Abstract: The present invention is directed to a novel dimethicone copolyol halo ester intermediate which conforms to the following structure; ##STR1## wherein R" is --C(O)--CH.sub.2 --Cl;a is an integer from 0 to 200;b is an integer from 0 to 200;c is an integer from 1 to 200;R.sup.1 is selected from --(CH.sub.2).sub.n CH.sub.3 or phenyl;n is an integer from 0 to 10;R.sup.2 is --(CH.sub.2).sub.3 --(OCH.sub.2 CH.sub.2)x--(OCH.sub.2 CH(CH.sub.3))y--(OCH.sub.2 CH.sub.2)z--OH;x, y and z are integers and are independently selected from 0 to 20, which is useful as an intermediate for reaction with amines to prepare silicone based quaternary compounds.

Abstract: The invention discloses novel fluorine containing silanol polyester waxes. Compounds of the invention by virtue of (a) the polyester group, and (b) the fluorine containing terminal groups are extremely efficient lubricating materials when applied to a variety of surfaces. These materials spread out when applied and provide durable lubrication and hydrophobicity when applied to hair, skin, wood, plastic and textile fibers. The compounds of the present invention are prepared by reacting a silanol compound with a dicarboxylic acid and a fluorine containing alcohol.

Abstract: The present invention deals with the composition, and application of novel silicone compounds, useful as softening, anti-tangle, and conditioning agents for use in personal care, textile and related applications. The properties of these novel compounds containing silicone which makes them well suited for these applications is the fact that they are substantive to fibers, hair and skin and also very mild to the skin and eyes. The incorporation of a silicone component into the molecule results in several additional desirable properties heretofore unattainable. The polymers are more elastomeric rather than resinous, are more oxygen permeable and can be made more hydrophobic.

Abstract: The present invention relates to a series of novel ester containing quaternary silicone polymers, useful in softening hair, and fiber and conditioning skin. The compounds of the present invention are prepared by the esterification reaction of chloroacetic acid with a pendant hydroxyl group which is present on a silicone polymer. In a preferred embodiment the hydroxy containing silicone polymer has been alkoxylated with ethylene oxide, propylene oxide or mixtures thereof.

Abstract: The invention relates to a series of novel organofunctional silicone polymers which have a phosphate terminal functionality present within the polymer. Compounds of the invention, by virtue of their phosphate group, provide a nonvolatile lubricant antistat which can be applied to a variety of fibers. The compounds of the invention deposit on the fiber surface thereby altering the surface's physical properties. Compounds of the present invention by virtue of their linear nature are film formers on a variety of substrates, including hair and skin.The compounds of the present invention are prepared by phosphation of a hydroxyl group on the silicone polymer. The compounds useful as raw materials are terminal dimethicone copolyols. The introduction of a phosphate group onto the silicone polymer is achieved by reaction of the hydroxyl group on the silicone with a suitable phosphating reagent.

Abstract: The invention relates to a series of novel silicone fatty esters. This class of compounds, provide outstanding softening and lubricating when applied to textiles and fibers. The compounds of the present invention are prepared by reacting a the hydroxyl group in a silicone polymer with a fatty carboxylic acid, ester or anhydride.

Abstract: The present invention provides a novel vinyl silicone monomer which contain urethane functional groups. These materials are used as an intermediates in the preparation of polymers. The vinyl reactive silicone urethane intermediates are prepared by the reaction of hydroxy containing silicone compounds with Benzene-1-(1-isocyanato-1-methylethyl)-3-(1-methylethenyl).

Abstract: The invention discloses novel fatty carboxylic acid salts of organofunctional silicone amines. The amino pendant functionality is present within the polymer. Compounds of the invention by virtue of their being salts, deposit on the surface of various substrates. Thereby altering the substrate's surface physical properties. The desirable durable properties which can be given to substrates include; softness, lubrication, soil release, and hydrophobicity. The compounds of the present invention are prepared by the neutralization of a silicone amine with a fatty carboxylic acid.

Abstract: The present invention relates to a series of novel silicone proteins which are high substantive to fiber and hair. The compounds contain both a silicone portion and protein portion in a covalent bone one molecule. Since the compounds of the present invention are high molecular weight silicone polymers, they have a high degree of oxidative stability, even at elevated temperatures and are nonirritating to skin and eyes. The proteins of the present invention plate out on and form a film on the surface of hair skin and textile fibers. In addition, these compounds are non volatile and exhibit a inverse cloud point. These combination of properties makes these polymers ideally suited for use in personal care applications.The compounds of the invention having a pendant amphoteric group is represented by the following formula; ##STR1## wherein R is ##STR2## a is an integer from 0 to 200; b is an integer from 0 to 200;c is an integer from 1 to 200;R.sup.1 is selected from --(CH.sub.2).sub.n CH.sub.

Abstract: The invention discloses novel silanol waxes and applications thereof. Compounds of the invention by virtue of their silanol fatty ester group are waxy lubricious solids which provide outstanding lubrication and hydrophobicity when applied to surfaces like fiber, hair, skin or paper. The compounds of the present invention are prepared by reacting a silanol compound with a fatty carboxylic and or polycarboxylic acid, ester or anhydride.

