Abstract: Process for obtaining a “diesel cut” fuel having a CN cetane number equal to or greater than 48 and a content of aromatics lower than 0.4% by weight starting from olefins or their mixtures, characterized in that it comprises oligomerizing said olefins having from 2 to 10 carbon, distilling the stream obtained from the oligomerization, and hydrogenating the separated C12-C24 hydrocarbon stream.
Abstract: A process is described for the production of hydrocarbons with a high octane number starting from mixtures essentially consisting of n-butane and isobutane (such as for example field butanes) comprising a skeleton isomerization section, a dehydrogenation section of paraffins, a selective hydrogenation section of butadiene, two conversion sections of olefins, in which the isobutene is firstly selectively transformed by means of dimerization and/or etherification, followed by the linear butenes by means of alkylation, in order to obtain, by joining the products of the two conversion sections, a product having excellent motoristic properties (octane number, volatility and distillation curve).
Type:
Grant
Filed:
April 23, 2003
Date of Patent:
May 24, 2005
Assignee:
Snamprogetti S.p.A.
Inventors:
Mario Marchionna, Marco Di Girolamo, Domenico Sanfilippo, Alberto Paggini
Abstract: Process for the production of hydrocarbon blends with a high octane number by the hydrogenation of hydrocarbon blends, containing branched C8, C12 and C16 olefinic cuts, characterized by sending said blends, as such or fractionated into two streams, one substantially containing the branched C8 olefinic cut, the other substantially containing the branched C12 and C16 olefinic cuts, to a single hydrogenation zone or to two hydrogenation zones in parallel, respectively, only the stream substantially containing saturated C8 hydrocarbons, obtained by the fractionation of the stream produced by the single hydrogenation zone or obtained by the hydrogenation zone fed by the fractionated stream substantially containing the branched C8 olefinic cut, being at least partly recycled to the single hydrogenation zone or to the hydrogenation zone fed by the fractionated stream substantially containing the branched C8 olefinic cut, and the hydrocarbon blend with a high octane number, obtained by the fractionation of the stre
Type:
Application
Filed:
December 29, 2003
Publication date:
April 14, 2005
Applicant:
SNAMPROGETTI S.p. A.
Inventors:
Roberto Catani, Marco Di Girolamo, Massimo Conte, Ambrogio Gusberti
Abstract: Process for the production of synthesis gas from heavy charges comprising a partial oxidation of heavy charges with oxygen or air enriched in oxygen in the presence of vapour, carried out at temperatures higher than 1000° C. and pressures equal to or higher than 20 atm and the subsequent cooling of the synthesis gas obtained, by the direct injection of water into the gas itself followed by the separation of the water effected by means of an adduction pipe surrounded by a concentric tube open at both ends so as to form a ring through which the cooled gas and water can rise, characterized in that the distance (L) between the lower end of the adduction pipe and the lower end of the open concentric tube must be equal to or higher than x times the diameter (D) of said lower end of the adduction pipe, wherein x varies in relation to the specific gas mass flow-rate (F), expressed in kg/h/cm2, according to the equation x=0.026 F+0.15.
Abstract: Process for the production of hydrogen consisting in subjecting a solid to oxidation and treating, in a different zone, the oxidized form thus produced with a reducing stream, preferably a hydrocarbon.
Type:
Grant
Filed:
March 19, 2001
Date of Patent:
April 5, 2005
Assignee:
Snamprogetti, S.p.A.
Inventors:
Domenico Sanfilippo, Alberto Paggini, Valerio Piccoli, Roberta Miglio, Stefano Rossini
Abstract: A process is described for the dehydrogenation of ethylbenzene to styrene in a fluid-bed reactor-regenerator system, which uses a catalyst based on iron oxide supported on a modified alumina and promoted with further metal oxides.
Abstract: Process for the production of synthesis gas, by means of catalytic partial oxidation or autothermal reforming of light hydrocarbons, which comprises partially oxidizing the hydrocarbon with oxygen coming from the reduction of at least one metal oxide selected from hexavalent chromium oxide, supported on an inert carrier and modified with an alkaline and/or earth-alkaline metal, and metal oxides capable of autonomously sustaining the catalytic partial oxidation reaction by means of redox cycles.
