Patents Assigned to Simbol Inc.
  • Patent number: 9650555
    Abstract: This invention relates to treated geothermal brine compositions containing reduced concentrations of iron and silica compared to the untreated brines. Exemplary compositions of the treated brine contain concentration of silica ranging from 0 to 80 mg/kg and concentration of iron ranging from 0 to 300 mg/kg. Exemplary compositions of the reduced silica and iron brines also contain reduced concentrations of elements like arsenic, barium, lead, and lithium.
    Type: Grant
    Filed: February 17, 2014
    Date of Patent: May 16, 2017
    Assignee: Simbol, Inc.
    Inventors: Stephen Harrison, John Burba, III
  • Patent number: 9644126
    Abstract: This invention relates to treated geothermal brine compositions containing reduced concentrations of iron, silica, and zinc compared to the untreated brines. Exemplary compositions contain concentration of zinc ranges from 0 to 300 mg/kg, concentration of silica ranges from 0 to 30 mg/kg, concentration of iron ranges from 0 to 300 mg/kg. Exemplary compositions also contain reduced concentrations of elements like lithium, manganese, arsenic, barium, and lead. Exemplary compositions include Salton Sea brines containing a concentration of zinc less than 10 mg/kg, a concentration of silica ranging from less than 10 mg/kg, and a concentration of iron less than 10 mg/kg.
    Type: Grant
    Filed: March 3, 2014
    Date of Patent: May 9, 2017
    Assignee: Simbol, Inc.
    Inventors: Stephen Harrison, John Burba
  • Patent number: 9644866
    Abstract: This invention relates to treated geothermal brine compositions containing reduced concentrations of silica, iron, and potassium compared to the untreated brines. Exemplary compositions of the treated brine contain a concentration of silica ranging from about 0 mg/kg to about 15 mg/kg, a concentration of iron ranging from about 0 mg/kg to about 10 mg/kg, and a concentration of potassium ranging from about 300 mg/kg to about 8500 mg/kg. Other exemplary compositions of the treated brines also contain reduced concentrations of elements like rubidium, cesium, and lithium.
    Type: Grant
    Filed: February 24, 2014
    Date of Patent: May 9, 2017
    Assignee: Simbol, Inc.
    Inventors: Stephen Harrison, John Burba, III
  • Patent number: 9249478
    Abstract: This invention relates to a method for the selective recovery of manganese and zinc from brines that includes the steps of contacting a brine with an ionic liquid in order to selectively extract manganese and zinc from the brine into the ionic liquid; and treating the ionic liquid containing extracted manganese and zinc with an aqueous solution to selectively precipitate manganese, producing a manganese depleted, zinc rich ionic liquid. The method can further include the steps of treating the manganese depleted, zinc rich ionic liquid with an aqueous solution to selectively precipitate zinc.
    Type: Grant
    Filed: March 14, 2013
    Date of Patent: February 2, 2016
    Assignee: Simbol, Inc.
    Inventors: Stephen Harrison, C. V. Krishnmohan Sharma, Pei-Yu Lan
  • Patent number: 9238851
    Abstract: This invention relates to a method for the selective recovery of manganese and zinc from geothermal brines that includes the steps of removing silica and iron from the brine, oxidizing the manganese and zinc to form precipitates thereof, recovering the manganese and zinc precipitates, solubilizing the manganese and zinc precipitates, purifying the manganese and zinc, and forming a manganese precipitate, and recovering the zinc by electrochemical means.
    Type: Grant
    Filed: July 16, 2013
    Date of Patent: January 19, 2016
    Assignee: Simbol, Inc.
    Inventors: Stephen Harrison, Samaresh Mohanta, C. V. Krishnamohan Sharma, Elizabeth Geler
  • Patent number: 9222149
    Abstract: This invention relates to a method for the preparation of lithium carbonate from lithium chloride containing brines. The method can include a silica removal step, capturing lithium chloride, recovering lithium chloride, supplying lithium chloride to an electrochemical cell and producing lithium hydroxide, contacting the lithium hydroxide with carbon dioxide to produce lithium carbonate.
    Type: Grant
    Filed: April 21, 2014
    Date of Patent: December 29, 2015
    Assignee: Simbol Inc.