Abstract: The disclosure defines a series of novel quaternary silicone polymers useful in softening hair, and fiber and conditioning skin. The compounds are silicone polymers which contain a quaternary nitrogen pendant group. In one embodiment, the quaternary nitrogen group has an alkylamido function, in another embodiment it contains a imidazoline derived function. These compounds have a high degree of oxidative stability, even at elevated temperatures, are non volatile and unlike many other traditional fatty quaternary compounds are non yellowing when applied to textile substrates.

Abstract: The present invention relates to a series of novel silicone phosphate organic amine salts. These compounds have one or more pendant phosphate group in the free acid form which is neutralized by a fatty amine group. The amine group will become protonated and a net positive charge will result. The phosphate will donate the proton and develop a net negative charge. This compound is more substantive and higher foaming than any of the components alone. These phosphated silicone salts by virtue of this unique salt formation is highly foaming, non irritating to eyes and skin and deposits on fiber surfaces and form effective surface modifying finishes. The compounds of the present invention are therefore very well suited to applications in the personal care market.

Abstract: The present invention relates to a series of novel silicone phosphobetaines which are high foaming low irritation surface active agents that are substantive to fiber and hair. The compounds, because they contain a pendant ionizable phosphate group and a quatarnary amine compound are amphoterics that is they contain both a positive and negative charge in the same molecule. Since the compounds of the present invention are high molecular weight silicone polymers, they have a high degree of oxidative stability, even at elevated temperatures. In addition, these compounds are non volatile and nonirritating. These combination of properties makes these polymers ideally suited for use in personal care applications.

Abstract: The invention discloses novel organofunctional silicone polymers which have an amphoteric pendant functionality. Compounds of the invention by virtue of their amphoteric structure are good detergents and foaming agents and essentially non irritating to eyes and skin. The compounds of the invention are nonirritating, and non yellowing and provide detergency and foam to many formulated products, including cosmetic and personal care products.The compounds of the present invention are prepared by introduction of a amphoteric group by reaction of acrylic acid or methyl acrylate with a primary alkoxylated amine containing the silicone polymer.

Abstract: The invention relates to a series of novel organofunctional silicone polymers which have an phosphate pendant functionality present within the polymer. Compounds of the invention by virtue of their phosphate group, provide a nonvolatile lubricant, antistat which can be applied to a variety of fibers. The compounds of the invention deposit on the fiber surface thereby altering the surface's physical properties.The compounds of the present invention are prepared by phosphation of a hydroxyl group on the silicone polymer. The compounds useful as raw materials are dimethicone copolyols. The introduction of a phosphate group onto the silicone polymer is achieved by reaction of the hydroxyl group on the silicone with a suitable phosphating reagent. Another method of introducing the phosphate group is by the phosphation of the hydroxy containing vinyl intermediate which is subsequently reacted with the silicone polymer by hydrosilation.

Abstract: The invention disclosed novel amino functional silicone polymers which have an ether amino pendant group. Compounds of the invention by virtue of their ether amino group, deposition on the surface of substrates, either alone or as complexes with cations, thereby altering the substrate's surface physical properties. The desirable durable properties which can be given to substrates include: softness, lubrication, soil release, and hydrophobicity. The compounds of the present invention are prepared by introduction of an amino group onto the silicone pendant group. Cyanoethylation followed by hydrogenation or reaction with ethylenimine or propylenimine of a hydroxy containing silicone polymer, or hydroxy containing vinyl intermediate which is subsequently introduced into the polymer backbone by hydrosilation are the preferred methods of preparation.

Abstract: The invention discloses novel silanol waxes. Compounds of the invention by virtue of their silanol fatty ester group are waxy lubricious solids which provide outstanding lubrication and hydrophobicity when applied to hair, skin and textile fibers. The compounds of the present invention are prepared by reacting a silanol compound with a fatty carboxylic and or polycarboxylic acid, ester or anhydride.

Abstract: An improved water-resistant cementitious composition and products made therefrom are provided by forming an aqueous cementitious slurry, as for example of calcined gypsum and adding an organic amine preferably containing a hydroxyl functionality and a silanic hydrogen containing silicone compound. The slurry is set in conventional manner by heating and drying. The resulting product has a high degree of water-resistance and has no adverse effect upon the physical properties of the board.

Abstract: The invention discloses novel organofunctional silicone polymers which have an ether amino pendant functionality present within the polymer. Compounds of the invention by virtue of their ether amino group, deposit on the surface of substrates, either alone or as complexes with cations. Thereby altering the substrate's surface physical properties. The desirable durable properties which can be given to substrates include; softness, lubrication, soil release, and hydrophoblicity. The compounds of the present invention are prepared by introduction of an amino group onto the silicone pendant group. Aminolysis and cyanoethylation of a hydroxy containing silicone polymer, or hydroxy containing vinyl intermediate which is subsequently introduced into the polymer backbone by hydrosilation are the preferred methods for peparing the compounds of the present invention.

Abstract: The invention discloses novel sulfated silicone polymers which have the sulfate group on a pendant functionality rather than within the polymer backbone. Compounds of the invention by virtue of the presence of this anionic group, are high foaming compounds which deposit on the surface of substrates. The deposition can be enhanced by forming complexes with cationic surface active agents. These compounds alter the substrate's surface physical properties providing softness and antistatic properties, but do not exhibit defoaming properties which would minimize their applicability to detergent systems.