Abstract: A method of preparing 3(4),8(9)-bisformyltricyclo[5.2.1.02,6]decane is provided. According to the present invention, 3(4),8(9)-bisformyltricyclo[5.2.1.02,6]decane (TCDDA) may be prepared with a high conversion rate and purity without a separate catalyst recovery process.
Type:
Grant
Filed:
May 31, 2019
Date of Patent:
January 21, 2025
Assignee:
SK Chemicals Co., Ltd.
Inventors:
Hee Il Chae, Jeong Ho Park, Kyung Sil Yoon, Ju-Sik Kang, Yu Mi Chang, Nam-Choul Yang, Jae Kyun Park, Song Lee
Abstract: A stretched polyester film and a method for preparing the stretched polyester film are disclosed. The stretched polyester film contains a polyester resin in which a diol component and a dicarboxylic acid component are polymerized, wherein the heat shrinkage rate of the film at 80° C. in the main shrinkage direction is 40% or more, and, upon a first thermal treatment and a second thermal treatment, a first melting temperature (Tm1) and a second melting temperature (Tm2) appear when the film is analyzed by differential scanning calorimetry (DSC). The stretched polyester film has excellent heat shrinkability, along with an increased efficiency of a recycling process of waste plastic containers.
Type:
Grant
Filed:
August 14, 2023
Date of Patent:
December 17, 2024
Assignee:
SK CHEMICALS CO., LTD.
Inventors:
Da-Young Hwang, Sangwoo Kim, Jiyeon Eom, Boo-Youn Lee
Abstract: The present invention relates to a highly bio-based polycarbonate ester and a method for producing same. The highly bio-based polycarbonate ester has a bio-based carbon content of 80% or more since the highly bio-based polycarbonate ester is obtained by copolymerization of 1,4:3,6-dianhydrohexitol, which is a bio-based monomer derived from biomass, and 1,4-cyclohexanedicarboxylate and/or terephthalate, and therefore, the highly bio-based polycarbonate ester is not only human-friendly and environmentally friendly, but also advantageous in terms of biodegradability.
Abstract: A method for producing bis(2-hydroxyethyl)terephthalate is disclosed. The method includes recovering and reusing ethylene glycol with an acetate removed, after the glycolysis of a waste polyester. According to the method, an acetate is not concentrated even though ethylene glycol is reused in a continuous process, leading to bis(2-hydroxyethyl)terephthalate with excellent purity and quality.
Type:
Application
Filed:
September 4, 2023
Publication date:
November 28, 2024
Applicant:
SK CHEMICAL CO., LTD.
Inventors:
Ji-Hun KIM, Joong Ki LEE, Kwang-Woo PARK, Seong-Ki LEE, Yuntae JIN
Abstract: The present invention relates to a copolymerized saturated polyester resin and a coating composition containing same. Provided are a copolymerized saturated polyester resin and a coating composition having excellent hot water resistance, chemical resistance and processability when formed into a coating film, and showing excellent adhesiveness to a metal base, and thus particularly useful for coating a can and pre-coated metal (PCM).
Type:
Grant
Filed:
January 31, 2019
Date of Patent:
November 26, 2024
Assignee:
SK CHEMICALS CO., LTD.
Inventors:
Hyung-Gon Kim, Jong-Ki Sim, Soon-Ki Kim
Abstract: A polymerization raw material obtained by the depolymerization of waste polyester is disclosed. The polymerization raw material contains recycled bis(2-hydroxyethyl) terephthalate in which the contents of acetate-based ester compounds and diethylene glycol ester compounds are adjusted to specific levels. The polymerization raw material is excellent in purity and quality, and free from the problem that thermal resistance characteristics deteriorate in the polymerization of a polymer from the recycled monomer.
Type:
Application
Filed:
September 25, 2023
Publication date:
October 17, 2024
Applicant:
SK CHEMICALS CO., LTD.
