Abstract: A frameless bipolar cell stack architecture with either internal manifolds of circulation of electrolyte solutions “in parallel” through all respective cell compartments or internal ducting adapted to provide for “serial” flow paths of the electrolyte solutions in succession through all respective cell compartments of the stack, does not employ any plastic frame and employs substantially planar bipolar electrical interconnects (I) of substantially homogeneous electrical conductivity with a perimeter that super-imposes to the perimeter of any other element of the stack. Whenever useful for the particular application, the planar interconnects may have a protruding “lug portion” that projects beyond the outer perimeter side of the other stacked elements, providing an externally contactable area sufficiently large for the power (current rating) of an electrical tap, at an intermediate voltage relative to the voltage difference between the end terminals of the stack, connectable to an external circuit.

Abstract: A static inverter for a battery of elementary, current sources or cells electrically in series and a number N of intermediate voltage taps along the chain of elementary DC current sources, wherein the number of elementary cells comprised between an intermediate tap and another intermediate tap adjacent to it or an end terminal of said chain is proportionate to the amplitude in the respective phase interval of a number N of discretization phases of the waveform of the AC voltage to be output in a quadrant; is implemented by arranging for: a number N of power switches each connecting a respective intermediate tap and a first end terminal of a first polarity of said chain of elementary cells in series to a common circuit node of said first polarity; an output bridge stage constituted by at least four power switches controlled in pairs for switching the current paths through the bridge stage, having a first pair of nodes coupled to said common circuit node of said first plurality and to the other end terminal of

Abstract: A multicell assembly for a redox flow electrolyzer is constituted by alternately stacking pre-assembled elements, typically an electrode subassembly including porous mat electrodes on opposite faces of a conductive plate and a permionic membrane subassembly. Pressure drops in circulating the electrolyte solutions through respective cell compartments, in contact with fluid permeable three-dimensional electrodes in the form of porous mats, are reduced while enhancing evenness of electrolyte refreshing over the whole geometrical cell-area, by defining cooperatively interleaved flow channels in the porous mat electrode. Two interleaved orders of parallel flow channels are defined. All the parallel spaced channels of each order extend from a common orthogonal base channel formed along the respective inlet or outlet side of the electrolyte flow chamber, and terminate short of reaching the base channel of the other.

Abstract: The ohmic losses in a redox cell, composed of a positive electrode inside a flow compartment of a positive halfcell acid electrolytic solution, a negative electrode inside a flow compartment of a negative halfcell acid electrolytic solution and a fluid impermeable membrane composed at least partially of an ion exchange resin separating said flow compartments of the respective halfcell electrolytic solution, may be reduced by using a membrane of mixed characteristics. The ion exchange resin of the membrane includes both a cation exchange resin and anion exchange resin allowing the migration through the membrane of anions as well as of protons (H+) of said acid electrolytic solutions.

Abstract: A static inverter for a battery of elementary, current sources or cells electrically in series and a number N of intermediate voltage taps along the chain of elementary DC current sources, wherein the number of elementary cells comprised between an intermediate tap and another intermediate tap adjacent to it or an end terminal of said chain is proportionate to the amplitude in the respective phase interval of a number N of discretization phases of the waveform of the AC voltage to be output in a quadrant; is implemented by arranging for: a number N of power switches each connecting a respective intermediate tap and a first end terminal of a first polarity of said chain of elementary cells in series to a common circuit node of said first polarity; an output bridge stage constituted by at least four power switches controlled in pairs for switching the current paths through the bridge stage, having a first pair of nodes coupled to said common circuit node of said first plurality and to the other end terminal of

Abstract: By realizing or installing check valve liquid vein interrupters in each compartment of the battery the phenomenon of slow discharge of the retained volumes of electrolytes during long periods of inactivity of a redox flow battery, with the electrolyte pumps stopped altogether, can be practically eliminated with the effect that the battery is perfectly ready to deliver electric power immediately upon request even after prolonged periods of inactivity. Moreover, the presence of liquid vein interrupters on each compartment in either an outlet or an inlet port substantially preventing by-pass current during a not pumping phase, permits to increase the by pumping the electrolytes through the compartments of a battery stack intermittently, in other words in a pulsed manner, with a certain duty-cycle.

Abstract: A multicell assembly for a redox flow electrolyzer is constituted by alternately stacking pre-assembled elements, typically an electrode subassembly including porous mat electrodes on opposite faces of a conductive plate and a permionic membrane subassembly. Pressure drops in circulating the electrolyte solutions through respective cell compartments, in contact with fluid permeable three-dimensional electrodes in the form of porous mats, are reduced while enhancing evenness of electrolyte refreshing over the whole geometrical cell-area, by defining cooperatively interleaved flow channels in the porous mat electrode. Two interleaved orders of parallel flow channels are defined. All the parallel spaced channels of each order extend from a common orthogonal base channel formed along the respective inlet or outlet side of the electrolyte flow chamber, and terminate short of reaching the base channel of the other.

Abstract: Carbon-base bipolar electrode for electrochemical redox reactions in an acid electrolyte in the form of a fluid impervious and electrically conductive septum, at least a face of which consists, at least partially, of a fluid previous woven or unwoven electrodically active fabric of carbon fibers or of yarns of carbon fibers, has an electrically conductive fluid impervious septum consisting of a composite of a matrix fabric in the form of a tightly knit or woven fabric of carbon fibers or of yarns of carbon fibers the pores of which are hydraulically sealed by an electrically conductive carbon containing material at least partly filling the pores of said matrix fabric.