Abstract: The present invention relates to a fluorosurfactant-free emulsion polymerization method for the synthesis of a fluoropolymer, more in particular of a VDF-based polymer.

Abstract: The invention pertains to a method of making fluoropolymer dispersions using certain polyfunctional perfluoropolyether derivatives including a plurality of ionisable groups selected from the group consisting of —SO.sub.3X.sub.a, —PO.sub.3X.sub.a and —COOX.sub.a, whereas X.sub.a is H, an ammonium group or a monovalent metal, and whereas said groups are comprised as pendant groups in the perfluoropolyether chain, and to fluoropolymer dispersions therefrom.

Abstract: The invention pertains to a perfluoroelastomer composition comprising: at least one perfluoroelastomer comprising iodine and/or bromine atoms [perfluoroelastomer (A)]; from 0.5 to 5 weight parts, per 100 parts by weight of said perfluoroelastomer (A), of at least one bis-olefin [bis-olefin (OF)] having general formula (1) wherein R1, R2, R3, R4, R5 and R6, equal or different from each other, are H, a halogen, or a C1-C5 optionally halogenated group, possibly comprising one or more oxygen group; Z is a linear or branched C1-C18 optionally halogenated alkylene or cycloalkylene radical, optionally containing oxygen atoms, or a (per)fluoropolyoxyalkylene radical; from 0.1 to 3 weight parts, per 100 parts by weight of said perfluoroelastomer (A), of at least one organic peroxide; from 0.

Abstract: The invention pertains to a composition (C1) comprising: at least one (meth)acrylic modified VDF polymer [polymer (A)] comprising recurring units derived from comprising recurring units derived from vinylidene fluoride (VDF) monomer and at least one hydrophilic (meth)acrylic monomer (MA) of formula (I), wherein each of R1, R2, R3, equal or different from each other, is independently a hydrogen atom or a C1-C3 hydrocarbon group, and ROH is a hydrogen or a C1-C5 hydrocarbon moiety comprising at least one hydroxyl group; at least one inorganic UV blocker compound in an amount not exceeding 5% wt, with respect to the weight of polymer (A), to multilayer assemblies comprising one layer made from said composition (C1), to a method for manufacturing said multilayer assemblies and to the use of the same in different field of use, including protection of PV modules.

Abstract: The invention pertains to a fluoropolymer composition comprising certain tetrafluoroethylene/perfluoromethyvinylether copolymers having well-defined TFE/MVE monomer composition and possessing low molecular weight and a white pigment, to the use of this latter for manufacturing shaped articles, and to shaped articles therefrom, including components of light emitting apparatuses, e.g. LED assemblies.

Abstract: The present invention relates to a novel process for the synthesis of (per)fluoropolyether polymers, to certain novel (per)fluoropolyether polymers. The present invention also relates to the use of the (per)fluoropolyether polymers thus obtained as intermediate compounds for the manufacture of further polymers suitable for use as lubricants, notably for magnetic recording media (MRM).

Abstract: The present invention pertains to a process for manufacturing a semi-crystalline fluoropolymer, to the fluoropolymer obtainable by said process and to uses of said fluoropolymer in various applications.

Abstract: The present invention relates to a polymer alloy comprising a sulphur-containing aromatic polymer and at least one fluoropolymer, which has improved dispersibility and improved mechanical properties. The invention also relates to a process for the preparation of said polymer alloy and to an article comprising the same.

Abstract: The invention pertains to a method of making fluoropolymer dispersions using certain polyfunctional perfluoropolyether derivatives including a plurality of ionisable groups selected from the group consisting of —SO3Xa, —PO3Xa and —COOXa, whereas Xa is H, an ammonium group or a monovalent metal, and whereas said groups are comprised as pendant groups in the perfluoropolyether chain, and to fluoropolymer dispersions therefrom.

Abstract: The present invention pertains to a multilayer assembly, to a process for the manufacture of said multilayer assembly, to a pipe comprising said multilayer assembly and to uses of said pipe in various applications.

