Abstract: In an embodiment, a method of concentrating a hydrogen isotope, comprises delivering a fluid comprising the hydrogen isotope to be concentrated and an additional gas other than then hydrogen isotope to an anode of an electrochemical cell comprising a hydron exchange membrane comprising hydrons of the hydrogen isotope, and also comprising said anode on a first side of the hydron exchange membrane, a cathode on a second side of the hydron exchange membrane, and an electrical circuit connection between the anode and the cathode; removing a first stream in fluid communication with the cathode, the first stream comprising concentrated hydrogen isotope; and removing a second stream in fluid communication with the anode, comprising the additional gas delivered to the anode depleted of the hydrogen isotope.

Abstract: In an aspect, a system comprises a water stream in fluid communication with an electrolyzer; the electrolyzer comprising an anode and a cathode side chamber; a deep space oxygen radiator in fluid communication with the anode side chamber of the electrolyzer; a cryogenic heat exchanger comprising an oxygen storage tank in fluid communication with the deep space oxygen radiator; an electrochemical hydrogen compressor in fluid communication with the cathode side chamber; a hydrogen storage tank in fluid communication with the electrochemical hydrogen compressor via a cooled hydrogen stream; wherein at least a portion of the cooled hydrogen stream is in a first fluid communication with an expansion valve and the cryogenic heat exchanger; wherein the hydrogen storage tank is in a second fluid communication with the electrochemical hydrogen compressor via a warmed hydrogen stream; and wherein the cryogenic heat exchanger is in fluid communication with the warmed hydrogen stream.

Abstract: In an embodiment, a method for recovering carbon dioxide comprises introducing a carbon dioxide rich stream to a scrubber comprising a metal hydroxide and allowing the carbon dioxide to react with the metal hydroxide to form a metal carbonate; directing a metal carbonate stream from the scrubber to an electrochemical concentrator and applying a potential to the electrochemical concentrator to form a metal hydroxide stream and a separated carbon dioxide stream; directing the metal hydroxide stream comprising a recovered metal hydroxide and hydrogen to an electrochemical separator and applying a potential to the electrochemical separator to separate the hydrogen forming a hydrogen recycle stream from the recovered metal hydroxide forming a metal hydroxide recycle stream; and directing the separated carbon dioxide stream to a gas liquid separator and separating the separated carbon dioxide stream into a recycled water stream and a concentrated carbon dioxide stream.

Abstract: In an embodiment, a hydrogen monitoring system comprises a plurality of sensing elements that individually comprise a working electrode, a counter electrode, an insulating layer located in between the working electrode and the counter electrode, a catalyst located on an end of both the working electrode and the counter electrode, an electrolyte located on the end of the sensing elements on both the working electrode and the counter electrode, between the working electrode and the counter electrode, and in contact with the catalyst, and an electrical circuit located on an opposite end of the sensing element that connects the working electrode and the counter electrode.

Abstract: Disclosed herein is an air-water extraction system that includes a water selective membrane configured to transport water from humid air via selective diffusion through the water selective membrane; a low pressure chamber in fluid communication with the water selective membrane and a hydrogen gas inlet configured to deliver a dry hydrogen to the low pressure gas chamber, a membrane and electrode assembly comprising an anode, a proton exchange membrane, a cathode, and a power supply; wherein the anode is in fluid communication with the low pressure chamber, a high pressure chamber in fluid communication with the cathode for receiving a saturated hydrogen and a liquid water from the cathode; a water conduit in fluid communication with the high pressure chamber configured to remove the liquid water from the high pressure chamber, and a hydrogen conduit for removing the saturated hydrogen from the high pressure chamber.

Abstract: In an embodiment, a hydrogen monitoring system comprises a plurality of sensing elements that individually comprise a working electrode, a counter electrode, an insulating layer located in between the working electrode and the counter electrode, a catalyst located on an end of both the working electrode and the counter electrode, an electrolyte located on the end of the sensing elements on both the working electrode and the counter electrode, between the working electrode and the counter electrode, and in contact with the catalyst, and an electrical circuit located on an opposite end of the sensing element that connects the working electrode and the counter electrode.

Abstract: An electrochemical cell stack is disclosed having a plurality of stacked planar electrochemical cell modules, a first end plate at a first end of the stacked planar modules, and a second end plate at a second end of the stacked planar modules. Also included in the stack is an intermediate planar module disposed between adjacent electrochemical cells in the stack. In some aspects, the intermediate module includes a cavity disposed internally within the intermediate module that is in fluid communication with a fluid source at a pressure higher than the operating pressure of the electrochemical cell stack on either side of the intermediate module. In some aspects, the electrochemical cell stack includes an electrically conductive process liquid in fluid communication with a plurality of electrochemical cells in the stack, and the intermediate planar module includes an electrically non-conductive channel in fluid communication with the electrically conductive process liquid.

Abstract: A system for providing hydrogen includes a first electrochemical cell or stack including a first cathode and a first anode separated by a first proton exchange membrane. A first inlet is in communication with the anode side of the first electrochemical cell or stack. The first inlet receives a first gas including hydrogen. A liquid composition on a liquid flow path is in communication with the cathode side of the first electrochemical cell or stack. The liquid composition includes water and a water-compatible redox compound. A second electrochemical cell stack including a second cathode and a second anode separated by a second proton exchange membrane is disposed with the anode side of the second electrochemical cell or stack in communication with the liquid flow path. A hydrogen outlet in communication with the cathode side of the second electrochemical cell or stack dispenses hydrogen from the system.