Patents Assigned to Solarmer Energy, Inc.
-
Patent number: 9783634Abstract: A method of making a fluorothieno[3,4-b]thiophene derivatives and photovoltaic polymers containing same using 3-bromothiophene-2-carboxylic acid as a starting material. This synthetic route provides an easier synthesis as well as greater yield and a purer product, which produces superior results over the prior art less pure products. The resulting materials can be used in a variety of photovoltaic applications and devices, especially solar cells.Type: GrantFiled: March 6, 2015Date of Patent: October 10, 2017Assignees: SOLARMER ENERGY, INC., PHILLIPS 66 COMPANYInventors: Shuangxi Wang, Chenjun Shi, Ruby Chen, Junlian Zhang, Wei Wang, Yue Wu, Hui Huang, Amit Palkar, Ting He
-
Patent number: 9691986Abstract: Compositions, synthesis and applications for furan, thiophene and selenophene derivatized benzo[1,2-b:3,4-b?]dithiophene(BDT)-thienothiophene (BDT-TT) based polymers, namely, poly[(4,8-bis(5-(2-ethyhexyl)selenophen-2-yl)-benzo[1,2-b;4,5-b?]dithiophene)-2,6-diyl-alt-(4-(2-ethylhexanoyl)-3-fluorothieno[3,4-b]thiophene)-2-6-diyl (CS-15), poly[(4,8-bis(5-(2-ethyhexyl)selenophen-2-yl)-benzo[1,2-b;4,5-b?]dithiophene)-2,6-diyl-alt-(4-(2-ethylhexyl)-3-fluorothieno[3,4-b]thiophene)-2-carboxylate-2-6-diyl (CS-16), poly[(4,8-bis(5-(2-ethyhexyl)furan-2-yl)-benzo[1,2-b;4,5-b?]dithiophene)-2,6-diyl-alt-(4-(2-ethylhexyl)-3-fluorothieno[3,4-b]thiophene)-2-carboxylate-2-6-diyl (CS-18) and poly[(4,8-bis(5-hexylfuran-2-yl)-benzo[1,2-b;4,5-b?]dithiophene)-2,6-diyl-alt-(4-(2-ethylhexanoyl)-3-fluorothieno[3,4-b]thiophene)-2-6-diyl (CS-24) are disclosed. Further, an organic solar cell constructed of a derivatized benzo[1,2-b:3,4-b?]dithiophene(BDT)-thienothiophene (BDT-TT) based polymer is discussed.Type: GrantFiled: November 19, 2013Date of Patent: June 27, 2017Assignees: Solarmer Energy, Inc., Phillips 66 CompanyInventors: Wei Wang, Chenjun Shi, Ruby Chen, Jun Yang, Yue Wu, Hui Huang, Kathy Woody, Joe Bullock, Amit Palkar, Ting He
-
Patent number: 9214635Abstract: Compositions, synthesis and applications for benzene, furan, thiophene, selenophene, pyrole, pyran, pyridine, oxazole, thiazole and imidazole derivatized anthra[2,3-b:6,7-b?]dithiophene (ADT) based polymers, namely, poly{5,11-bis(5-(2-ethylhexyl)thiophen-2-yl)anthra[2,3-b:6,7-b?]dithiophene-2,8-diyl-alt-2-ethyl-1-(thieno[3,4-b]thiophen-2-yl)hexan-1-one-4,6-diyl}, poly{5,11-bis(5-(2-ethylhexyl)furan-2-yl)anthra[2,3-b:6,7-b?]dithiophene-2,8-diyl-alt-2-ethyl-1-(thieno[3,4-b]thiophen-2-yl)hexan-1-one-4,6-diyl and poly{5,11-bis(5-(2-ethylhexyl)selenophen-2-yl)anthra[2,3-b:6,7-b?]dithiophene-2,8-diyl-alt-2-ethyl-1-(thieno[3,4-b]thiophen-2-yl)hexan-1-one-4,6-diyl} are disclosed. Further, an organic solar cell constructed of a derivatized anthra[2,3-b:6,7-b?]dithiophene (ADT) based polymer is discussed.Type: GrantFiled: November 4, 2014Date of Patent: December 15, 2015Assignees: Phillips 66 Company, Solarmer Energy, Inc.Inventors: Chenjun Shi, Ruby Chen, Jun Yang, Christopher S. Daeffler, Janice Hawkins, Yue Wu, Wei Wang, Kathy Woody, Joe Bullock, Hui Huang, Amit Palkar, Ting He
-
Publication number: 20150344608Abstract: A polymer having two different sets of repeat units consisting essentially of: In this polymer, R1, R2, R3 and R4 can be independently selected from the group consisting of alkyl group, alkoxy group, aryl groups and combinations thereof. Also the combination of R1, R2, R3 and R4 are not all identical and n and o are greater than 1.Type: ApplicationFiled: May 27, 2015Publication date: December 3, 2015Applicants: SOLARMER ENERGY, INC., PHILLIPS 66 COMPANYInventors: Wei Wang, Jun Yang, Chenjun Shi, Christopher Daeffler, Janice Hawkins, Yue Wu, Ting He, Hui Huang, Amit Palkar, Kathy Woody, Joe Bullock
-