Abstract: The invention pertains to a fluoropolymer composition comprising: —at least one polymer comprising recurring units derived from ethylene (E) and from chlorotrifluoroethylene (CTFE) [ECTFE polymer]; —at least one water-soluble polyelectrolyte [polyelectrolyte (E)]; and—at least one antioxidant compound [compound (P)], said composition having improved thermal resistance.

Abstract: The invention pertains to a multilayer assembly comprising: (L1) a first inner layer [layer (L1)] made from a first composition [composition (C1)], said composition (C1) comprising: at least one polymer comprising recurring units derived from ethylene (E) and from chlorotrifluoroethylene (CTFE), and at least one Ti compound; and (L2) a second outer layer [layer (L2)] made from a second composition [composition (C2)], said composition (C2) being substantially free from TiO2-containing additives, said second composition comprising at least one semi-crystalline polymer comprising recurring units derived from ethylene and from at least one fluoromonomer selected from chlorotrifluoroethylene (CTFE), tetrafluoroethylene (TFE) and mixtures thereof, said semi-crystalline polymer having a heat of fusion of at least 35 J/g [polymer (A)].

Abstract: The present invention relates to a novel liquid electrolyte to be used in lithium batteries, said electrolyte comprising a lithium salt and a (per)fluoropolyether (PFPE) polymer.

Abstract: The present invention pertains to a ferroelectric fluoropolymer, to a process for manufacturing said fluoropolymer and to uses of said fluoropolymer in electric and/or electronic applications.

Abstract: Described here are blocky PEEK copolymers and corresponding synthesis methods. It was surprisingly found that synthesis of blocky PEEK copolymers in a non-solvent environment with respect to PEEK produced blocky PEEK copolymers with high degrees of functionalization and crystallinity. The blocky PEEK copolymers had an increased blocky structure, relative to corresponding PEEK copolymer synthesized with other known methods. Moreover, membranes formed from the blocky PEEK polymers are particularly desirable in fuel cell applications. For example, the membranes formed from the blocky PEEK polymers had surprisingly large ion conductivities as well as significantly improved chemical and thermal resistance, at least in part, to the improved functionalization and crystallinity.

Abstract: The present invention pertains to a vinylidene fluoride polymer, to a process for manufacturing said vinylidene fluoride polymer and to an article comprising said vinylidene fluoride polymer.

Abstract: The present invention relates to new fluorinated thermoplastic elastomer compositions comprising a continuous thermoplastic fluorocarbon polymer phase and a dispersed vulcanized fluorine-containing elastomer phase having improved thermal processability.

Abstract: The invention pertains to certain perfluorinated thermoplastic elastomers suitable for being processed through additive manufacturing techniques, thanks to their surprising ability to possess better processability (notably more significant shear thinning at processability temperature) than corresponding perfluorinated thermoplasts, which possess similar product profile and hence performances, offering hence advantages in throughput and part design accurate control, containment of degradation, reduction of fumes, and yet delivering parts with outstanding chemical resistance.

Abstract: The present invention pertains to a cable comprising: —at least one conductor coated by an insulation coating layer, —a first protective layer surrounding said insulation coating layer, said first protective layer at least comprising, but preferably being made of a tetrafluoroethylene (TFE) copolymer comprising from 0.8% to 2.5% by weight of recurring units derived from at least one perfluorinated alkyl vinyl ether having formula (I) here below: CF2?CF—O—Rf, wherein Rf is a linear or branched C3-C5 perfluorinated alkyl group or a linear or branched C3-C12 perfluorinated alkyl group comprising one or more ether oxygen atoms, said TFE copolymer having a melt flow index comprised between 1.0 and 6.0 g/10 min, as measured according to ASTM D1238 at 372° C. under a load of 5 Kg [polymer (F)]; —optionally, a second protective layer surrounding said first protective layer, and —an armor shell surrounding said first or second protective layer. The invention also pertains to use of the cable in downhole wells.

Abstract: The invention pertains to a (per)fluoroelastomer composition comprising at least one (per)fluoroelastomer comprising iodine and/or bromine atoms, at least one polyunsaturated compound, at least one organic peroxide and at least one organic compound selected from the group consisting of (thio)urea compounds, cyclic addition products of ammonia or primary amine and aldehyde; (thio)carbamates.