Inventors:
Ji-Hun KIM, Kwang-Woo PARK, Seong-Ki LEE, Joong Ki LEE, Yuntae JIN
Abstract: A stretched polyester film and a method for preparing the stretched polyester film are disclosed. The stretched polyester film contains a polyester resin in which a diol component and a dicarboxylic acid component are polymerized, wherein the heat shrinkage rate of the film at 80° C. in the main shrinkage direction is 40% or more, and, upon a first thermal treatment and a second thermal treatment, a first melting temperature (Tm1) and a second melting temperature (Tm2) appear when the film is analyzed by differential scanning calorimetry (DSC). The stretched polyester film has excellent heat shrinkability, along with an increased efficiency of a recycling process of waste plastic containers.
Type:
Application
Filed:
August 14, 2023
Publication date:
October 17, 2024
Applicant:
SK CHEMICALS CO., LTD.
Inventors:
Da-Young HWANG, Sangwoo Kim, Jiyeon Eom, Boo-Youn Lee
Abstract: The present disclosure relates to a method for purifying bis-2-hydroxyethyl terephthalate with high purity and a polyester resin containing the same.
Type:
Grant
Filed:
September 14, 2021
Date of Patent:
September 3, 2024
Assignee:
SK Chemicals Co., Ltd.
Inventors:
Da-Young Hwang, Kwang-Woo Park, Yoo Jin Lee, Jong-In Lee
Abstract: The present disclosure relates to a polyester film and a preparation method of the same. Since the polyester film includes a resin layer formed from a mixture comprising a polyester resin, which includes a first diol moiety derived from isosorbide and a second diol moiety derived from cyclohexanedimethanol in a controlled ratio, and polyethylene terephthalate in a specific ratio, it is possible to exhibit improved heat resistance and adhesion with excellent light transmittance.
Abstract: A method for producing bis-2-hydroxyethyl terephthalate is disclosed. The method includes the steps of: (1) adding a waste polyester raw material into a co-extruder to obtain a co-extrudate; (2) adding the co-extrudate into a reactor with an agitation shaft and depolymerizing same to obtain a first reaction product; (3) adding the first reaction product into a first continuous stirred tank reactor and depolymerizing same to obtain a second reaction product; and (4) adding the second reaction product into a second continuous stirred tank reactor and depolymerizing same to obtain a third reaction product.
Type:
Application
Filed:
June 15, 2023
Publication date:
August 15, 2024
Applicant:
SK CHEMICALS CO., LTD.
Inventors:
Ji-Hun KIM, Kwang-Woo PARK, Seong-Ki LEE, Joong Ki LEE, Yuntae JIN
Abstract: A polyester resin comprising regenerated BHET according to an embodiment has excellent heat resistance characteristics since a diethylene glycol generated from the regenerated BHET to remain in the polyester resin is adjusted to a predetermined level or less, so that the polyester resin can be manufactured into a heat-shrinkable film.
Type:
Grant
Filed:
April 18, 2023
Date of Patent:
June 25, 2024
Assignee:
SK CHEMICALS CO., LTD.
Inventors:
Da-Young Hwang, Sangwoo Kim, Ha-Neul Kim, Boo-Youn Lee
Abstract: The present invention relates to a phosphine precursor for the preparation of a quantum dot, and a quantum dot prepared therefrom. Using the phosphine precursor for the preparation of a quantum dot of the present invention, a quantum dot with improved luminous efficiency and higher luminous color purity can be provided.
Type:
Grant
Filed:
April 7, 2022
Date of Patent:
June 4, 2024
Assignee:
SK Chemicals Co., Ltd.
Inventors:
Jeong Ho Park, Hee Il Chae, Kyung Sil Yoon, Ju-Sik Kang, Yu Mi Chang, Nam-Choul Yang, Jae Kyun Park, Song Lee
Abstract: The present disclosure relates to a polyester film and a preparation method of the same. Since the polyester film includes a resin layer formed from a polyester resin including a first diol moiety derived from isosorbide and a second diol moiety derived from cyclohexanedimethanol in a controlled ratio on at least one surface of a base layer, it is possible to exhibit excellent heat resistance and adhesion.
