Patents Assigned to Solvay USA, Inc.
  • Publication number: 20240101721
    Abstract: Described herein are hydrophobically-modified polysaccharides, their manufacture, and their use in microencapsulation, typically of water-insoluble active materials.
    Type: Application
    Filed: October 8, 2020
    Publication date: March 28, 2024
    Applicants: RHODIA OPERATIONS, SOLVAY USA INC.
    Inventors: Ahmed Alsayed, Manasi Chawathe, Celine Anna Simone Burel, Denis Bendejacq
  • Publication number: 20230017258
    Abstract: A polymer dispersion includes a water-soluble copolymer prepared by controlled radical polymerization; a water soluble salt; a polyol; a salt selected from the group consisting of sodium citrate, sodium phosphate, sodium nitrate, and combinations thereof; and water. Methods for using the polymer dispersion for oilfield friction reduction occur under a variety of adverse conditions including low temperatures, salt, scale, and iron.
    Type: Application
    Filed: September 12, 2022
    Publication date: January 19, 2023
    Applicant: SOLVAY USA INC.
    Inventors: Qing Wang, Genyao Lin, Zhihua Zhang, Fulya Sudur Zalluhoglu
  • Patent number: 11441066
    Abstract: A polymer dispersion includes a water-soluble copolymer prepared by controlled radical polymerization; a water soluble salt; a polyol; a salt selected from the group consisting of sodium citrate, sodium phosphate, sodium nitrate, and combinations thereof; and water. Methods for using the polymer dispersion for oilfield friction reduction occur under a variety of adverse conditions including low temperatures, salt, scale, and iron.
    Type: Grant
    Filed: November 17, 2020
    Date of Patent: September 13, 2022
    Assignee: SOLVAY USA INC.
    Inventors: Qing Wang, Genyao Lin, Zhihua Zhang, Fulya Sudur Zalluhoglu
  • Patent number: 11377588
    Abstract: A well treatment fluid composition that includes a tetrakis(hydroxyorgano)phosphonium salt and 1,3-dimethylol-5,5-dimethylhydantoin. Methods for preparing a well treatment fluid composition and treating a subterranean formation are also presented.
    Type: Grant
    Filed: March 1, 2021
    Date of Patent: July 5, 2022
    Assignee: SOLVAY USA INC.
    Inventors: Christopher Raymond Jones, Stephanie Edmunds, Jean C. Molina
  • Patent number: 11261361
    Abstract: A friction reducing treatment solution that includes water, from 100 to 500,000 ppm of total dissolved solids, and from 0.5 to 3 gallons per thousand gallons of a water-in-oil emulsion containing a water soluble polymer. The total dissolved solids include at least 10 weight percent of a multivalent cation. The water-in-oil emulsion includes an oil phase and an aqueous phase, where the oil phase is a continuous phase containing an inert hydrophobic liquid and the aqueous phase is present as dispersed distinct particles in the oil phase and contains water, the water soluble polymer, and surfactants and an inverting surfactant. The water soluble polymer is made up of 30 to 60 weight percent of a non-ionic monomer, 5 to 50 weight percent of a sulfonic acid containing monomer, and 10 to 60 weight percent of a cationic monomer and makes up from 5 to 40 weight percent of the water-in-oil emulsion.
    Type: Grant
    Filed: July 29, 2019
    Date of Patent: March 1, 2022
    Assignee: SOLVAY USA INC.
    Inventors: Kevin Frederick, Shih-Ruey Chen, Randy Loeffler
  • Patent number: 11234377
    Abstract: Pesticide compositions containing an adjuvant which contains, based on 100 parts by weight of the adjuvant, (a) greater than about 50 parts by weight of at least one alkyl fatty acid ester, (b) from about 2 parts by weight to less than about 5 parts by weight of a surfactant comprising: (b)(i) one or more anionic surfactants selected from sulfonic acids, sulfonic acid esters, alkylsulfosuccinic acid esters, phosphate esters, sulfate esters, and oleoyltaurate salts, or (b)(ii) one or more non-ionic surfactants selected from sorbitan fatty acid esters, aryl alkoxylates, alkoxylated fatty alcohols, alkoxylated fatty acids, alkoxylated triglycerides, alkoxy copolymers, alkylpolyglucosides, alkoxylated fatty amines, and ether amines, or (iii) a mixture (b)(i) and (b)(ii), exhibit improved performance, particularly when sprayed through a flat fan spray nozzle, an air induction spray nozzle, or other spray nozzle and at a pressure of from about 10 pounds per square inch to about 100 pounds per square inch.