Publication number: 20150344630Abstract: A process of dissolving 3-fluoro-4,6-dihydrothieno[3,4-b]thiophene in a solvent to create a solution. An initiator is then added to the solution to produce an initiated solution followed by adding a fluorinated chemical to the initiated solution to produce 2,3-difluoro-4,6-dihydrothieno[3,4-b]thiophene. 2,3-difluoro-4,6-dihydrothieno[3,4-b]thiophene is then oxidized with an oxidant to produce 2,3-difluorothieno[3,4-b]thiophene. A brominating step then occurs to the 2,3-difluorothieno[3,4-b]thiophene to produce 4,6-dibromo-2,3-difluorothieno[2,3-c]thiophene. 4,6-dibromo-2,3-difluorothieno[2,3-c]thiophene is then debrominated and polymerized to The stoichiometric ratio of (f+g)?h and f, g and h are not equal to 0. Additionally, in this embodiment R1, R2, R3 and R4 are independently selected from the group consisting of alkyl group, alkoxy group, aryl groups and combinations thereof and where the combination of R1, R2, R3 and R4 are not all identical.Type: ApplicationFiled: May 27, 2015Publication date: December 3, 2015Applicants: SOLARMER ENERGY, INC., PHILLIPS 66 COMPANYInventors: Wei Wang, Jun Yang, Chenjun Shi, Christopher Daeffler, Janice Hawkins, Yue Wu, Ting He, Hui Huang, Amit Palkar, Kathy Woody, Joe Bullock
-
Publication number: 20150349260Abstract: A polymer having at least four different repeat units comprising: In this polymer R1, R2, R3 and R4 can be independently selected from the group consisting of alkyl group, alkoxy group, aryl groups and combinations thereof and where the combination of R1, R2, R3 and R4 are not all identical. Additionally, in this polymer, m, n, o and p can be greater than 1. x and y are different from each other and can be independently selected from the group consisting of: of alkyl group, alkoxy group, aryl groups, where y=1-3, where y=0-12, where R5 is selected from the group consisting of H, of alkyl group, alkoxy group, aryl groups, where R6 is selected from the group consisting of H, alkyl, substituted alkyls, aryls and substituted aryls, where R7 and R8 are independently selected from the group consisting of H, of alkyl group, alkoxy group, aryl groups, —NR9R10 where R9 and R10 are independently selected from the group consisting of H, of alkyl group, alkoxy group, aryl groups.Type: ApplicationFiled: May 27, 2015Publication date: December 3, 2015Applicants: SOLARMER ENERGY, INC., PHILLIPS 66 COMPANYInventors: Kathy Woody, Hui Huang, Ting He, Wei Wang, Chenjun Shi, Yue Wu
-
Publication number: 20150344616Abstract: A process of polymerizing wherein the stoichiometric ratio of (f+g)?(h+i) and f, g, h and i are not equal to 0. Additionally, R1, R2, R3 and R4 can be independently selected from the group consisting of alkyl group, alkoxy group, aryl groups and combinations thereof and where the combination of R1, R2, R3 and R4 are not all identical. In addition, x and y can be different from each other and independently selected from the group consisting of: alkyl group, alkoxy group, aryl groups, where y=1-3, where y=0-12, where R5 is selected from the group consisting of H, alkyl group, alkoxy group, aryl groups, where R6 is selected from the group consisting of H, alkyl group, alkoxy group, aryl groups, where R7 and R8 are independently selected from the group consisting of H, alkyl group, alkoxy group, aryl groups, —NR9R10 where R9 and R10 are independently selected from the group consisting of H, alkyl group, alkoxy group, aryl groups.Type: ApplicationFiled: May 27, 2015Publication date: December 3, 2015Applicants: SOLARMER ENERGY, INC., PHILLIPS 66 COMPANYInventors: Kathy Woody, Hui Huang, Ting He, Wei Wang, Chenjun Shi, Yue Wu
-
