Patents Assigned to Societa' Italiana Resine S.p.A.
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Patent number: 4100212Abstract: Liquid-phase chlorination of n-paraffins is improved as to yield on chlorine and as to restriction to mono-substitution by passing the paraffins up a reactor divided into stages by baffles and feeding chlorine in controlled amounts to each stage.Type: GrantFiled: October 28, 1975Date of Patent: July 11, 1978Assignee: Societa'Italiana Resine S.p.A.Inventors: Lucio Di Fiore, Benedetto Calcagno, Marcello Ghirga
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Patent number: 3969344Abstract: A process for purifying a polymerisable monomer selected from the group consisting of cyclic ethers, hydrocarbon olefins, vinyl compounds, aldehydes, lactams of the formula: ##EQU1## wherein x is an integer from 3 to 13 and lactones of the formula: ##EQU2## wherein n is an integer of from 1 to 4 and wherein R represents an hydrogen atom, an alkyl group or an aryl group; said process comprising contacting a liquid consisting of said monomer at a temperature of not greater than 130.degree. centigrade and at a pressure sufficient to keep said monomer in liquid form, with a solid absorbent consisting essentially of a porous reticulated macromolecular alkali metal or alkaline earth metal salt of a cationic exchange resin containing carboxylic, sulfonic or phosphoric acid groups, said cationic exchange resin having a specific surface area of at least one square meter per gram and a pore diameter of from 10.sup.1.3 to 10.sup.5 angstroms and recovering the purified monomer.Type: GrantFiled: November 4, 1971Date of Patent: July 13, 1976Assignee: Societa' Italiana Resine S.p.A.Inventors: Jacob Ackermann, Pierino Radici
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Patent number: 3956376Abstract: An improved process for the production of acrolein from propylene and of acrylic acid from propylene or acrolein or mixtures of propylene and acrolein which essentially comprises catalytic oxidation of propylene and/or acrolein with oxygen or a gas containing molecular oxygen in the presence of an oxidation catalyst and of methanol in a quantity of from 0.01 to 1% by volume with respect to the total gaseous mixture of the reactants. Acrolein and acrylic acid are formed in the process at high conversion rates and selectivities.Type: GrantFiled: November 29, 1973Date of Patent: May 11, 1976Assignee: Societa Italiana Resine S.p.A.Inventors: Natale Ferlazzo, Gian Fausto Buzzi, Marcello Ghirga
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Patent number: 3948621Abstract: Process for the simultaneous separation of ethylene oxide and carbon dioxide from the gaseous mixtures obtained in the direct oxidation of ethylene with oxygen, comprisingA. cooling the gaseous mixture containing ethylene oxide, unreacted ethylene, water vapour, carbon dioxide and inert gases after addition of methanol to a temperature such that the water vapour present separates in the form of an aqueous methanol solution;B. washing the obtained gaseous mixture in an absorption zone with methanol, the methanol being fed into the intermediate part of the absorption zone as a main methanol stream and into the upper part as a secondary methanol stream, maintaining the temperature of the secondary methanol stream at least about 30.degree.C lower than that of the main methanol stream and removing from the upper part a gaseous mixture being practically free of ethylene oxide and containing carbon dioxide and ethylene and from the lower part of the absorption zone a solution of ethylene oxide in methanol; andC.Type: GrantFiled: December 26, 1973Date of Patent: April 6, 1976Assignee: Societa' Italiana Resine S.p.A.Inventors: Gioacchino Cocuzza, Benedetto Calcagno, Gianni Torreggiani
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Patent number: 3940368Abstract: A copolymer suitable for making self-extinguishing fibers, containing at least 50 wt.% acrylonitrile, from 2 to 30 wt.% vinyl or vinylidene chloride, from 0 to 10 wt.% of a neutral, ethylenically unsaturated, non-halogenated monomer and from 2 to 40 wt.% of alpha-bromoacrylonitrile.Type: GrantFiled: November 19, 1974Date of Patent: February 24, 1976Assignee: Societa' Italiana Resine S.p.A.Inventors: Luciano Console, Ferdinando Bencini, Enzo Chiellini
