Abstract: The invention relates to a catalyst comprising a rare metal of Group VIII of the Periodic Table of Elements which has been deposited on an inert support and which has been used to dehalogenate .alpha.-halogenated carboxylic acids in the presence of hydrogen, and a rare metal of Group VIII of the Periodic Table of Elements which has been deposited on an inert support and which is such that the granulometry of b) is very much lower than that of a) to form a homogeneous mixture as a result of the action of currents of .alpha.-halogenated carboxylic acid and hydrogen wherein said invention is particularly useful for regenerating palladium catalyst used in the purification of crude monochloroacetic acid.
Type:
Grant
Filed:
June 24, 1994
Date of Patent:
December 12, 1995
Assignee:
Societe Elf Atochem S.A.
Inventors:
Yves Correia, Dominique Jourdain, Joseph Nowocien, Alexandre Salerno
Abstract: The invention relates to a catalyst formed of an active charcoal support in the form of particles or of cylinders having a diameter from 0.3 to 1.5 mm and a length of 0.3 to 5 mm or spheres having a diameter from 0.3 to 2 mm, the said particles being loaded with a precious metal from group 8. Advantageously, palladium on active charcoal is used.The invention is particularly useful for purifying monochloroacetic acid.
Abstract: The invention relates to a catalyst formed of an active charcoal support in the form of particles or of cylinders having a diameter from 0.3 to 1.5 mm and a length of 0.3 to 5 mm or spheres having a diameter from 0.3 to 2 mm, the said particles being loaded with a precious metal from group 8. Advantageously, palladium on active charcoal is used.The invention is particularly useful for purifying monochloroacetic acid.
Abstract: The invention relates to a catalyst comprising a rare metal of Group VIII of the Periodic Table of Elements which has been deposited on an inert support and which has been used to dehalogenate .alpha.-halogenated carboxylic acids in the presence of hydrogen, and a rare metal of Group VIII of the Periodic Table of Elements which has been deposited on an inert support and which is such that the granulometry of b) is very much lower than that of a) to form a homogeneous mixture as a result of the action of currents of .alpha.-halogenated carboxylic acid and hydrogen.It is particularly useful for regenerating palladium catalysts used in the purification of crude monochloroacetic acid.
Type:
Grant
Filed:
October 16, 1992
Date of Patent:
October 18, 1994
Assignee:
Societe Elf Atochem S.A.
Inventors:
Yves Correia, Dominique Jourdain, Joseph Nowocien, Alexandre Salerno