    Type: Grant
    Filed: July 1, 2019
    Date of Patent: February 1, 2022
    Assignee: SOLVAY USA INC.
    Inventors: Hedieh Modaressi, Joe V. Gednalske, Rajesh Pazhianur, Andrew Douglass, Gregory K. Dahl
  • Publication number: 20220017808
    Abstract: A water-in-oil emulsion having an oil phase (O) and an aqueous phase (A) at an O/A ratio of from about 1:8 to about 10:1; wherein the water-in-oil emulsion includes the oil phase as a continuous phase that includes an inert hydrophobic liquid, and the aqueous phase as a dispersed phase of distinct particles in the oil phase that includes water, a water soluble polymer, and at least one surfactant; wherein the water soluble polymer includes from about 1 to about 60 weight percent of one or more cationic monomers, wherein the amount is by total weight of the water soluble polymer; wherein the water soluble polymer is present in an amount from about 5 to about 40 weight percent of the water-in-oil emulsion; and wherein an aqueous solution prepared by inverting the water-in-oil emulsion by adding it to water has at least comparable viscosity build to an aqueous solution made from a water-in-oil emulsion of the same composition containing 15 weight percent more water soluble polymer.
    Type: Application
    Filed: September 30, 2021
    Publication date: January 20, 2022
    Applicant: SOLVAY USA INC.
    Inventors: Kailas Sawant, Louis Villafane, Kevin Frederick, Shih-Ruey Chen, Randy Loeffler
  • Patent number: 11162011
    Abstract: A water-in-oil emulsion having an oil phase (O) and an aqueous phase (A) at an O/A ratio of from about 1:8 to about 10:1; wherein the water-in-oil emulsion includes the oil phase as a continuous phase that includes an inert hydrophobic liquid, and the aqueous phase as a dispersed phase of distinct particles in the oil phase that includes water, a water soluble polymer, and at least one surfactant; wherein the water soluble polymer includes from about 1 to about 60 weight percent of one or more cationic monomers, wherein the amount is by total weight of the water soluble polymer; wherein the water soluble polymer is present in an amount from about 5 to about 40 weight percent of the water-in-oil emulsion; and wherein an aqueous solution prepared by inverting the water-in-oil emulsion by adding it to water has at least comparable viscosity build to an aqueous solution made from a water-in-oil emulsion of the same composition containing 15 weight percent more water soluble polymer.
    Type: Grant
    Filed: August 25, 2016
    Date of Patent: November 2, 2021
    Assignee: SOLVAY USA INC.
    Inventors: Kailas Sawant, Louis Villafane, Kevin Frederick, Shih-Ruey Chen, Randy Loeffler
  • Publication number: 20210179927
    Abstract: A well treatment fluid composition that includes a tetrakis(hydroxyorgano)phosphonium salt and 1,3-dimethylol-5,5-dimethylhydantoin. Methods for preparing a well treatment fluid composition and treating a subterranean formation are also presented.
    Type: Application
    Filed: March 1, 2021
    Publication date: June 17, 2021
    Applicant: SOLVAY USA INC.
    Inventors: Christopher Raymond Jones, Stephanie Edmunds, Jean C. Molina
  • Publication number: 20210163816
    Abstract: The present invention relates to a polymer dispersion prepared by controlled radical polymerization. The present invention also relates to methods for using the polymer dispersion for oilfield friction reduction under a variety of adverse conditions.
    Type: Application
    Filed: November 17, 2020
    Publication date: June 3, 2021
    Applicant: SOLVAY USA INC.
    Inventors: Qing WANG, Genyao LIN, Zhihua ZHANG, Fulya Sudur ZALLUHOGLU
  • Patent number: 10968384
    Abstract: A well treatment fluid composition that includes a tetrakis(hydroxyorgano)phosphonium salt and 1,3-dimethylol-5,5-dimethylhydantoin. Methods for preparing a well treatment fluid composition and treating a subterranean formation are also presented.
    Type: Grant
    Filed: December 6, 2016
    Date of Patent: April 6, 2021
    Assignee: SOLVAY USA INC.
