Patents Assigned to Solvay USA, Inc.
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Publication number: 20240101721Abstract: Described herein are hydrophobically-modified polysaccharides, their manufacture, and their use in microencapsulation, typically of water-insoluble active materials.Type: ApplicationFiled: October 8, 2020Publication date: March 28, 2024Applicants: RHODIA OPERATIONS, SOLVAY USA INC.Inventors: Ahmed Alsayed, Manasi Chawathe, Celine Anna Simone Burel, Denis Bendejacq
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Publication number: 20230017258Abstract: A polymer dispersion includes a water-soluble copolymer prepared by controlled radical polymerization; a water soluble salt; a polyol; a salt selected from the group consisting of sodium citrate, sodium phosphate, sodium nitrate, and combinations thereof; and water. Methods for using the polymer dispersion for oilfield friction reduction occur under a variety of adverse conditions including low temperatures, salt, scale, and iron.Type: ApplicationFiled: September 12, 2022Publication date: January 19, 2023Applicant: SOLVAY USA INC.Inventors: Qing Wang, Genyao Lin, Zhihua Zhang, Fulya Sudur Zalluhoglu
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Patent number: 11441066Abstract: A polymer dispersion includes a water-soluble copolymer prepared by controlled radical polymerization; a water soluble salt; a polyol; a salt selected from the group consisting of sodium citrate, sodium phosphate, sodium nitrate, and combinations thereof; and water. Methods for using the polymer dispersion for oilfield friction reduction occur under a variety of adverse conditions including low temperatures, salt, scale, and iron.Type: GrantFiled: November 17, 2020Date of Patent: September 13, 2022Assignee: SOLVAY USA INC.Inventors: Qing Wang, Genyao Lin, Zhihua Zhang, Fulya Sudur Zalluhoglu
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Patent number: 11377588Abstract: A well treatment fluid composition that includes a tetrakis(hydroxyorgano)phosphonium salt and 1,3-dimethylol-5,5-dimethylhydantoin. Methods for preparing a well treatment fluid composition and treating a subterranean formation are also presented.Type: GrantFiled: March 1, 2021Date of Patent: July 5, 2022Assignee: SOLVAY USA INC.Inventors: Christopher Raymond Jones, Stephanie Edmunds, Jean C. Molina
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Patent number: 11261361Abstract: A friction reducing treatment solution that includes water, from 100 to 500,000 ppm of total dissolved solids, and from 0.5 to 3 gallons per thousand gallons of a water-in-oil emulsion containing a water soluble polymer. The total dissolved solids include at least 10 weight percent of a multivalent cation. The water-in-oil emulsion includes an oil phase and an aqueous phase, where the oil phase is a continuous phase containing an inert hydrophobic liquid and the aqueous phase is present as dispersed distinct particles in the oil phase and contains water, the water soluble polymer, and surfactants and an inverting surfactant. The water soluble polymer is made up of 30 to 60 weight percent of a non-ionic monomer, 5 to 50 weight percent of a sulfonic acid containing monomer, and 10 to 60 weight percent of a cationic monomer and makes up from 5 to 40 weight percent of the water-in-oil emulsion.Type: GrantFiled: July 29, 2019Date of Patent: March 1, 2022Assignee: SOLVAY USA INC.Inventors: Kevin Frederick, Shih-Ruey Chen, Randy Loeffler
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Patent number: 11234377Abstract: Pesticide compositions containing an adjuvant which contains, based on 100 parts by weight of the adjuvant, (a) greater than about 50 parts by weight of at least one alkyl fatty acid ester, (b) from about 2 parts by weight to less than about 5 parts by weight of a surfactant comprising: (b)(i) one or more anionic surfactants selected from sulfonic acids, sulfonic acid esters, alkylsulfosuccinic acid esters, phosphate esters, sulfate esters, and oleoyltaurate salts, or (b)(ii) one or more non-ionic surfactants selected from sorbitan fatty acid esters, aryl alkoxylates, alkoxylated fatty alcohols, alkoxylated fatty acids, alkoxylated triglycerides, alkoxy copolymers, alkylpolyglucosides, alkoxylated fatty amines, and ether amines, or (iii) a mixture (b)(i) and (b)(ii), exhibit improved performance, particularly when sprayed through a flat fan spray nozzle, an air induction spray nozzle, or other spray nozzle and at a pressure of from about 10 pounds per square inch to about 100 pounds per square inch.Type: GrantFiled: July 1, 2019Date of Patent: February 1, 2022Assignee: SOLVAY USA INC.Inventors: Hedieh Modaressi, Joe V. Gednalske, Rajesh Pazhianur, Andrew Douglass, Gregory K. Dahl