    Inventor: Stephen Harrison
  • Patent number: 9074265
    Abstract: The invention generally relates to methods of selectively removing lithium from various liquids, methods of producing high purity lithium carbonate, methods of producing high purity lithium hydroxide, and methods of regenerating resin.
    Type: Grant
    Filed: October 3, 2013
    Date of Patent: July 7, 2015
    Assignee: Simbol, Inc.
    Inventors: Stephen Harrison, Robert Blanchet
  • Patent number: 9057117
    Abstract: This invention relates to a method for the selective recovery of manganese and zinc from geothermal brines that includes the steps of removing silica and iron from the brine, oxidizing the manganese and zinc to form precipitates thereof, recovering the manganese and zinc precipitates, solubilizing the manganese and zinc precipitates, purifying the manganese and zinc, and forming a manganese precipitate, and recovering the zinc by electrochemical means.
    Type: Grant
    Filed: April 30, 2013
    Date of Patent: June 16, 2015
    Assignee: Simbol, Inc.
    Inventors: Stephen Harrison, Samaresh Mohanta
  • Publication number: 20150152309
    Abstract: This invention relates to treated geothermal brine compositions containing reduced concentrations of lithium, iron and silica compared to the untreated brines. Exemplary compositions contain concentration of lithium ranges from 0 to 200 mg/kg, concentration of silica ranges from 0 to 30 mg/kg, concentration of iron ranges from 0 to 300 mg/kg. Exemplary compositions also contain reduced concentrations of elements like arsenic, barium, and lead.
    Type: Application
    Filed: February 25, 2014
    Publication date: June 4, 2015
    Applicant: Simbol Inc
    Inventors: Stephen Harrison, John Burba, III
  • Patent number: 9034294
    Abstract: This invention relates to a method for the preparation of lithium carbonate from lithium chloride containing brines. The method can include a silica removal step, capturing lithium chloride, recovering lithium chloride, supplying lithium chloride to an electrochemical cell and producing lithium hydroxide, contacting the lithium hydroxide with carbon dioxide to produce lithium carbonate.
    Type: Grant
    Filed: September 14, 2012
    Date of Patent: May 19, 2015
    Assignee: Simbol, Inc.
    Inventor: Stephen Harrison
  • Patent number: 9034295
    Abstract: This invention relates to a method for the preparation of lithium carbonate from lithium chloride containing brines. The method can include a silica removal step, capturing lithium chloride, recovering lithium chloride, supplying lithium chloride to an electrochemical cell and producing lithium hydroxide, contacting the lithium hydroxide with carbon dioxide to produce lithium carbonate.
    Type: Grant
    Filed: April 21, 2014
    Date of Patent: May 19, 2015
    Assignee: Simbol, Inc.
    Inventor: Stephen Harrison
  • Patent number: 9012357
    Abstract: This invention relates to a particulate extraction material for the extraction of lithium from a geothermal brine or lithium containing solution. The particulate material includes an inorganic or polymer based substrate that includes a lithium aluminate intercalate layer applied to the exterior of the substrate, wherein the lithium aluminate intercalate layer is operable to capture lithium ions from solution.
    Type: Grant
    Filed: December 16, 2013
    Date of Patent: April 21, 2015
    Assignee: Simbol, Inc.
    Inventors: Stephen Harrison, C.V. Krishnamohan Sharma, Brian E. Viani, Diana Rex
  • Patent number: 8901032
    Abstract: This invention relates to a method for preparing a lithium activated alumina intercalate solid by contacting a three-dimensional activated alumina with a lithium salt under conditions sufficient to infuse lithium salts into activated alumina for the selective extraction and recovery of lithium from lithium containing solutions, including brines.
    Type: Grant
    Filed: October 27, 2011
    Date of Patent: December 2, 2014
    Assignee: Simbol Inc.
    Inventors: Stephen Harrison, C. V. Krishnamohan Sharma, M. Scott Conley
  • Publication number: 20140301922
    Abstract: This invention relates to a method for the preparation of lithium carbonate from lithium chloride containing brines. The method can include a silica removal step, capturing lithium chloride, recovering lithium chloride, supplying lithium chloride to an electrochemical cell and producing lithium hydroxide, contacting the lithium hydroxide with carbon dioxide to produce lithium carbonate.