Type:
Grant
Filed:
April 25, 2000
Date of Patent:
December 21, 2004
Assignee:
Snamprogetti S.p.A.
Inventors:
Domenico Sanfilippo, Alberto Paggini, Ivano Miracca, Carlo Rescalli
Abstract: Use of a liquid oxygenated product with a cetane number higher than 50, consisting of one or more compounds selected from dialkyl-polyformals represented by the formula
Type:
Application
Filed:
November 20, 2003
Publication date:
September 30, 2004
Applicants:
ENI S.p.A., SNAMPROGETTI S.p.A.
Inventors:
Domenico Sanfilippo, Renata Patrini, Mario Marchionna
Abstract: Catalytic system for the production of hydrogen consisting of an active component based on iron and a micro-spheroidal carrier based on alumina and represented by the following formula
Abstract: A process is described for the production of hydrocarbons with a high octane number starting from mixtures essentially consisting of n-butane and isobutane (such as for example field butanes) comprising a skeleton isomerization section, a dehydrogenation section of paraffins, a selective hydrogenation section of butadiene, two conversion sections of olefins, in which the isobutene is firstly selectively transformed by means of dimerization and/or etherification, followed by the linear butenes by means of alkylation, in order to obtain, by joining the products of the two conversion sections, a product having excellent motoristic properties (octane number, volatility and distillation curve).
Type:
Application
Filed:
April 23, 2003
Publication date:
January 15, 2004
Applicant:
SNAMPROGETTI S.p.A.
Inventors:
Mario Marchionna, Marco Di Girolamo, Domenico Sanfilippo, Alberto Paggini
Abstract: A liquid mixture having a cetane number higher than 40, comprising a typical diesel gas oil cut having a boiling point ranging from 150 to 380° C., and a density ranging from 0.76 and 0.935 g/ml at 15 ° C.; and one or more compounds selected from dialkyl-polyformals represented by the formula RO(CH2O)mR, wherein R is a CnH2n+1 alkyl chain, m is an integer equal to or greater than 2 and less than or equal to 6, n is an integer ranging from 1 to 10, wherein the concentration of these dialkyl-polyformals in the gas oil ranges from 1 to 20%; and a process for production of dialkyl-polyformals using sulfonic acid-based catalysts.
Abstract: A process is described for the hydrogenation of olefinic streams containing sulfurated compounds, obtained starting from hydrocarbon cuts containing isobutene (by means of selective dimerization), characterized by fractionating said streams in one or more distillation columns and hydrogenating separately the two fractions obtained. The stream at the head, with a minimum content of sulfurated compounds, is hydrogenated with conventional catalysts based on nickel or noble metals (Platinum and/or Palladium), extremely active but also very sensitive to sulfur, whereas the bottom of the column, rich in sulfurated compounds, is treated with bimetallic catalysts (for example Ni/Co and/or Ni/Mo), less active but not deactivated by sulfur.
Type:
Application
Filed:
October 7, 2002
Publication date:
April 24, 2003
Applicant:
SNAMPROGETTI S.p.A.
Inventors:
Marco Di Gerolamo, Roberto Catani, Mario Marchionna
Abstract: A liquid mixture is described having a cetane number higher than 40, characterized in that it consists of:
a typical diesel gas oil cut having a boiling point ranging from 150 to 380° C. and a density ranging from 0.76 to 0.935 g/ml at 15° C.;
one or more compounds selected from dialkyl-polyformals represented by the formula:
RO(CH2O)mR
wherein R is a CnH2n+1 alkyl chain
m is an integer equal to or greater than 2 and less than or equal to 6,
n is an integer ranging from 1 to 10,
wherein the concentration of said dialkyl-polyformals in the gas oil ranges from 1 to 20% by volume.
A process is also described for the production of dialkyl-polyformals, starting from alcohols and/or dialkylformals and formaldehyde in the presence of sulfonic acids optionally substituted.
