Patents Assigned to Sinopec
  • Publication number: 20230118300
    Abstract: The invention relates to a process of converting methanol in a fluidized bed reactor comprising feeding a methanol-containing feedstock into a fluidized bed reactor, contacting the feedstock with a catalyst, to produce a product comprising ethylene and propylene under effective conditions; the fluidized bed reactor comprises a diluent-phase zone and a dense-phase zone, wherein the diluent-phase temperature difference between any regions of the diluent-phase zone having a methanol concentration of more than 0.1 wt % (preferably more than 0.01 wt %) in the fluidized bed reactor is controlled to be less than 20° C., and the dense-phase temperature difference between any regions in the dense-phase zone having a methanol concentration of more than 0.1 wt % (preferably more than 0.01 wt %) in the fluidized bed reactor is controlled to be less than 10° C.
    Type: Application
    Filed: March 12, 2021
    Publication date: April 20, 2023
    Applicants: CHINA PETROLEUM & CHEMICAL CORPORATION, SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC
    Inventors: Guozhen QI, Jing CAO, Xiaohong LI, Hongtao WANG, Li WANG, Yanxue WANG
  • Publication number: 20230118436
    Abstract: A process for producing lower olefins from oxygenates includes the steps of contacting a feedstock comprising oxygenates with molecular sieve catalyst in fluidized bed reaction zone under effective conditions, to produce product including ethylene and/or propylene; the effective conditions include that in the fluidized bed reaction zone, the weights of catalysts having various carbon deposition amounts are controlled, calculated as the weight of the molecular sieve in the catalysts, to have the following proportions based on the total weight of the catalysts in the fluidized bed reaction zone: the proportion of the weight of the catalyst having a coke deposition amount of less than 3 wt % is 1-20 wt %; the catalyst having a coke deposition amount of from 3 wt % to less than 5 wt % represents 10 to 70 wt %; the catalyst having a coke deposition amount from 5 wt % to 10 wt % represents 10 to 88 wt %.
    Type: Application
    Filed: March 11, 2021
    Publication date: April 20, 2023
    Applicants: CHINA PETROLEUM & CHEMICAL CORPORATION, SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC
    Inventors: Guozhen QI, Jing CAO, Xiaohong LI, Hongtao WANG, Yongming JIN, Pan GAO
  • Patent number: 11624033
    Abstract: A process for the catalytic cracking of hydrocarbon oils includes the step of contacting a hydrocarbon oil feedstock with a catalytic cracking catalyst in a reactor having one or more fast fluidized reaction zones for reaction. At least one of the fast fluidized reaction zones of the reactor is a full dense-phase reaction zone, and the axial solid fraction ? of the catalyst is controlled within a range of about 0.1 to about 0.2 throughout the full dense-phase reaction zone. When used for catalytic cracking of hydrocarbon oils, particularly heavy feedstock oils, the process, reactor and system show a high contact efficiency between oil and catalyst, a selectivity of the catalytic reaction, an effectively reduced yield of dry gas and coke, and an improved yield of high value-added products such as ethylene and propylene.
    Type: Grant
    Filed: July 15, 2019
    Date of Patent: April 11, 2023
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Jianhong Gong, Zhigang Zhang, Xiaoli Wei
  • Publication number: 20230083045
    Abstract: A computer-implemented method that uses a preprogrammed neural network and a trained neural network computer program product to predict and then compared borehole and formation sigmas, when using a pulse neutron source and at least three dual-function radiation detectors. These dual-function radiation detectors are used for detecting both neutrons and gamma rays and further pre-programmed to distinguish between neutrons and gamma rays by using pulse shape discrimination techniques. The trained neural network computer program product can be used on above-surface systems, as well as below surface systems like borehole assemblies in logging-while-drilling systems.
    Type: Application
    Filed: September 16, 2021
    Publication date: March 16, 2023
    Applicants: China Petroleum & Chemical Corporation, Sinopec Tech Houston
    Inventors: Sheng Zhan, Jeremy Zhang
  • Publication number: 20230075550
    Abstract: A method for wireline or logging-while-drilling systems that uses pulsed neutron sources coupled to multiple dual-function radiation detectors of neutrons and gamma rays, as well as a non-transitory computer readable memory device that can distinguish using pulse shape discrimination techniques the neutrons from the gamma rays in order to measure thermal neutron time-decay signals and thermal neutron capture gamma ray time-decay signals that are later further process using the non-transitory computer readable memory device to obtain a borehole sigma and formation sigma that are not affected by near-wellbore environments.