    Type: Application
    Filed: April 21, 2014
    Publication date: October 9, 2014
    Applicant: Simbol Inc.
    Inventor: Stephen Harrison
  • Publication number: 20140239224
    Abstract: This invention relates to a method for preparing a lithium aluminate intercalate (LAI) matrix solid and methods for the selective extraction and recovery of lithium from lithium containing solutions, including brines. The method for preparing the LAI matrix solid includes reacting aluminum hydroxide and a lithium salt for form the lithium aluminate intercalate, which can then be mixed with up to about 25% by weight of a polymer to form the LAI matrix.
    Type: Application
    Filed: May 5, 2014
    Publication date: August 28, 2014
    Applicant: Simbol Inc.
    Inventors: John L. Burba, Ray F. Stewart, Brian E. Viani, Stephen Harrison, Christine ellen Vogdes, John Galil Salim Lahlouh
  • Publication number: 20140239221
    Abstract: This invention relates to treated geothermal brine compositions containing reduced concentrations of lithium, iron and silica compared to the untreated brines. Exemplary compositions contain concentration of lithium ranges from 0 to 200 mg/kg, concentration of silica ranges from 0 to 30 mg/kg, concentration of iron ranges from 0 to 300 mg/kg. Exemplary compositions also contain reduced concentrations of elements like arsenic, barium, and lead.
    Type: Application
    Filed: February 25, 2014
    Publication date: August 28, 2014
    Applicant: Simbol Inc
    Inventors: Stephen Harrison, John Burba, III
  • Publication number: 20140231041
    Abstract: This invention relates to treated geothermal brine compositions containing reduced concentrations of iron and silica compared to the untreated brines. Exemplary compositions of the treated brine contain concentration of silica ranging from 0 to 80 mg/kg and concentration of iron ranging from 0 to 300 mg/kg. Exemplary compositions of the reduced silica and iron brines also contain reduced concentrations of elements like arsenic, barium, lead, and lithium.
    Type: Application
    Filed: February 17, 2014
    Publication date: August 21, 2014
    Applicant: Simbol Inc
    Inventors: Stephen Harrison, John Burba, III
  • Publication number: 20140227154
    Abstract: This invention relates to a method for the preparation of lithium carbonate from lithium chloride containing brines. The method can include a silica removal step, capturing lithium chloride, recovering lithium chloride, supplying lithium chloride to an electrochemical cell and producing lithium hydroxide, contacting the lithium hydroxide with carbon dioxide to produce lithium carbonate.
    Type: Application
    Filed: April 21, 2014
    Publication date: August 14, 2014
    Applicant: Simbol Inc.
    Inventor: Stephen Harrison
  • Publication number: 20140187452
    Abstract: This invention relates to treated geothermal brine compositions containing reduced concentrations of iron, silica, and manganese compared to the untreated brines. Exemplary compositions contain a concentration of manganese less than 10 mg/kg, a concentration of silica ranging from less than 10 mg/kg, and a concentration of iron less than 10 mg/kg, and the treated geothermal brine is derived from a Salton Sea geothermal reservoir.
    Type: Application
    Filed: March 5, 2014
    Publication date: July 3, 2014
    Applicant: Simbol Inc
    Inventors: Stephen Harrison, John Burba, III
  • Publication number: 20140174745
    Abstract: This invention relates to treated geothermal brine compositions containing reduced concentrations of iron, silica, and zinc compared to the untreated brines. Exemplary compositions contain concentration of zinc ranges from 0 to 300 mg/kg, concentration of silica ranges from 0 to 30 mg/kg, concentration of iron ranges from 0 to 300 mg/kg. Exemplary compositions also contain reduced concentrations of elements like lithium, manganese, arsenic, barium, and lead. Exemplary compositions include Salton Sea brines containing a concentration of zinc less than 10 mg/kg, a concentration of silica ranging from less than 10 mg/kg, and a concentration of iron less than 10 mg/kg.
    Type: Application
    Filed: March 3, 2014
    Publication date: June 26, 2014
    Applicant: Simbol Inc
    Inventors: Stephen Harrison, John Burba, III