki Mogamiya, Ichiro Kawamura
  • Patent number: 5234755
    Abstract: The present invention provides a novel cloth superior in water absorption and oil absorption and besides, in dehydration by using a cloth made of synthetic fibers of low water absorption such as nylon and Tetron as a base and subjecting this base cloth to processing treatment with a composite comprising collagen short fibers chemically modified with oxide of fish oil and polyurethane resin, thereby to impart water absorption property thereto.
    Type: Grant
    Filed: March 4, 1991
    Date of Patent: August 10, 1993
    Assignee: Showa Shell Sekiyu Kabushiki Kaisha
    Inventor: Hiroshi Okamura
  • Patent number: 5235030
    Abstract: Linear aromatic copolyamides having good processability, superior thermal stability and excellent mechanical properties are provided. They comprise 55-90 mole % of a repearing unit of ##STR1## and 45-10 mole % of a repeating unit of ##STR2## wherein R.sub.1 and R.sub.2 each is a C.sub.4-12 aliphatic alkylene.
    Type: Grant
    Filed: April 17, 1992
    Date of Patent: August 10, 1993
    Assignee: Showa Shell Sekiyu Kabushiki Kaisha
    Inventor: Shunichi Koide
  • Patent number: 5220098
    Abstract: The present invention relates to a process for separating 2,7-DMN, characterized in that a mixture containing at least 50% by weight of 2,7-DMN and the other DMN isomers obtained by preliminarily concentrating a fraction in the range of 250.degree.-270.degree. C. of catalytically cracked petroleum oil is preliminarily adjusted to a temperature of 60.degree.-90.degree. C. to form a slurry containing the crystal of 2,7-DMN, which is placed in a tightly sealed pressure vessel, adiabatically pressurized to the range of 500-2,500 kgf/cm.sup.2 and solidified to form a state of co-existing of solid and liquid phases, liquid is then discharged under pressure from the solid-liquid co-existing system, the solid remaining in the vessel is pressed to discharge the liquid remaining between the solid particles, which are integrated to give 2,7-DMN having a purity of 98% by weight or more.
    Type: Grant
    Filed: September 9, 1991
    Date of Patent: June 15, 1993
    Assignees: Petroleum Energy Center, Showa Shell Sekiyu Kabushiki Kaisha, Kobe Steel Limited
    Inventors: Kazumoto Nakamura, Shinji Aihara, Yutaka Mito, Masami Takao, Hitoshi Hatakeyama
  • Patent number: 5207947
    Abstract: Liquid crystal compound of the formula ##STR1## wherein R.sub.1 and R.sub.2 each is a C.sub.1-18 alkyl group or an aralkyl group, R' is a haloalkyl group, X is --0--, --CO--, --COO-- or direct bond, Y is --COO--, --OCO-- or --CH.sub.2 O--, (A) and (B) each is ##STR2## and p and l each is zero or one.
    Type: Grant
    Filed: June 11, 1991
    Date of Patent: May 4, 1993
    Assignee: Showa Shell Sekiyu Kabushiki Kaisha
    Inventors: Yoshiichi Suzuki, Noriko Yamakawa, Yoshihiko Aihara, Hiroyuki Mogamiya, Toru Ooide, Tadaaki Isozaki, Yuvra Negi, Shigenori Sakuma