Publication number: 20150344495Abstract: A method of producing a monomer wherein the method begins by dissolving 3-fluoro-4,6 dihydrothieno[3,4-b]thiophene in a solvent to create a solution. An initiator is then added to the solution to produce an initiated solution. This is followed by adding a fluorinated chemical to the initiated solution to produce 2,3-difluoro-4,6-dihydrothieno[3,4-b]thiophene. 2,3-difluoro-4,6-dihydrothieno[3,4-b]thiophene is then oxidized with an oxidant to produce 2,3-difluorothieno[3,4-b]thiophene. 2,3-difluorothieno[3,4-b]thiophene is then bromoated to produce 4,6-dibromo-2,3-difluorothieno[2,3-c]thiophene.Type: ApplicationFiled: May 27, 2015Publication date: December 3, 2015Applicants: SOLARMER ENERGY, INC., PHILLIPS 66 COMPANYInventors: Wei Wang, Jun Yang, Chenjun Shi, Christopher Daeffler, Janice Hawkins, Yue Wu, Ting He, Hui Huang, Amit Palkar, Kathy Woody, Joe Bullock
-
Publication number: 20150349261Abstract: A polymer having a monomer repeat unit comprising wherein Ar is an aryl group.Type: ApplicationFiled: May 27, 2015Publication date: December 3, 2015Applicants: SOLARMER ENERGY, INC., PHILLIPS 66 COMPANYInventors: Wei Wang, Jun Yang, Chenjun Shi, Christopher Daeffler, Janice Hawkins, Yue Wu, Ting He, Hui Huang, Amit Palkar, Kathy Woody, Joe Bullock
-
Publication number: 20150210800Abstract: A method of making a fluorothieno[3,4-b]thiophene derivatives and photovoltaic polymers containing same using 3-bromothiophene-2-carboxylic acid as a starting material. This synthetic route provides an easier synthesis as well as greater yield and a purer product, which produces superior results over the prior art less pure products. The resulting materials can be used in a variety of photovoltaic applications and devices, especially solar cells.Type: ApplicationFiled: March 6, 2015Publication date: July 30, 2015Applicants: Phillips 66 Company, Solarmer Energy, Inc.Inventors: Shuangxi Wang, Chenjun Shi, Ruby Chen, Junlian Zhang, Wei Wang, Yue Wu, Hui Huang, Amit Palkar, Ting He
-
Publication number: 20150136224Abstract: Compositions, synthesis and applications for benzene, furan, thiophene, selenophene, pyrole, pyran, pyridine, oxazole, thiazole and imidazole derivatized anthra[2,3-b:6,7-b?]dithiophene (ADT) based polymers, namely, poly{5,11-bis(5-(2-ethylhexyl)thiophen-2-yl)anthra[2,3-b:6,7-b?]dithiophene-2,8-diyl-alt-2-ethyl-1-(thieno[3,4-b]thiophen-2-yl)hexan-1-one-4,6-diyl}, poly{5,11-bis(5-(2-ethylhexyl)furan-2-yl)anthra[2,3-b:6,7-b?]dithiophene-2,8-diyl-alt-2-ethyl-1-(thieno[3,4-b]thiophen-2-yl)hexan-1-one-4,6-diyl and poly{5,11-bis(5-(2-ethylhexyl)selenophen-2-yl)anthra[2,3-b:6,7-b?]dithiophene-2,8-diyl-alt-2-ethyl-1-(thieno[3,4-b]thiophen-2-yl)hexan-1-one-4,6-diyl} are disclosed. Further, an organic solar cell constructed of a derivatized anthra[2,3-b:6,7-b?]dithiophene (ADT) based polymer is discussed.Type: ApplicationFiled: November 4, 2014Publication date: May 21, 2015Applicants: Phillips 66 Company, Solarmer Energy, Inc.Inventors: Chenjun Shi, Ruby Chen, Jun Yang, Christopher S. Daeffler, Janice Hawkins, Yue Wu, Wei Wang, Kathy Woody, Joe Bullock, Hui Huang, Amit Palkar, Ting He
-
Patent number: 9006568Abstract: A method of making a fluorothieno[3,4-b]thiophene derivatives and photovoltaic polymers containing same using 3-bromothiophene-2-carboxylic acid as a starting material. This synthetic route provides an easier synthesis as well as greater yield and a purer product, which produces superior results over the prior art less pure products. The resulting materials can be used in a variety of photovoltaic applications and devices, especially solar cells.Type: GrantFiled: February 12, 2013Date of Patent: April 14, 2015Assignees: Phillips 66 Company, Solarmer Energy, Inc.Inventors: Shuangxi Wang, Chenjun Shi, Ruby Chen, Junlian Zhang, Hui Huang, Yue Wu, Wei Wang, Amit Palkar, Ting He
-