Abstract: A process is described for the production of hydrocarbons with a high octane number starting from hydrocarbon cuts containing isobutene by means of selective dimerization with acid catalysts, characterized in that the dimerization reaction is carried out in a tubular reactor using a feeding containing isobutene in quantities of less than 20% by weight and with a molar ratio linear olefins/isobutene greater than 3, preferably operating at a reaction temperature ranging from 30 to 120° C., at a pressure of less than 5 MPa and at feeding space velocities of less than 60 h−1.
Type:
Grant
Filed:
January 18, 2001
Date of Patent:
December 31, 2002
Assignee:
Snamprogetti S.p.A.
Inventors:
Mario Di Girolamo, Mario Marchionna, Lorenzo Tagliabue
Abstract: A process for preparing light olefins from corresponding paraffins consists of reacting said paraffins in a reactor, operating at a temperature of between 450 and 800° C., a pressure of between 0.1 and 3 atm absolute and a GHSV of between 100 and 10000 h−1, with a catalytic system containing gallium, platinum, possibly one or more alkaline or alkaline-earth metals, and a support consisting of alumina in delta or theta phase or in delta+theta or theta+alpha or delta+theta+alpha mixed phase, modified with silica, the gallium, expressed as Ga2O3, being in a quantity of between 0.1 and 33.6 wt %, the platinum being in a quantity of between 1 and 99 ppm, the alkaline or alkaline-earth metals, expressed as oxide, being in a quantity of between 0 and 5 wt %, and the silica being in a quantity of between 0.
Type:
Application
Filed:
July 1, 2002
Publication date:
December 26, 2002
Applicant:
SNAMPROGETTI S.p.A.
Inventors:
Rodolfo Iezzi, Andrea Bartolini, Franco Buonomo
Abstract: A process is described for the production of hydrocarbons with a high octane number starting from hydrocarbon cuts containing isobutene by selective dimerization with acid catalysts, characterized in that the dimerization reaction is carried out in the presence of tertiary alcohols, alkyl ethers and primary alcohols in such a quantity as to have, in the feeding, a molar ratio tertiary alcohols+alkyl ethers+primary alcohols/isobutene higher than 0.1, a molar ratio tertiary alcohols/isobutene lower than 0.2 and a molar ratio primary alcohols/isobutene lower than 0.2, preferably operating at a reaction temperature ranging from 30 to 120° C., at a pressure lower than 5 MPa and feeding space velocities of less than 30 h−1.
Type:
Grant
Filed:
August 4, 2000
Date of Patent:
August 13, 2002
Assignees:
Snamprogetti S.p.A., Ecofuel S.p.A.
Inventors:
Marco Di Girolamo, Mario Marchionna, Lorenzo Tagliabue
Abstract: A process is described for the production of hydrocarbons with a high octane number starting from mixtures essentially consisting of n-butane and isobutane (such as for example field butanes) comprising a skeleton isomerization section, a dehydrogenation section of paraffins, a selective hydrogenation section of butadiene, two conversion sections of olefins, in which the isobutene is firstly selectively transformed by means of dimerization and/or etherification, followed by the linear butenes by means of alkylation, in order to obtain, by joining the products of the two conversion sections, a product having excellent motoristic properties (octane number, volatility and distillation curve).
Type:
Application
Filed:
November 9, 2001
Publication date:
July 4, 2002
Applicant:
SNAMPROGETTI S.p.A.
Inventors:
Mario Marchionna, Marco Di Girolamo, Domenico Sanfilippo, Alberto Paggini
Abstract: Process for the separation of light olefins from paraffins contained in mixtures, optionally also containing hydrogen, comprising bringing said mixtures into contact with an aqueous solution of one or more compounds of silver, preferably silver nitrate, and one or more ferric compounds, preferably ferric nitrate.
Type:
Grant
Filed:
July 18, 2000
Date of Patent:
July 2, 2002
Assignee:
Snamprogetti S.p.A.
Inventors:
Carmen Pirovano, Domenico Sanfilippo, Francesco Saviano, Laura Piovesan