    Type: Application
    Filed: August 31, 2021
    Publication date: March 9, 2023
    Applicants: Sinopec Tech Houston, China Petroleum & Chemical Corporation
    Inventors: Sheng Zhan, Jeremy Zhang
  • Patent number: 11591303
    Abstract: A method for producing epoxyalkane includes the step of separating, in a separation column, a stream containing epoxyalkane, extractant, and diol. The separation column operates under conditions so as to enable the extractant and the diol to form an azeotrope, and a stream containing extractant and binary azeotrope is extracted from the side-draw of the separation column to liquid-liquid separation. The method can be used for the industrial production of epoxyalkane.
    Type: Grant
    Filed: November 30, 2018
    Date of Patent: February 28, 2023
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY SINOPEC
    Inventors: Song Hu, Shuai Hu, Weisheng Yang
  • Patent number: 11578253
    Abstract: This invention relates to a surfactant composition, production and use thereof in tertiary oil recovery. The present surfactant composition comprises a cationic surfactant and an anionic-nonionic surfactant, and exhibits significantly improved interfacial activity and stability as compared with the prior art. With the present surfactant composition, a flooding fluid composition for tertiary oil recovery with improved oil displacement efficiency and oil washing capability as compared with the prior art could be produced.
    Type: Grant
    Filed: June 11, 2020
    Date of Patent: February 14, 2023
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC
    Inventors: Yingcheng Li, Songyuan Gu, Weidong Zhang, Xinning Bao, Zhiqin Shen, Hengzhi Tang, Xiaodong Zhai
  • Patent number: 11572289
    Abstract: Apparatus and methods are related to treating waste water containing ammonium salts, which contains NH4+, SO42?, Cl?, and Na+. In such a method, the pH value of the waste water to be treated is adjusted to a specific range in advance; sodium sulfate crystal and relatively concentrated ammonia are obtained by first evaporation, and then sodium chloride crystal and relatively dilute ammonia is obtained by second evaporation; alternatively, sodium chloride crystal and relatively concentrated ammonia is obtained by third evaporation, and then sodium sulfate crystal and relatively dilute ammonia are obtained by fourth evaporation. Ammonia, sodium sulfate, and sodium chloride from the waste water are recovered so that the resources in the waste water can be reused.
    Type: Grant
    Filed: September 21, 2020
    Date of Patent: February 7, 2023
    Assignees: China Petroleum & Chemical Corporation, Sinopec Catalyst Co., Ltd.
    Inventors: Xiping Yin, Ye Li, Songyuan Gu, Zhijian Liu, Tao Wang, Jin'ai Gao, Yuhua Chen, Yan Zhou, Ling Yang, Zhiwei Yuan, Hongliang Yi, Tao An, Fuzu Liu, Zhimin Zhang, Shupeng Xu
  • Patent number: 11572283
    Abstract: A molecular sieve has a silica/alumina molar ratio of 100-300, and has a mesopore structure. One closed hysteresis loop appears in the range of P/P0=0.4-0.99 in the low temperature nitrogen gas adsorption-desorption curve, and the starting location of the closed hysteresis loop is in the range of P/P0=0.4-0.7. The catalyst formed from the molecular sieve as a solid acid not only has a good capacity of isomerization to reduce the freezing point, but also can produce a high yield of the product with a lower pour point. The process for preparing the catalyst involves steps including crystallization, filtration, calcination, and hydrothermal treatment.
    Type: Grant
    Filed: October 26, 2018
    Date of Patent: February 7, 2023
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Yunfei Bi, Guofu Xia, Mingfeng Li, Qinghe Yang, Weiguo Huang, Qingzhou Guo, Wenxiu Fang, Luqiang Wang, Hongbao Li, Honghui Li, Jie Gao
  • Patent number: 11571673
    Abstract: A fluid distributor includes one or more fluid transport main pipe. The fluid transport main pipe is configured to assume a closed shape when its centerlines and/or centerline extensions are joined end-to-end. Each of the fluid transport main pipe has at least one fluid inlet and is connected with a plurality of fluid transport branch pipes. Each of the fluid transport branch pipes has a plurality of open pores disposed along the length of the fluid transport branch pipe and a connection portion. The connection portion is configured to connect the fluid transport branch pipe to the housing after the fluid transport branch pipe passes through the housing of the vessel into the inner cavity.
    Type: Grant
    Filed: November 9, 2018
    Date of Patent: February 7, 2023
    Assignees: China Petroleum & Chemical Corporation, Shanghai Research Institute of Petrochemical Technology SINOPEC
    Inventors: Le Zhao, Lianghua Wu
  • Patent number: 11560524
    Abstract: Disclosed are a pulverized coal preprocessing method and a pulverized coal gasifying method. The pulverized coal preprocessing method comprises the following steps: (1) performing pore broadening on pulverized coal to obtain preprocessed pulverized coal; (2) loading alkali metal ions into the preprocessed pulverized coal under an ion exchange condition to obtain alkali metal loaded pulverized coal. The method further comprises loading a chrome complex into the alkali metal loaded pulverized coal obtained in described step (2). In gasification, the pulverized coal loaded with alkali metal potassium and chrome catalysts obtained by the method has the advantages of high sulphur removal rate, high carbon conversion rate, short gasifying reaction time and high methane production.