Publication number: 20140151657Abstract: Compositions, synthesis and applications for furan, thiophene and selenophene derivatized benzo[1,2-b:3,4-b?]dithiophene(BDT)-thienothiophene (BDT-TT) based polymers, namely, poly[(4,8-bis(5-(2-ethyhexyl)selenophen-2-yl)-benzo[1,2-b;4,5-b?]dithiophene)-2,6-diyl-alt-(4-(2-ethylhexanoyl)-3-fluorothieno[3,4-b]thiophene)-2-6-diyl (CS-15), poly[(4,8-bis(5-(2-ethyhexyl)selenophen-2-yl)-benzo[1,2-b;4,5-b?]dithiophene)-2,6-diyl-alt-(4-(2-ethylhexyl)-3-fluorothieno[3,4-b]thiophene)-2-carboxylate-2-6-diyl (CS-16), poly[(4,8-bis(5-(2-ethyhexyl)furan-2-yl)-benzo[1,2-b;4,5-b?]dithiophene)-2,6-diyl-alt-(4-(2-ethylhexyl)-3-fluorothieno[3,4-b]thiophene)-2-carboxylate-2-6-diyl (CS-18) and poly[(4,8-bis(5-hexylfuran-2-yl)-benzo[1,2-b;4,5-b?]dithiophene)-2,6-diyl-alt-(4-(2-ethylhexanoyl)-3-fluorothieno[3,4-b]thiophene)-2-6-diyl (CS-24) are disclosed. Further, an organic solar cell constructed of a derivatized benzo[1,2-b:3,4-b?]dithiophene(BDT)-thienothiophene (BDT-TT) based polymer is discussed.Type: ApplicationFiled: November 19, 2013Publication date: June 5, 2014Applicants: SOLARMER ENERGY, INC., PHILLIPS 66 COMPANYInventors: Wei Wang, Chenjun Shi, Ruby Chen, Jun Yang, Yue Wu, Hui Huang, Kathy Woody, Joe Bullock, Amit Palkar, Ting He
-
Patent number: 8697833Abstract: In one embodiment of the present disclosure, a series of conjugated polymers used, among other things, as polymer solar cell or polymer photovoltaic device active layer materials, is provided. In one embodiment, the conjugated polymers have the general structure and formula shown in (I), wherein: R1 and R2 are independently selected from proton, halogens, alkyls, aryls and substituted aryls; Ar is selected from the group consisting of monocyclic, bicyclic and polycyclic arylene, or monocyclic, bicyclic and polycyclic heteroarylene. In another embodiment, the conjugated photovoltaic polymers are comprised of repeated units having the general structure of formula (II), wherein, R1, R2, R3, R4, R5, and R6 are independently selected from proton, alkyls, halogens, aryls, substituted aryls, and other kinds of substituents.Type: GrantFiled: January 7, 2013Date of Patent: April 15, 2014Assignee: Solarmer Energy, Inc.Inventors: Jianhui Hou, Shaoqing Zhang
-
Publication number: 20130214213Abstract: A method of making a fluorothieno[3,4-b]thiophene derivatives and photovoltaic polymers containing same using 3-bromothiophene-2-carboxylic acid as a starting material. This synthetic route provides an easier synthesis as well as greater yield and a purer product, which produces superior results over the prior art less pure products. The resulting materials can be used in a variety of photovoltaic applications and devices, especially solar cells.Type: ApplicationFiled: February 12, 2013Publication date: August 22, 2013Applicants: Solarmer Energy, Inc., Phillips 66 CompanyInventors: Shuangxi Wang, Chenjun Shi, Ruby Chen, Junlian Zhang, Hui Huang, Yue Wu, Wei Wang, Amit Palkar, Ting He
-
Publication number: 20130123449Abstract: In one embodiment of the present disclosure, a series of conjugated polymers used, among other things, as polymer solar cell or polymer photovoltaic device active layer materials, is provided. In one embodiment, the conjugated polymers have the general structure and formula shown in (I), wherein: R1 and R2 are independently selected from proton, halogens, alkyls, aryls and substituted aryls; Ar is selected from the group consisting of monocyclic, bicyclic and polycyclic arylene, or monocyclic, bicyclic and polycyclic heteroarylene. In another embodiment, the conjugated photovoltaic polymers are comprised of repeated units having the general structure of formula (II), wherein, R1, R2, R3, R4, R5, and R6 are independently selected from proton, alkyls, halogens, aryls, substituted aryls, and other kinds of substituents.Type: ApplicationFiled: January 7, 2013Publication date: May 16, 2013Applicant: SOLARMER ENERGY, INC.Inventor: Solarmer Energy, Inc.
