Abstract: Silica-based substrate surface-modified by grafting covalent links of organic polysubstituted guanidinium groups, and preferably polyakylguanidinium groups. These substrates can be obtained by reacting silica with a polyalkylguanidinium anion, the silanol residual groups of silica being optionally treated with hexamethyldisilazane to stabilize the substrates. These substrates can be used as chlorination and esterification catalysts.
Type:
Grant
Filed:
November 30, 1992
Date of Patent:
September 20, 1994
Assignee:
Societe Nationale des Poudres et Explosifs - S.N.P.E.
Inventors:
Patricia Gauthier, Philippe Gros, Pierre Le Perchec, Jean-Pierre Senet