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Publication number: 20220017808Abstract: A water-in-oil emulsion having an oil phase (O) and an aqueous phase (A) at an O/A ratio of from about 1:8 to about 10:1; wherein the water-in-oil emulsion includes the oil phase as a continuous phase that includes an inert hydrophobic liquid, and the aqueous phase as a dispersed phase of distinct particles in the oil phase that includes water, a water soluble polymer, and at least one surfactant; wherein the water soluble polymer includes from about 1 to about 60 weight percent of one or more cationic monomers, wherein the amount is by total weight of the water soluble polymer; wherein the water soluble polymer is present in an amount from about 5 to about 40 weight percent of the water-in-oil emulsion; and wherein an aqueous solution prepared by inverting the water-in-oil emulsion by adding it to water has at least comparable viscosity build to an aqueous solution made from a water-in-oil emulsion of the same composition containing 15 weight percent more water soluble polymer.Type: ApplicationFiled: September 30, 2021Publication date: January 20, 2022Applicant: SOLVAY USA INC.Inventors: Kailas Sawant, Louis Villafane, Kevin Frederick, Shih-Ruey Chen, Randy Loeffler
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Patent number: 11162011Abstract: A water-in-oil emulsion having an oil phase (O) and an aqueous phase (A) at an O/A ratio of from about 1:8 to about 10:1; wherein the water-in-oil emulsion includes the oil phase as a continuous phase that includes an inert hydrophobic liquid, and the aqueous phase as a dispersed phase of distinct particles in the oil phase that includes water, a water soluble polymer, and at least one surfactant; wherein the water soluble polymer includes from about 1 to about 60 weight percent of one or more cationic monomers, wherein the amount is by total weight of the water soluble polymer; wherein the water soluble polymer is present in an amount from about 5 to about 40 weight percent of the water-in-oil emulsion; and wherein an aqueous solution prepared by inverting the water-in-oil emulsion by adding it to water has at least comparable viscosity build to an aqueous solution made from a water-in-oil emulsion of the same composition containing 15 weight percent more water soluble polymer.Type: GrantFiled: August 25, 2016Date of Patent: November 2, 2021Assignee: SOLVAY USA INC.Inventors: Kailas Sawant, Louis Villafane, Kevin Frederick, Shih-Ruey Chen, Randy Loeffler
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Publication number: 20210179927Abstract: A well treatment fluid composition that includes a tetrakis(hydroxyorgano)phosphonium salt and 1,3-dimethylol-5,5-dimethylhydantoin. Methods for preparing a well treatment fluid composition and treating a subterranean formation are also presented.Type: ApplicationFiled: March 1, 2021Publication date: June 17, 2021Applicant: SOLVAY USA INC.Inventors: Christopher Raymond Jones, Stephanie Edmunds, Jean C. Molina
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Publication number: 20210163816Abstract: The present invention relates to a polymer dispersion prepared by controlled radical polymerization. The present invention also relates to methods for using the polymer dispersion for oilfield friction reduction under a variety of adverse conditions.Type: ApplicationFiled: November 17, 2020Publication date: June 3, 2021Applicant: SOLVAY USA INC.Inventors: Qing WANG, Genyao LIN, Zhihua ZHANG, Fulya Sudur ZALLUHOGLU
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Patent number: 10968384Abstract: A well treatment fluid composition that includes a tetrakis(hydroxyorgano)phosphonium salt and 1,3-dimethylol-5,5-dimethylhydantoin. Methods for preparing a well treatment fluid composition and treating a subterranean formation are also presented.Type: GrantFiled: December 6, 2016Date of Patent: April 6, 2021Assignee: SOLVAY USA INC.Inventors: Christopher Raymond Jones, Stéphanie Edmunds, Jean C. Molina
