Abstract: The presence of certain impurities in diphenyl sulfone have a deleterious effect on the properties of the poly(aryletherketone)s produced therein, including one or more of color, melt stability, molecular weight, crystallinity, etc. and here identify those impurities and provide processes for the recovery of the diphenyl sulfone.
Type:
Grant
Filed:
August 10, 2015
Date of Patent:
September 19, 2017
Assignee:
Solvay Advanced Polymers, L.L.C.
Inventors:
Chantal Louis, William Gandy, Edward Ryan, Geoffrey Scott Underwood, Kong Yi
Abstract: A poly(ether ketone) polymer comprising recurring units derived from the reaction of at least one aromatic dihalo-compound comprising at least one —C(O)— group and at least one diol having a general formula HO-Dol-OH wherein Dol is an aliphatic group comprising from 4 to 20 carbon atoms which comprises at least one cycloaliphatic moiety.
Type:
Grant
Filed:
December 19, 2013
Date of Patent:
September 19, 2017
Assignee:
Solvay Specialty Polymers USA, LLC
Inventors:
Narmandakh Taylor, DeeDee Smith, David Blake Roller
Abstract: Disclosed are a composite oxide which is capable of maintaining a large volume of pores even used in a high temperature environment, and which has excellent heat resistance and catalytic activity, as well as a method for producing the composite oxide and a catalyst for exhaust gas purification employing the composite oxide. The composite oxide contains cerium and at least one element selected from aluminum, silicon, or rare earth metals other than cerium and including yttrium, at a mass ratio of 85:15 to 99:1 in terms oxides, and has a property of exhibiting a not less than 0.30 cm3/g, preferably not less than 0.40 cm3/g volume of pores with a diameter of not larger than 200 nm, after calcination at 900° C. for 5 hours, and is suitable for a co-catalyst in a catalyst for vehicle exhaust gas purification.
Abstract: Elemental fluorine is often manufactured electrochemically from a solution of KF in hydrogen fluoride and contains varying amounts of HF as impurity. The present invention provides a method for chamber cleaning using F2 which contains more than 0.1% by weight and equal to or less than 10% by weight of HF. Surprisingly, such an F2 is very well suited for the purpose of chamber cleaning. In a preferred embodiment, the F2 which contains more than 0.1% by weight and less than 2.5% by weight of HF is electrolytically produced, cleaned, delivered and used on site, without any pressurizing treatment. Omitting cleaning steps and process and using process conditions leaving a relatively high HF content in the F2 allows at the same time to omit pressurizing steps. The advantage is that less cleaning steps.
Abstract: The present invention pertains to a fluoropolymer [polymer (F)] comprising: recurring units derived from vinylidene fluoride (VDF); from 10% to 50% by moles of recurring units derived from trifluoroethylene (TrFE); and from 0.01% to 10% by moles of recurring units derived from at least one (meth)acrylic monomer [monomer (MA)] having formula (I) here below: wherein: R1, R2 and R3, equal to or different from each other, are independently selected from a hydrogen atom and a C1-C3 hydrocarbon group, and ROH represents a hydrogen atom or a C1-C5 hydrocarbon moiety comprising at least one hydroxyl group. The invention also pertains to a process for the manufacture of said polymer (F) and to use of said polymer (F) as ferroelectric, piezoelectric, pyroelectric or dielectric material in electrical and electronic devices.
Abstract: Described are electrolyte compositions comprising a fluorinated solvent, an organic carbonate, a sultone, and optionally a borate. The fluorinated solvent may be a fluorinated acyclic carboxylic acid ester, a fluorinated acyclic carbonate, a fluorinated acyclic ether, or mixtures thereof. The organic carbonate may be fluorinated or non-fluorinated. The electrolyte compositions are useful in electrochemical cells, such as lithium ion batteries.
Type:
Application
Filed:
August 12, 2015
Publication date:
August 31, 2017
Applicant:
Solvay SA
Inventors:
Stephen E. Burkhardt, Kostantinos Kourtakis, Jun J. Liu, Mark Gerrit Roelofs, Sang-Hwan Kim
Abstract: The invention relates to hydroxybenzophenone-based compounds of formula (I) that are used to improve UV, thermal, and thereto-oxidative stability of high performance aromatic polymers in a blend or as end-cappers of the same polymers.
Abstract: A process for the dehydrochlorination of a chlorinated hydrocarbon comprising at least one chlorine atom and at least one hydrogen atom on vicinal carbon atoms to yield the corresponding unsaturated hydrocarbon, said process comprising contacting the chlorinated hydrocarbon with a guanidinium salt or its guanidine precursor.
Type:
Grant
Filed:
July 28, 2014
Date of Patent:
August 15, 2017
Assignee:
SOLVAY SPECIALTY POLYMERS ITALY S.P.A.
