Abstract: In accordance with the present invention, there is now provided a novel selective catalyst useful for the synthesis of methyl-tert-butyl ether (MTBE) or ethyl-tert-butyl ether (ETBE) prepared by reacting isobutene with methanol or ethanol, respectively. More specifically, the catalyst of the present invention comprises from about 0.5 to about 7% by weight of triflic acid (trifluoro-methanesulfonic acid, CF.sub.3 SO.sub.3 H, hereafter referred to as TFA) incorporated onto an acid form Y zeolite.
Abstract: In accordance with the present invention, there is now provided a hybrid catalyst suitable for the aromatization of light paraffins and olefins, comprising a mixture of a pentasil type zeolite having the structure of ZSM-5 or ZSM-11, and a cocatalyst consisting of gallium oxide supported by an oxide selected from the group consisting of silica, alumina particles and chromium oxide particles.
Abstract: The invention is concerned with a high-density adsorbent comprising a compacted mass of high surface area carbon particles bound together with a binder and defining a network of substantially unobstructed micropores, the mass of carbon particles having been compacted under a pressure sufficient to cause a reduction of about 50 to about 200% in bulk volume of the mass and a corresponding increase of about 50 to about 200% in density, thereby providing a gas storage capacity increase of about 20 to about 100% over that of the high surface area carbon particles in loose or uncompacted form. The high-density adsorbent according to the invention is particularly useful in adsorption storage systems for low-pressure storage of compressed natural gas.
Type:
Grant
Filed:
February 21, 1989
Date of Patent:
March 12, 1991
Assignees:
Universite du Quebec a Trois-Rivieres, Societe Quebecoise d'Initiatives Petrolieres, Gas Metropolitain Inc.
Inventors:
Tapan K. Bose, Richard Chahine, Jean-Marie St-Arnaud
Abstract: A method and apparatus for measuring physical adsorption of a gas by a solid adsorbent are disclosed. Use is made of a capacitance cell in controlled gas flow communication with a sample cell initially under vacuum and containing the solid adsorbent. The capacitance cell is filled with an adsorptive gas at a predetermined pressure and the dielectric constant of the gas at the predetermined pressure is measured to determine a first density value. The gas from the capacitance cell is then allowed to expand into the sample cell for adsorption by the solid adsorbent, whereby an adsorption takes place pressure falls until eqilibrium is established. The dielectric constant of the gas at equilibrium pressure is measured to determine a second density value, and the amount of gas adsorbed by the solid adsorbent is determined from the first and second density values.
Type:
Grant
Filed:
September 8, 1988
Date of Patent:
August 15, 1989
Assignee:
Universite du Quebec a Trois-Rivieres, Societe Quebecoise d'Initiatives Petrolieres and Gaz Metropolitain Inc.
Inventors:
Tapan K. Bose, Richard Chahine, Louis Marchildon, Jean-Marie St-Arnaud