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Publication number: 20200399529Abstract: A water-in-oil emulsion that includes an oil phase (O) and an aqueous phase (A) at an O/A ratio of from about 1:8 to about 10:1; wherein the water-in-oil emulsion includes the oil phase as a continuous phase that includes an inert hydrophobic liquid, at least one water-insoluble hydrophobic monomer, and at least one surfactant, and the aqueous phase as a dispersed phase of distinct particles in the oil phase that includes water and a water soluble polymer that includes: (i) at least one acrylamide monomer and (ii) at least one acrylic acid monomer; wherein the water soluble polymer is present in an amount from about 10 to about 35 weight percent of the water-in-oil emulsion.Type: ApplicationFiled: August 31, 2020Publication date: December 24, 2020Applicant: Solvay USA Inc.Inventors: Genyao LIN, Louis VILLAFANE, Kailas SAWANT, Shih-Ruey CHEN, Kevin FREDERICK
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Patent number: 10836954Abstract: A well treatment fluid composition that includes a tetrakis(hydroxyorgano)phosphonium salt and at least one oxidizing viscosity breaker. Methods for preparing a microbial viscosity breaker composition and treating a subterranean formation are also presented.Type: GrantFiled: June 30, 2016Date of Patent: November 17, 2020Assignee: Solvay USA Inc.Inventors: Chris Jones, Jean Molina, Francis Smith, Henry Wiggins, Dru Bishop
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Patent number: 10808166Abstract: A composition and method for treating a fracturing fluid comprising produced water with high levels of dissolved solids using a polymer crosslinked with a boron compound and a high pH alkylamine buffer. The composition improves the viscosity stability of the fracturing fluid at elevated bottom-hole temperatures, particularly when the fluid has high levels of calcium and magnesium. The composition is particularly useful with polysaccharides, including galactomannan gums, such as guar gum, locust bean gum, and karaya gum, and allows for the use of the preferred boron compound crosslinkers in high total dissolved solids fracturing fluids without the pH destabilization problems encountered with the prior art.Type: GrantFiled: August 11, 2016Date of Patent: October 20, 2020Assignee: SOLVAY USA INC.Inventors: Tyler Heath Nelson, Stephen Anthony Glover, Enrique Lopez
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Patent number: 10711173Abstract: A friction reducing treatment solution that includes water, from 100 to 500,000 ppm of total dissolved solids, and from 0.5 to 3 gallons per thousand gallons of a water-in-oil emulsion containing a water soluble polymer. The total dissolved solids include at least 10 weight percent of a multivalent cation. The water-in-oil emulsion includes an oil phase and an aqueous phase, where the oil phase is a continuous phase containing an inert hydrophobic liquid and the aqueous phase is present as dispersed distinct particles in the oil phase and contains water, the water soluble polymer, and surfactants and an inverting surfactant. The water soluble polymer is made up of 30 to 60 weight percent of a non-ionic monomer, 0.5 to 25 weight percent of a carboxylic acid containing monomer, 0 to 10 weight percent of a sulfonic acid containing monomer, and 10 to 60 weight percent of a cationic monomer and makes up from 10 to 35 weight percent of the water-in-oil emulsion.Type: GrantFiled: November 21, 2017Date of Patent: July 14, 2020Assignee: SOLVAY USA INC.Inventors: Kevin Frederick, Shih-Ruey Chen, Randy Loeffler, Kailas Sawant
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Patent number: 10584277Abstract: A method of treating a portion of a subterranean formation that includes: providing a water-in-oil emulsion, inverting the water-in-oil emulsion to form a friction reducing treatment solution, and introducing the treatment solution into the portion of the subterranean formation. The water-in-oil emulsion has an oil phase, an aqueous phase and surfactants. The oil phase (O) and an aqueous phase (A) are present at an O/A ratio of from about 1:8 to about 10:1. The oil phase is present as a continuous phase and contains an inert hydrophobic liquid. The aqueous phase is present as a dispersed phase of distinct particles in the oil phase and includes water and a water soluble polymer. The water soluble polymer makes up from 10 to 25 weight percent of the water-in-oil emulsion. The water-in-oil emulsion is inverted by adding it to water to form a friction reducing treatment solution.Type: GrantFiled: February 3, 2014Date of Patent: March 10, 2020Assignee: SOLVAY USA INC.Inventors: Kevin W Frederick, Shih-Ruey T Chen
