Abstract: Moldable sheet materials include a first layer including a first polyester, a second layer including a second polyester, and, optionally, a third layer including a third polyester. The first polyester, the second polyester, and the third polyester are the same as or different from each other of the first polyester, the second polyester, and the third polyester. The sheet materials exclude one or more of adhesives, ethylene vinyl alcohol, polyvinyl alcohol, polyvinylidene chloride, polyamides, polyolefins, polystyrenes, and the like. Molded packages made from the sheet materials exhibit desirable oxygen and water vapor barrier properties while also being suitable for recycling in a polyethylene terephthalate recycle stream.

Abstract: Urethane-urea-acrylic cast sheet materials are made from a reaction product of components including polyisocyanate compound having at least two isocyanate functional groups and optional polyol (or pre-reacted urethane prepolymer having at least two isocyanate functional groups), curative having at least two amine functional groups, acrylic monomer, and optional multifunctional monomer having a first functional group having an active hydrogen and a second functional group having at least one double bond. The urethane-urea-acrylic cast sheet materials exhibit excellent impact properties and desirable hardness while also maintaining optical properties such as low haze that can be comparable to that of conventional cast acrylic sheet.

Abstract: Copolymers comprising a polyurethane segment, a polyvinyl segment and a multifunctional monomer having first and second functional groups covalently bound to the polyurethane segment and polyvinyl segment, respectively, are disclosed. Cast sheets formed therefrom exhibit improved high impact resistance and similar optical properties as compared to polyvinyl cast sheets.