Abstract: Coating composition especially for preparing automotive surfacers, comprising a condensation product A of a carboxyl group-containing resin A1 and a hydroxyl group-containing resin A2, a curing agent C which becomes active only at an elevated temperature of at least 80° C., with the proviso that at least 20% of the mass of the curing agent C is insoluble in water, and a low molar mass polyester B having a hydroxyl number of from 100 to 450 mg/g and a Staudinger Index of from 2.5 to 6 cm3/g, obtainable by condensing aliphatic polyols B1 and aliphatic, cycloaliphatic or aromatic polycarboxylic acids B2, the average functionality (number of the hydroxyl groups and/or acid groups per molecule) of component B1 being greater by at least 0.2 than that of component B2.
Abstract: Water dilutable binder for soft feel coating materials, comprising an aqueous dispersion of a hydroxyl-containing polyester-urethane A, preparable by reacting a polyester A1 with hydroxyl groups as functional groups, formed from difunctional or polyfunctional carboxylic acids A11 and difunctional or polyfunctional alcohols A12, with a polyfunctional isocyanate A2, with a compound A3 having at least one isocyanate-reactive group and at least one acid group, an aqueous solution or dispersion of a triazine resin B, wherein the glass transition temperature of the polyester-urethane A is between −70 and −20° C. and wherein the hydroxyl number of the polyester-urethane A is from 10 to 120 mg/g, a process for its preparation, and its use in soft feel coating materials for plastics, metals, glass, wood, textiles, and leather.
Type:
Grant
Filed:
September 22, 2000
Date of Patent:
July 2, 2002
Assignee:
Solutia Austria GmbH
Inventors:
Markus A. Schafheutle, Anton Arzt, Julius Burkl, Martina Glettler, Ursula Meisner, Gerlinde Petritsch, Joerg Wango
Abstract: Oxidatively drying aqueous polyurethane dispersions obtainable by reacting drying and/or simidrying oils with low molar mass hydroxy compounds having two or more hydroxyl groups to give compounds containing on average at least one hydroxyl group and at least one radical of a fatty acid having at least one olefinic double bond, then reacting these compounds together with high molar mass polyols, compounds having at least two isocyanate-reactive groups and at least one acid or cation-forming group with polyfunctional isocyanates to give prepolymers having a mass fraction of unreacted isocyanate groups of from 0.1 to 4%, then neutralizing the product and transferring the utilized product to the aqueous phase, a process for preparing them and their use for coating wood.
Type:
Grant
Filed:
February 2, 2000
Date of Patent:
March 19, 2002
Assignee:
Solutia Austria GmbH
Inventors:
Markus A. Schafheutle, Rami-Raimund Awad, Hannelore Gsoell, Birgit Anner, Anton Arzt, Martina Glettler, Andreas Lerch, Gerlinde Petritsch, Joerg Wango
Abstract: Aqueous binders for soft feel materials, comprising predominantly aliphatic, water-soluble or water-dispersible polymers A having terminal or lateral cyclic carbonate groups and an amine B having at least two primary amino groups, the ratio of the number of primary amino groups in the component B to the number of cyclic carbonate groups in the component A being from 7:3 to 3:7.
Type:
Grant
Filed:
January 14, 2000
Date of Patent:
April 3, 2001
Assignee:
Solutia Austria GmbH
Inventors:
Markus A. Schafheutle, Martin Gerlitz, Anton Arzt, Julius Burkl, Joerg Wango, Martina Glettler
Abstract: Mixtures of low molar mass polyester polyols having a weight-average molar mass Mw of not more than 2000 g/mol, with hydroxyl numbers of from 80 to 300 mg/g and acid numbers of from 5 to 35 mg/g, comprising structural units derived from aliphatic polycyclic polyhydroxy compounds having at least two hydroxyl groups per molecule, branched aliphatic acyclic dihydroxy compounds, aliphatic cyclic polycarboxylic acids, aliphatic acyclic or monocyclic polyhydroxy compounds having three or more hydroxyl groups per molecule, and polyfunctional compounds selected from aliphatic linear and monocyclic dihydroxy compounds, aliphatic linear and branched dicarboxylic acids, aromatic dicarboxylic acids and polycarboxylic acids having three or more carboxyl groups per molecule, and also monofunctional units selected from monocarboxylic acids and monoalcohols, and acrylic copolymers made by radically initiated polymerisation in the presence of cyclic compounds that can react with hydroxy or acid functional comonomers can be us