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Patent number: 3939120Abstract: A copolymer suitable for making self-extinguishing fibers, containing at least 50 wt.% acrylonitrile, from 2 to 30 wt.% of vinyl or vinylidene chloride, from 0 to 10 wt.% of a neutral, non-halogenated, ethylenically unsaturated monomer and from 2 to 40 wt.% of a monomer of the general formula: ##EQU1## WHEREIN R is hydrogen or methyl and n is an integer from 1 to 4.Type: GrantFiled: November 25, 1974Date of Patent: February 17, 1976Assignee: Societa' Italiana Resine S.p.A.Inventors: Luciano Console, Ferdinando Bencini, Enzo Chiellini
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Patent number: 3936292Abstract: Compositions useful in agriculture as soil modifiers and fertilizers are prepared by contacting the waste materials, obtained in the manufacture of titanium dioxide from ilmenites by the sulphate process, and which consist essentially of ferrous sulphate, with oxides, hydroxides or carbonates of alkali metals or alkaline earth metals or ammonium carbonate, and then submitting the reaction product to oxidation to convert the ferrous hydroxide into ferric hydroxide. Ferric hydroxide is further converted to ferric sulphate by treatment with sulphuric acid.Type: GrantFiled: September 26, 1974Date of Patent: February 3, 1976Assignee: Societa' Italiana Resine S.p.A.Inventors: Luigi Piccolo, Benedetto Calcagno, Marcello Ghirga, Antonio Paolinelli
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Patent number: 3936507Abstract: A process for the production of 2,2-(4,4'-dihydroxydiphenyl)propane (bisphenol A) of high purity of condensation of phenol with acetone in the presence of strong acids, which comprisesPreparing an addition product of bisphenol A and phenol andSeparating the constituents of this addition product by fractional condensation of the vapours obtained by treating the addition product at high temperature and at reduced pressure for a short time.Type: GrantFiled: December 26, 1973Date of Patent: February 3, 1976Assignee: Societa' Italiana Resine S.p.A.Inventors: Ferdinando Ligorati, Vittorio Emanuele Nova, Giancarlo Aglietti
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Patent number: 3933686Abstract: A catalyst suitable for the production ofAcrylonitrile from propylene or acrolein,Acrylic acid from propylene or acrolein, andAcrolein from propyleneComprising silver oxide and molybdenum oxide in a molar ratio of from about 0.1 to about 2.0.The catalytic reactions using this new catalyst are directed towards the desired end product by variation of the molar ratio of silver oxide to molybdenum oxide.Type: GrantFiled: November 29, 1973Date of Patent: January 20, 1976Assignee: Societa' Italiana Resine S.p.A.Inventors: Natale Ferlazzo, Gian Fausto Buzzi, Marcello Ghirga
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Patent number: 3934039Abstract: Process for the production of microorganism lysates, comprising subjecting the said microorganisms suspended in water to thermal shock produced by a spray-drying treatment and then subjecting the product resulting from spray drying to autolysis.Type: GrantFiled: November 29, 1973Date of Patent: January 20, 1976Assignee: Societa' Italiana Resine S.p.A.Inventors: Giuliano Cardini, Aldo Zotti
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Patent number: 3933597Abstract: A multistage flash-evaporator for producing soft water from a saline water, comprising a shell forming a pair of lobes enclosing therebetween a spinal portion in symmetrical arrangement with respect to a vertical longitudinal mid-plane. The top and bottom walls of the spinal portion are, in cross-sectional shape, circular arcs having their centres of curvature on the said mid-plane, while the lobes are polycentric curves each of which has its centres of curvature on a plane parallel to the mid-plane. A specifically shaped hood arrangement in the shell is provided to define in each stage a condensation chamber centrally located between a pair of evaporation chambers.Type: GrantFiled: December 18, 1974Date of Patent: January 20, 1976Assignee: Societa' Italiana Resine S.p.A.Inventors: Diego Barba, Antonino Germana, Giuseppe Liuzzo, Giovanni Tagliaferri, Giancarlo Spizzichino