-
Patent number: 8440496Abstract: Conductive material grids or lines embedded or partially embedded in a transparent substrate of a solar cell. The grids or lines can have a higher conductivity than the anode or they can have the same conductivity. The grids or lines increase the volume of the anode and, thus decrease sheet resistance of the same.Type: GrantFiled: July 8, 2009Date of Patent: May 14, 2013Assignee: Solarmer Energy, Inc.Inventors: Casey Scott Irvin, Vishal Shrotriya, Yue Wu
-
Patent number: 8399889Abstract: This disclosure relates to an organic solar cell and an organic light emitting diode stack. The stack comprises a solar cell portion having a substrate, an electrode, an active layer, and a second electrode. The stack also comprises a light emitting diode portion having a substrate, an electrode, an active layer, and a second electrode. The solar cell portion is laminated to the light emitting diode portion to form a stack. In a variation, the stack comprises a solar cell portion that includes a substrate, an electrode and an active layer. In this variation, there is a connection portion that includes a second substrate, having, a second electrode on one side and a third electrode on the other side of the second substrate. Also in this variation, there is also a light emitting diode portion, which includes a third substrate, an electrode on the third substrate and a second active layer.Type: GrantFiled: November 9, 2009Date of Patent: March 19, 2013Assignee: Solarmer Energy, Inc.Inventors: Yue Wu, Travis Currier, Yuyi Li, Szu-Ting Tsai
-
Patent number: 8372945Abstract: In one embodiment of the present disclosure, a series of conjugated polymers used, among other things, as polymer solar cell or polymer photovoltaic device active layer materials, is provided. In one embodiment, the conjugated polymers have the general structure and formula shown in (I), wherein: R1 and R2 are independently selected from proton, halogens, alkyls, aryls and substituted aryls; Ar is selected from the group consisting of monocyclic, bicyclic and polycyclic arylene, or monocyclic, bicyclic and polycyclic heteroarylene. In another embodiment, the conjugated photovoltaic polymers are comprised of repeated units having the general structure of formula (II), wherein, R1, R2, R3, R4, R5, and R6 are independently selected from proton, alkyls, halogens, aryls, substituted aryls, and other kinds of substituents.Type: GrantFiled: July 24, 2009Date of Patent: February 12, 2013Assignee: Solarmer Energy, Inc.Inventors: Jianhui Hou, Shaoqing Zhang
-
Publication number: 20110108856Abstract: This disclosure relates to an organic solar cell and an organic light emitting diode stack. The stack comprises a solar cell portion having a substrate, an electrode, an active layer, and a second electrode. The stack also comprises a light emitting diode portion having a substrate, an electrode, an active layer, and a second electrode. The solar cell portion is laminated to the light emitting diode portion to form a stack. In a variation, the stack comprises a solar cell portion that includes a substrate, an electrode and an active layer. In this variation, there is a connection portion that includes a second substrate, having a second electrode on one side and a third electrode on the other side of the second substrate. Also in this variation, there is also a light emitting diode portion, which includes a third substrate, an electrode on the third substrate and a second active layer.Type: ApplicationFiled: November 9, 2009Publication date: May 12, 2011Applicant: SOLARMER ENERGY, INC.Inventors: Yue Wu, Travis Currier, Yuyi Li, Szu-Ting Tsai