    Type: Grant
    Filed: October 28, 2019
    Date of Patent: January 24, 2023
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, SINOPEC NANJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY CO., LTD.
    Inventors: Jinli Wang, Jin Cai, Yang Yu, Yusheng Yin, Haitao Li, Yanfang Zhu, Xianliang Huang, Huijun Wang, Bengang Xu, Jie Zhang, Xueqi Wu, Lin Wu
  • Patent number: 11541377
    Abstract: A modified Y-type molecular sieve has a rare earth content of about 4-11% by weight on the basis of rare earth oxide, a sodium content of no more than about 0.5 wt % by weight on the basis of sodium oxide, a zinc content of about 0.5-5% by weight on the basis of zinc oxide, a phosphorus content of about 0.05-10% by weight on the basis of phosphorus pentoxide, a framework silica-alumina ratio of about 7-14 calculated on the basis of SiO2/Al2O3 molar ratio, a percentage of non-framework aluminum content to the total aluminum content of no more than about 10%, and a percentage of the pore volume of secondary pores having a pore size of 2-100 nm to the total pore volume of about 20-40%. The modified Y-type molecular sieve has a high crystallinity and a high thermal and hydrothermal stability, and is rich in secondary pores.
    Type: Grant
    Filed: August 20, 2019
    Date of Patent: January 3, 2023
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Hao Sha, Lingping Zhou, Shuai Yuan, Weilin Zhang, Zhenyu Chen, Mingde Xu, Huiping Tian
  • Publication number: 20220403263
    Abstract: Described are a process and a system for processing aromatics-rich fraction oil. The process includes: (1) introducing an aromatics-rich fraction oil into a fifth reaction unit for hydrosaturation, followed by fractionation, to provide a first light component and a first heavy component; (2) introducing a deoiled asphalt and an aromatics-comprising stream including the first heavy component into a hydrogen dissolving unit to be mixed with hydrogen, and introducing the mixed material into a first reaction unit for a hydrogenation reaction; (3) fractionating a liquid-phase product from the first reaction unit to provide a second light component and a second heavy component; (41) introducing the second light component into a second reaction unit for reaction; and (42) introducing the second heavy component into a delayed coking unit for reaction; or using the second heavy component as a component of low sulfur ship fuel oil.
    Type: Application
    Filed: October 30, 2020
    Publication date: December 22, 2022
    Applicants: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Qinghe YANG, Yanzi JIA, Dawei HU, Chuanfeng NIU, Shuling SUN, Lishun DAI, Zhen WANG, Anpeng HU, Liang REN, Dadong LI
  • Patent number: 11529612
    Abstract: The present invention relates to the field of catalytic cracking, and discloses a composition capable of reducing CO and NOx emissions, the preparation method and use thereof, and a fluidized catalytic cracking method. The inventive composition capable of reducing CO and NOx emissions comprises an inorganic oxide carrier, and a first metal element, optionally a second metal element, optionally a third metal element and optionally a fourth metal element supported on the inorganic oxide carrier, wherein the first metal element includes Fe and Co, and wherein the weight ratio of Fe to Co is 1:(0.1-10) on an oxide basis. The inventive composition has better hydrothermal stability and higher activity of reducing CO and NOx emissions in the flue gas from the regeneration.
    Type: Grant
    Filed: July 5, 2018
    Date of Patent: December 20, 2022
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Haitao Song, Qiuqiao Jiang, Huiping Tian, Wei Lin, Peng Wang, Yan Sun, Xue Yang, Jiushun Zhang, Zhijian Da
  • Patent number: 11524281
    Abstract: A phosphorus-containing molecular sieve has a phosphorus content of about 0.3-5 wt %, a pore volume of about 0.2-0.95 ml/g, and a ratio of B acid content to L acid content of about 2-10. The molecular sieve has a specific combination of characteristics, including a high ratio of B acid content to L acid content, thereby exhibiting higher hydrocracking activity and ring-opening selectivity when used in the preparation of a hydrocracking catalyst.
    Type: Grant
    Filed: October 22, 2018
    Date of Patent: December 13, 2022
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Yichao Mao, Mingfeng Li, Xiangyun Long, Runqiang Zhang, Yang Zhao
  • Patent number: 11517886
    Abstract: A modified Y-type molecular sieve has a modifying metal content of about 0.5-6.3 wt % calculated on the basis of an oxide of the modifying metal and a sodium content of no more than about 0.5 wt % calculated on the basis of sodium oxide. The modifying metal is magnesium and/or calcium. The modified Y-type molecular sieve has a proportion of non-framework aluminum content to the total aluminum content of no more than about 20%, a total pore volume of about 0.33-0.39 ml/g, a proportion of the pore volume of secondary pores having a pore size of 2-100 nm to the total pore volume of about 10-25%, a lattice constant of about 2.440-2.455 nm, a lattice collapse temperature of not lower than about 1040° C., and a ratio of B acid to L acid in the total acid content of no less than about 2.30.