    Inventors: Christopher Raymond Jones, Stéphanie Edmunds, Jean C. Molina
  • Publication number: 20200399529
    Abstract: A water-in-oil emulsion that includes an oil phase (O) and an aqueous phase (A) at an O/A ratio of from about 1:8 to about 10:1; wherein the water-in-oil emulsion includes the oil phase as a continuous phase that includes an inert hydrophobic liquid, at least one water-insoluble hydrophobic monomer, and at least one surfactant, and the aqueous phase as a dispersed phase of distinct particles in the oil phase that includes water and a water soluble polymer that includes: (i) at least one acrylamide monomer and (ii) at least one acrylic acid monomer; wherein the water soluble polymer is present in an amount from about 10 to about 35 weight percent of the water-in-oil emulsion.
    Type: Application
    Filed: August 31, 2020
    Publication date: December 24, 2020
    Applicant: Solvay USA Inc.
    Inventors: Genyao LIN, Louis VILLAFANE, Kailas SAWANT, Shih-Ruey CHEN, Kevin FREDERICK
  • Patent number: 10836954
    Abstract: A well treatment fluid composition that includes a tetrakis(hydroxyorgano)phosphonium salt and at least one oxidizing viscosity breaker. Methods for preparing a microbial viscosity breaker composition and treating a subterranean formation are also presented.
    Type: Grant
    Filed: June 30, 2016
    Date of Patent: November 17, 2020
    Assignee: Solvay USA Inc.
    Inventors: Chris Jones, Jean Molina, Francis Smith, Henry Wiggins, Dru Bishop
  • Patent number: 10808166
    Abstract: A composition and method for treating a fracturing fluid comprising produced water with high levels of dissolved solids using a polymer crosslinked with a boron compound and a high pH alkylamine buffer. The composition improves the viscosity stability of the fracturing fluid at elevated bottom-hole temperatures, particularly when the fluid has high levels of calcium and magnesium. The composition is particularly useful with polysaccharides, including galactomannan gums, such as guar gum, locust bean gum, and karaya gum, and allows for the use of the preferred boron compound crosslinkers in high total dissolved solids fracturing fluids without the pH destabilization problems encountered with the prior art.
    Type: Grant
    Filed: August 11, 2016
    Date of Patent: October 20, 2020
    Assignee: SOLVAY USA INC.
    Inventors: Tyler Heath Nelson, Stephen Anthony Glover, Enrique Lopez
  • Patent number: 10711173
    Abstract: A friction reducing treatment solution that includes water, from 100 to 500,000 ppm of total dissolved solids, and from 0.5 to 3 gallons per thousand gallons of a water-in-oil emulsion containing a water soluble polymer. The total dissolved solids include at least 10 weight percent of a multivalent cation. The water-in-oil emulsion includes an oil phase and an aqueous phase, where the oil phase is a continuous phase containing an inert hydrophobic liquid and the aqueous phase is present as dispersed distinct particles in the oil phase and contains water, the water soluble polymer, and surfactants and an inverting surfactant. The water soluble polymer is made up of 30 to 60 weight percent of a non-ionic monomer, 0.5 to 25 weight percent of a carboxylic acid containing monomer, 0 to 10 weight percent of a sulfonic acid containing monomer, and 10 to 60 weight percent of a cationic monomer and makes up from 10 to 35 weight percent of the water-in-oil emulsion.
    Type: Grant
    Filed: November 21, 2017
    Date of Patent: July 14, 2020
    Assignee: SOLVAY USA INC.
    Inventors: Kevin Frederick, Shih-Ruey Chen, Randy Loeffler, Kailas Sawant
  • Patent number: 10584277
    Abstract: A method of treating a portion of a subterranean formation that includes: providing a water-in-oil emulsion, inverting the water-in-oil emulsion to form a friction reducing treatment solution, and introducing the treatment solution into the portion of the subterranean formation. The water-in-oil emulsion has an oil phase, an aqueous phase and surfactants. The oil phase (O) and an aqueous phase (A) are present at an O/A ratio of from about 1:8 to about 10:1. The oil phase is present as a continuous phase and contains an inert hydrophobic liquid. The aqueous phase is present as a dispersed phase of distinct particles in the oil phase and includes water and a water soluble polymer. The water soluble polymer makes up from 10 to 25 weight percent of the water-in-oil emulsion. The water-in-oil emulsion is inverted by adding it to water to form a friction reducing treatment solution.
    Type: Grant
    Filed: February 3, 2014
    Date of Patent: March 10, 2020
    Assignee: SOLVAY USA INC.