Inventors:
Ivan Wlassics, Marco Colladon, Stefano Millefanti, Giuseppe Marchionni, Marco Piccinini
Abstract: The present invention concerns a process for the recovery of carboxylic acid from a fraction comprising carboxylic acid and impurities, and a process for the manufacture of treated wood, which comprise the step of submitting a fraction containing carboxylic acid and impurities to a gas stripping operation.
Type:
Application
Filed:
August 13, 2015
Publication date:
August 10, 2017
Applicant:
SOLVAY ACETOW GmbH
Inventors:
Thomas KRUMREY, Andreas HUMMEL, Dirk HÖLTER
Abstract: A mobile electronic device comprising at least one part made of a polymer composition [composition (C), herein after] comprising at least one part made of a polymer composition [composition (C), herein after] comprising from at least one polyaryletherketone polymer [(PAEK) polymer], and at least one nitride (NI) of an element having an electronegativity (?) of from 1.3 to 2.5, as defined in <<Handbook of Chemistry and Physics>>, CRC Press, 64th edition, pages B-65 to B-158, based on the total weight of the composition (C).
Type:
Grant
Filed:
December 18, 2013
Date of Patent:
August 8, 2017
Assignee:
SOLVAY SPECIALTY POLYMERS USA, LLC
Inventors:
Mohammad Jamal El-Hibri, David B. Thomas
Abstract: The invention relates to piperidine-based compounds of formula (I) that are used to improve UV, thermal, and thermo-oxidative stability of high performance aromatic polymers in a blend or as end-cappers of the same polymers.
Type:
Application
Filed:
May 11, 2015
Publication date:
July 20, 2017
Applicant:
SOLVAY SPECIALTY POLYMERS USA, LLC
Inventors:
Joel POLLINO, Satchit SRINIVASAN, Henry BRADLEY, Claire HARTMANN-THOMPSON, Gregory GOSCHY
Abstract: The present invention pertains to a process for the manufacture of a grafted fluorinated polymer comprising at least one grafted side chain comprising one or more glycosidic recurring units [polymer (F)], said process comprising polymerizing: vinylidene fluoride (VDF), optionally, one or more other fluorinated monomers [monomers (F)], and optionally, one or more (meth)acrylic monomers [monomers (MA)], in the presence of at least one polysaccharide derivative [derivative (P)], said polysaccharide derivative having a dynamic viscosity of less than 15 mPa×s, as measured according to ASTM D445 at 20° C. in an aqueous solution at a concentration of 2% by weight, and by further providing novel polymers (F) as defined above.
Type:
Grant
Filed:
December 13, 2011
Date of Patent:
July 11, 2017
Assignee:
SOLVAY SPECIALTY POLYMERS ITALY S.P.A.
Inventors:
Julio A. Abusleme, Roberto Biancardi, Fabien Roblot, Anna Maria Bertasa, Giulio Brinati
Abstract: A piperidine-based stabilizer compound of formula (I) or (II) that imparts UV, thermal, and/or thermo-oxidative stability to polymer compositions and more specifically to aromatic polymers and polymer compositions thereof.
Type:
Application
Filed:
May 20, 2015
Publication date:
July 6, 2017
Applicant:
SOLVAY SPECIALTY POLYMERS USA, LLC
Inventors:
Joel POLLINO, Gregory GOSCHY, Satchit SRINIVASAN
Abstract: A process for preparing sodium bicarbonate particles, comprising the steps of: (a) adding at least one alkali metal carbonate to an aqueous solution in order to form an aqueous composition; wherein the alkali metal carbonate comprises sodium carbonate and wherein the aqueous composition comprises at least one polycarboxylic acid and/or the salts thereof, in an amount of at least 200 ppm based on the weight of the aqueous composition; and (b) precipitating solid particles comprising sodium bicarbonate crystals and separating said sodium bicarbonate particles from the aqueous composition, in order to obtain sodium bicarbonate particles and an aqueous mother liquor.
Type:
Grant
Filed:
December 19, 2012
Date of Patent:
July 4, 2017
Assignee:
Solvay SA
Inventors:
Thoi-Dai Chau, David Jean Lucien Savary
Abstract: The invention pertains to a hyperbranched (per)fluoroelastomer [fluoroelastomer (B)] comprising recurring units derived from a bis-olefin [bis-olefin (OF)] having general formula (I): wherein R1, R2, R3, R4, R5 and R6, equal or different from each other, are H or C1-C5 alkyl; Z is a linear or branched C1-C18 alkylene or cycloalkylene radical, optionally containing oxygen atoms, preferably at least partially fluorinated, or a (per)fluoropolyoxyalkylene radical, said fluoroelastomer (B) having a slope in G? curve such that the ratio: G?100/G?0.01 is of less than 10, when determined at 260° C. according to ASTM D4440 standard, wherein G?100 is the storage modulus at a shear rate of 100 rad/sec and G?0.01 is the storage modulus at a shear rate of 0.01 rad/sec, to compositions comprising the same, and to a process for their manufacture.