    Type: Grant
    Filed: June 27, 2019
    Date of Patent: December 6, 2022
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Shuai Yuan, Lingping Zhou, Huiping Tian, Zhenyu Chen, Weilin Zhang, Hao Sha
  • Patent number: 11518949
    Abstract: A process for producing propylene and a low-sulfur fuel oil component, comprising the steps of contacting a heavy feedstock oil with a solvent for extraction separation to obtain a deasphalted oil and a deoiled asphalt; contacting the deasphalted oil and optionally a light feedstock oil with a catalytic conversion catalyst for reaction to obtain a reaction product comprising propylene; separating the reaction product to obtain a catalytic cracking distillate oil, and subjecting the catalytic cracking distillate oil to hydrodesulfurization to obtain a low-sulfur hydrogenated distillate oil, wherein the low-sulfur hydrogenated distillate oil and/or the deoiled asphalt is suitable for use as a fuel oil component. The process allows the conversion of saturated hydrocarbons in the heavy feedstock into propylene, eliminates the use of saturated hydrocarbons in the fuel oil component, and thus has better economic and social benefits.
    Type: Grant
    Filed: October 26, 2020
    Date of Patent: December 6, 2022
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Youhao Xu, Xuhui Bai, Xinyu Xie, Shouye Cui, Xin Wang, Yanfen Zuo
  • Patent number: 11517887
    Abstract: A modified Y-type molecular sieve has a rare earth content of about 4% to about 11% by weight on the basis of the oxide, a phosphorus content of about 0.05% to about 10% by weight on the basis of P2O5, a sodium content of no more than about 0.5% by weight on the basis of sodium oxide, and an active element content of about 0.1% to about 5% by weight on the basis of the oxide, with the active element being gallium and/or boron. The modified Y-type molecular sieve has a total pore volume of about 0.36 mL/g to about 0.48 mL/g, a percentage of the pore volume of secondary pores having a pore size of 2-100 nm of about 20% to about 40%; a lattice constant of about 2.440 nm to about 2.455 nm, and a lattice collapse temperature of not lower than about 1060° C.
    Type: Grant
    Filed: August 15, 2019
    Date of Patent: December 6, 2022
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Lingping Zhou, Hao Sha, Mingde Xu, Weilin Zhang, Shuai Yuan, Zhenyu Chen, Qiuqiao Jiang, Huiping Tian
  • Patent number: 11518684
    Abstract: A NaY molecular sieve with an aluminum-rich surface is prepared using a process that includes the steps of: a. mixing a directing agent and a first silicon source to obtain a first mixture, wherein the directing agent has a molar composition of Na2O:Al2O3:SiO2:H2O=(6-25):1:(6-25):(200-400); b. mixing the first mixture obtained in the step a with a second silicon source, an aluminum source and water to obtain a second mixture; c. carrying out hydrothermal crystallization on the second mixture obtained in the step b, and collecting a solid product. Calculated as SiO2, the weight ratio of the first silicon source to the second silicon source is 1:(0.01-12). The NaY molecular sieve has larger aluminum distribution gradient from the surface to the center of the particle than the conventional molecular sieve.
    Type: Grant
    Filed: May 27, 2019
    Date of Patent: December 6, 2022
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Qiang Fu, Yongxiang Li, Chengxi Zhang, Hexin Hu, Xuhong Mu, Xingtian Shu
  • Patent number: 11512259
    Abstract: A process for producing propylene and a low-sulfur fuel oil component, comprising the steps of: i) contacting a hydrocarbon-containing feedstock oil with a catalytic conversion catalyst for reaction under effective conditions in a catalytic conversion reactor in the absence of hydrogen to obtain a reaction product comprising propylene; ii) separating the reaction product from step i) to obtain a catalytic cracking distillate oil, and iii) subjecting the catalytic cracking distillate oil to hydrodesulfurization to obtain a low-sulfur hydrogenated distillate oil suitable for use as a fuel oil component. The process can greatly improve the propylene selectivity and propylene yield while producing more fuel oil components, significantly reduce the yield of dry gas and coke, and thus has better economic and social benefits.
    Type: Grant
    Filed: October 26, 2020
    Date of Patent: November 29, 2022
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Youhao Xu, Xin Wang, Yanfen Zuo, Shouye Cui, Xuhui Bai, Xinyu Xie