    Inventors: Kevin W Frederick, Shih-Ruey T Chen
  • Publication number: 20200032134
    Abstract: A method of treating a portion of a subterranean formation that includes: providing a water-in-oil emulsion, inverting the water-in-oil emulsion to form a friction reducing treatment solution, and introducing the treatment solution into the portion of the subterranean formation. The water-in-oil emulsion has an oil phase, an aqueous phase and surfactants. The oil phase (O) and an aqueous phase (A) are present at an O/A ratio of from about 1:8 to about 10:1. The oil phase is present as a continuous phase and contains an inert hydrophobic liquid. The aqueous phase is present as a dispersed phase of distinct particles in the oil phase and includes water and a water soluble polymer. The water soluble polymer makes up from 10 to 25 weight percent of the water-in-oil emulsion. The water-in-oil emulsion is inverted by adding it to water to form a friction reducing treatment solution.
    Type: Application
    Filed: October 1, 2019
    Publication date: January 30, 2020
    Applicant: SOLVAY USA INC.
    Inventors: Kevin W. Frederick, Shih-Reuy T. Chen
  • Publication number: 20200024497
    Abstract: A friction reducing treatment solution that includes water, from 100 to 500,000 ppm of total dissolved solids, and from 0.5 to 3 gallons per thousand gallons of a water-in-oil emulsion containing a water soluble polymer. The total dissolved solids include at least 10 weight percent of a multivalent cation. The water-in-oil emulsion includes an oil phase and an aqueous phase, where the oil phase is a continuous phase containing an inert hydrophobic liquid and the aqueous phase is present as dispersed distinct particles in the oil phase and contains water, the water soluble polymer, and surfactants and an inverting surfactant. The water soluble polymer is made up of 30 to 60 weight percent of a non-ionic monomer, 5 to 50 weight percent of a sulfonic acid containing monomer, and 10 to 60 weight percent of a cationic monomer and makes up from 5 to 40 weight percent of the water-in-oil emulsion.
    Type: Application
    Filed: July 29, 2019
    Publication date: January 23, 2020
    Applicant: SOLVAY USA INC.
    Inventors: Kevin FREDERICK, Shih-Ruey CHEN, Randy LOEFFLER
  • Patent number: 10385253
    Abstract: A friction reducing treatment solution that includes water, from 100 to 500,000 ppm of total dissolved solids, and from 0.5 to 3 gallons per thousand gallons of a water-in-oil emulsion containing a water soluble polymer. The total dissolved solids include at least 10 weight percent of a multivalent cation. The water-in-oil emulsion includes an oil phase and an aqueous phase, where the oil phase is a continuous phase containing an inert hydrophobic liquid and the aqueous phase is present as dispersed distinct particles in the oil phase and contains water, the water soluble polymer, and surfactants and an inverting surfactant. The water soluble polymer is made up of 20 to 80 weight percent of a non-ionic monomer, 0.5 to 30 weight percent of a carboxylic acid containing monomer, and 5 to 70 weight percent of a cationic monomer and makes up from 10 to 35 weight percent of the water-in-oil emulsion.
    Type: Grant
    Filed: July 15, 2015
    Date of Patent: August 20, 2019
    Assignee: Solvay USA Inc.
    Inventors: Kevin Walter Frederick, Shih-Ruey Tom Chen, Randy Jack Loeffler, Kailas Sawant
  • Patent number: 10334843
    Abstract: Pesticide compositions containing an adjuvant which contains, based on 100 parts by weight of the adjuvant, (a) greater than about 50 parts by weight of at least one alkyl fatty acid ester, (b) from about 2 parts by weight to less than about 5 parts by weight of a surfactant comprising: (b)(i) one or more anionic surfactants selected from sulfonic acids, sulfonic acid esters, alkylsulfosuccinic acid esters, phosphate esters, sulfate esters, and oleoyltaurate salts, or (b)(ii) one or more non-ionic surfactants selected from sorbitan fatty acid esters, aryl alkoxylates, alkoxylated fatty alcohols, alkoxylated fatty acids, alkoxylated triglycerides, alkoxy copolymers, alkylpolyglucosides, alkoxylated fatty amines, and ether amines, or (iii) a mixture (b)(i) and (b)(ii), exhibit improved performance, particularly when sprayed through a flat fan spray nozzle, an air induction spray nozzle, or other spray nozzle and at a pressure of from about 10 pounds per square inch to about 100 pounds per square inch.
    Type: Grant
    Filed: September 17, 2014
    Date of Patent: July 2, 2019
    Assignee: SOLVAY USA, INC.
    Inventors: Hedieh Modaressi, Joe V. Gednalske, Rajesh Pazhianur, Andrew Douglass, Gregory K. Dahl