Type:
Grant
Filed:
June 7, 2012
Date of Patent:
June 27, 2017
Assignee:
SOLVAY SPECIALTY POLYMERS ITALY S.P.A.
Inventors:
Matteo Fantoni, Giovanni Comino, Marco Apostolo
Abstract: Process for the recovery of carboxylic acid, in particular acetic acid containing carboxylic anhydride in particular acetic anhydride and other impurities, which comprises: (a) treating a fraction, in particular a fraction originating from a wood treatment process, containing carboxylic acid and impurities with a metal salt in the presence of water, (b) treating at least part of the fraction obtained from step (a) to remove metal salt and, (c) treating at least part of the fraction obtained from step (b) by distillation, stripping or membrane separation to recover at least a purified carboxylic acid fraction.
Abstract: Particles containing a strong oxidizer (classified as PG I according to the standard test method of the UN Manual of Tests and Criteria, 5th revised Edition, sub-section 34.4.1) and at least one other constituent, the amount and nature of the constituent(s) other than the strong oxidizer in the particles being such that the particles are classified as non-oxidizer according to the standard test method of the UN Manual of Tests and Criteria, 5th revised Edition, sub-section 34.4.1. Process for the production of these particles.
Abstract: The invention relates to a non-aqueous fluoropolymer composition comprising: a) at least one fluorinated ionizable polymer [polymer (A)] as defined in the description, and b) at least one fluorinated ionizable polymer [polymer (B)] as defined in the description; c) at least one fluorinated solvent; and d) at least one alcohol. The invention further relates to a process for manufacturing the composition and to the use of the composition for preparing polymeric materials.
Type:
Grant
Filed:
December 4, 2013
Date of Patent:
June 20, 2017
Assignee:
SOLVAY SPECIALTY POLYMERS ITALY S.P.A.
Inventors:
Silvia Rita Petricci, Solange Barbieri, Claudio Adolfo Pietro Tonelli, Giuseppe Marchionni
Abstract: The present invention pertains to a process for the manufacture of a grafted fluoropolymer [polymer (Fg)], said process comprising reacting: A) at least one fluoropolymer comprising at least one functional group selected from the group consisting of a hydroxyl group and a carboxylic acid group [polymer (F)], B) at least one polyoxyalkylene (POA) of formula (I): RB—(CH2—O)x—(CH2CHRAO)n—(CH2—O)x?—RC, wherein at least one of RB and RC is a reactive group comprising at least one heteroatom selected from oxygen and nitrogen different from the hydroxyl group, the remaining, if any, being a —[O]z—CH3 alkyl group, wherein z is 0 or 1, RA is a hydrogen atom or a C1-C5 alkyl group, x and x?, equal to or different from each other, are independently 0 or 1, and n is an integer comprised between 2 and 1000, preferably between 5 and 200, C) optionally, in the presence of at least one catalyst, and D) optionally, in the presence of at least one organic solvent (S).
Type:
Grant
Filed:
December 17, 2013
Date of Patent:
June 13, 2017
Assignee:
SOLVAY SPECIALTY POLYMERS ITALY S.P.A.
Inventors:
Ivan Wlassics, Roberto Biancardi, Pasquale Campanelli, Emanuele Di Nicolo', Aldo Sanguineti, Claudio Adolfo Pietro Tonelli
Abstract: Utilization of mine methane produced by mining a non-combustible ore, such as trona, as an energy source for heat, steam, and/or power generation. Such utilization is beneficial for a surface appliance which is close to surface outlet(s) of mine methane recovery system(s). A method for reducing greenhouse gas emissions generated during mining of a non-combustible ore uses the combustion of co-produced mine methane. The mine methane is recovered in a mine ventilation air exhaust with very low methane content, and may be additionally recovered in a drainage gas, such as gob gas, with much higher methane content. The surface appliance may be selected from the group consisting of calciner, dryer, boiler, kiln, furnace, engine, turbine, power generation unit, co-generation unit, and any combinations thereof. Benefits may include reduction in energy purchases, reduction in greenhouse emissions, and/or gain through sale of carbon credits to the carbon market by registering carbon reductions.
Type:
Grant
Filed:
April 13, 2012
Date of Patent:
June 13, 2017
Assignee:
Solvay Chemicals, Inc.
Inventors:
Ronald O. Hughes, Bryan M. Mortimer, David M. Hansen