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Publication number: 20200032134Abstract: A method of treating a portion of a subterranean formation that includes: providing a water-in-oil emulsion, inverting the water-in-oil emulsion to form a friction reducing treatment solution, and introducing the treatment solution into the portion of the subterranean formation. The water-in-oil emulsion has an oil phase, an aqueous phase and surfactants. The oil phase (O) and an aqueous phase (A) are present at an O/A ratio of from about 1:8 to about 10:1. The oil phase is present as a continuous phase and contains an inert hydrophobic liquid. The aqueous phase is present as a dispersed phase of distinct particles in the oil phase and includes water and a water soluble polymer. The water soluble polymer makes up from 10 to 25 weight percent of the water-in-oil emulsion. The water-in-oil emulsion is inverted by adding it to water to form a friction reducing treatment solution.Type: ApplicationFiled: October 1, 2019Publication date: January 30, 2020Applicant: SOLVAY USA INC.Inventors: Kevin W. Frederick, Shih-Reuy T. Chen
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Publication number: 20200024497Abstract: A friction reducing treatment solution that includes water, from 100 to 500,000 ppm of total dissolved solids, and from 0.5 to 3 gallons per thousand gallons of a water-in-oil emulsion containing a water soluble polymer. The total dissolved solids include at least 10 weight percent of a multivalent cation. The water-in-oil emulsion includes an oil phase and an aqueous phase, where the oil phase is a continuous phase containing an inert hydrophobic liquid and the aqueous phase is present as dispersed distinct particles in the oil phase and contains water, the water soluble polymer, and surfactants and an inverting surfactant. The water soluble polymer is made up of 30 to 60 weight percent of a non-ionic monomer, 5 to 50 weight percent of a sulfonic acid containing monomer, and 10 to 60 weight percent of a cationic monomer and makes up from 5 to 40 weight percent of the water-in-oil emulsion.Type: ApplicationFiled: July 29, 2019Publication date: January 23, 2020Applicant: SOLVAY USA INC.Inventors: Kevin FREDERICK, Shih-Ruey CHEN, Randy LOEFFLER
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Patent number: 10385253Abstract: A friction reducing treatment solution that includes water, from 100 to 500,000 ppm of total dissolved solids, and from 0.5 to 3 gallons per thousand gallons of a water-in-oil emulsion containing a water soluble polymer. The total dissolved solids include at least 10 weight percent of a multivalent cation. The water-in-oil emulsion includes an oil phase and an aqueous phase, where the oil phase is a continuous phase containing an inert hydrophobic liquid and the aqueous phase is present as dispersed distinct particles in the oil phase and contains water, the water soluble polymer, and surfactants and an inverting surfactant. The water soluble polymer is made up of 20 to 80 weight percent of a non-ionic monomer, 0.5 to 30 weight percent of a carboxylic acid containing monomer, and 5 to 70 weight percent of a cationic monomer and makes up from 10 to 35 weight percent of the water-in-oil emulsion.Type: GrantFiled: July 15, 2015Date of Patent: August 20, 2019Assignee: Solvay USA Inc.Inventors: Kevin Walter Frederick, Shih-Ruey Tom Chen, Randy Jack Loeffler, Kailas Sawant
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Patent number: 10334842Abstract: Pesticide compositions containing an adjuvant which contains, based on 100 parts by weight of the adjuvant, (a) greater than about 50 parts by weight of at least one alkyl fatty acid ester, (b) from about 2 parts by weight to less than about 5 parts by weight of a surfactant comprising: (b)(i) one or more anionic surfactants selected from sulfonic acids, sulfonic acid esters, alkylsulfosuccinic acid esters, phosphate esters, sulfate esters, and oleoyltaurate salts, or (b)(ii) one or more non-ionic surfactants selected from sorbitan fatty acid esters, aryl alkoxylates, alkoxylated fatty alcohols, alkoxylated fatty acids, alkoxylated triglycerides, alkoxy copolymers, alkylpolyglucosides, alkoxylated fatty amines, and ether amines, or (iii) a mixture (b)(i) and (b)(ii), exhibit improved performance, particularly when sprayed through a flat fan spray nozzle, an air induction spray nozzle, or other spray nozzle and at a pressure of from about 10 pounds per square inch to about 100 pounds per square inch.Type: GrantFiled: September 17, 2014Date of Patent: July 2, 2019Assignee: SOLVAY USA, INC.Inventors: Hedieh Modaressi, Joe V. Gednalske, Rajesh Pazhianur, Andrew Douglass, Gregory K. Dahl