Abstract: Provided are a tricyclodecane dimethanol composition, in which a ratio of structural isomers is controlled, and a preparation method thereof.
Type:
Grant
Filed:
May 20, 2022
Date of Patent:
April 23, 2024
Assignee:
SK Chemicals Co., Ltd.
Inventors:
Hee Il Chae, Ju-Sik Kang, Jeong Ho Park, Song Lee, Yu Mi Chang
Abstract: The present invention is a composition for liquid crystal polymer synthesis comprising an alicyclic dicarboxylic acid or its derivative (e.g., 1,4-cyclohexanedicarboxylic acid (CHDA)); an aromatic diol (e.g., hydroquinone (HQ)); an aromatic monocarboxylic acid having 7 to 10 carbon atoms and containing a hydroxyl group (e.g., 4-hydroxybenzoic acid, (HBA)); and an aromatic monocarboxylic acid having 11 to 20 carbon atoms and containing a hydroxyl group (e.g., 6-hydroxy-2-naphthalenecarboxylic acid (HNA)), and a liquid crystal polymer for electrical/electronic products, a polymer resin composition, and a molded product using the same.
Type:
Grant
Filed:
May 29, 2018
Date of Patent:
March 26, 2024
Assignee:
SK Chemicals Co., Ltd.
Inventors:
Kwang Sei Oh, Ji-Hoon Kim, Jong-In Lee, Sun-Hee Lee, Myung-Se Lee
Abstract: The present invention relates to a polyester resin. The polyester resin is useful for bottles, sheets, multilayer sheets, stretched films and fiber applications due to excellent heat resistance and transparency, and in particular, the polyester resin has little deterioration of physical properties such as yellowing, etc., during processing. A process for making the polyester resin includes an esterification reaction between a dicarboxylic acid that includes terephthalic acid and a diol that includes isosorbide in the presence of a catalyst, followed by a polycondensation reaction on a product of the esterification reaction. In some embodiments, an initial mixing ratio of the dicarboxylic acid and the diol is between 1:1.02 and 1:1.04.
Type:
Grant
Filed:
September 23, 2020
Date of Patent:
March 26, 2024
Assignee:
SK Chemicals Co., Ltd.
Inventors:
Yoo Jin Lee, Su-Min Lee, Sung-Gi Kim, Min-Young Han, Dong-jin Han
Abstract: The present invention relates to an MDO thermoresistant heat-shrinkable multilayer film of a copolymer polyester having excellent thermal resistance. In particular, the present invention provides an MDO thermoresistant heat-shrinkable multilayer film that includes multiple skin layers capable of improving thermal resistance formed on a substrate layer capable of providing high shrinkage, and simultaneously has excellent thermal resistance and high shrinkage properties through MD orientation instead of the conventional TD orientation method.
Abstract: The present invention relates to a phosphine precursor for the preparation of a quantum dot, and a quantum dot prepared therefrom. Using the phosphine precursor for the preparation of a quantum dot of the present invention, a quantum dot with improved luminous efficiency and higher luminous color purity can be provided.
Type:
Grant
Filed:
March 2, 2018
Date of Patent:
February 27, 2024
Assignee:
SK Chemicals Co., Ltd.
Inventors:
Hee Il Chae, Jeong Ho Park, Kyung Sil Yoon, Ju-Sik Kang, Yu Mi Chang, Nam-Choul Yang, Jae Kyun Park, Song Lee
Abstract: Provided are a tricyclodecane dimethanol composition which may be suitably used in preparing a polyester resin exhibiting excellent solvent resistance and chemical resistance when forming a coating film and having excellent solubility in organic solvents or water, and a preparation method thereof.
Type:
Grant
Filed:
May 20, 2022
Date of Patent:
February 6, 2024
Assignee:
SK Chemicals Co., Ltd.
Inventors:
Hee Il Chae, Ju-Sik Kang, Jeong Ho Park, Song Lee, Yu Mi Chang