Patents Assigned to Stamicarbon B.V.
  • Patent number: 5260378
    Abstract: The invention relates to a block copolymer according to the general formula A-b-B on the basis of a furan derivative as binding group (b) and the process for the preparation hereof. The furan derivative as binding group (b) is a compound according to formula (I). ##STR1## The block copolymer can simply be prepared in one single reactor and is suitable for use as compatibilizer.
    Type: Grant
    Filed: January 18, 1990
    Date of Patent: November 9, 1993
    Assignee: Stamicarbon B.V.
    Inventors: Alessandro Gandini, Marie C. Salon
  • Patent number: 5254712
    Abstract: The invention relates to a process for the preparation of high yields of 5-oxohexane nitriles with minimum formation of 1 undesired isomer. Such nitriles may be utilized as starting materials for the preparation of pharmaceutical and agrochemical intermediates and as well as final products. The process comprises reacting a methyl ketone and an .alpha.,.beta.-unsaturated nitrile in the presence of a catalytically effective amount of a strong base. One of the products which may be created by the process is 2,4-dimethyl-5-oxohexane nitrile.
    Type: Grant
    Filed: June 24, 1992
    Date of Patent: October 19, 1993
    Assignee: Stamicarbon B.V.
    Inventors: Anna M. C. F. Castelijns, Henricus J. Arts, Richard Green
  • Patent number: 5248461
    Abstract: The invention relates to microporous films of ultrahigh molecular weight polyethylene and to a process for the preparation thereof by forming a solution of UHMWPE in an evaporable solvent into a film and evaporating the solvent from the film at a temperature below the dissolution temperature, the shrinking tendency occurring in the film being prevented in at least one direction in the plane of the film.
    Type: Grant
    Filed: September 3, 1991
    Date of Patent: September 28, 1993
    Assignee: Stamicarbon B.V.
    Inventors: Pieter B. Pluyter, Paul Smith, Lambert H. T. Van Unen, Hendrikus J. J. Rutten
  • Patent number: 5236781
    Abstract: The present invention relates to a granulated thermoplastic polymer composition comprising granules incorporating 0.1-50% (vol) fiber bundles. The fiber bundles have a three dimensional orientation in each of the granules, and each fiber bundle contains at least 100 fibers. The present invention also relates to a process for producing a granulated thermoplastic polymer composition containing non-dispersed fiber bundles comprising the steps of mixing a thermoplastic polymer with fiber bundles at a sheer stress low enough to prevent the fiber bundles from falling apart, and the forming granules. A temperature of a dosage point where the fiber bundles are added to the thermoplastic polymer is below a processing temperature of the thermoplastic polymer. Each granule comprises 0.1 to 50% (vol) of the fiber bundles. The fiber bundles have a three dimensional orientation in each granule, and each fiber bundle contains at least 100 fibers.
    Type: Grant
    Filed: January 31, 1991
    Date of Patent: August 17, 1993
    Assignee: Stamicarbon B.V.
    Inventors: Louis C. Krijger, Jozef M. A. Jansen, Caroline H. Ipenburg
  • Patent number: 5219896
    Abstract: Photocurable liquid coating compositions adapted to provide primary coatings for optical glass fibers are disclosed. These compositions comprise polycarbonate-based acrylate-terminated polyurethane, an acrylate of an unsubstituted or C.sub.1 -C.sub.10 alkyl substituted phenol that is alkoxylated with a C.sub.2 -C.sub.4 alkylene oxide and at least one alkylacrylate having a T.sub.g below about -45.degree. C. Films produced from these ultraviolet light curable compositions are flexible and possess good water resistance and good wet adhesion.
    Type: Grant
    Filed: March 27, 1992
    Date of Patent: June 15, 1993
    Assignee: Stamicarbon, B.V.
    Inventors: Clive J. Coady, Erwin S. Poklacki, John M. Zimmerman, Timothy E. Bishop, John L. Derer
  • Patent number: 5205974
    Abstract: A process for the manufacture of filaments, tapes and films that possess a shish-kebab morphology. This is effected in that for instance UHMW PE after extrusion is stretched at a temperature between the melting temperature (Tm) and a critical temperature (Tc) and subsequently cooled in stressed condition. The stretching rate is between 0.1 and 10 [sec.].sup.-1.
    Type: Grant
    Filed: November 20, 1991
    Date of Patent: April 27, 1993
    Assignee: Stamicarbon B.V.
    Inventors: Cornelis W. M. Bastiaansen, Henricus E. H. Meijer, Zaheer Bashir
  • Patent number: 5194321
    Abstract: The invention relates to a reinforced veneer laminate comprising at least one layer of veneer and at least one layer of polyethylene filaments enveloped by resin and possessing a tensile strength of at least 1.2 GPa and a modulus of at least 30 GPA.The reinforced veneer laminate bends very well and has a good resistance against static mechanical loads and mechanical impact loads.
    Type: Grant
    Filed: April 12, 1991
    Date of Patent: March 16, 1993
    Assignee: Stamicarbon B.V.
    Inventors: Eduard A. Blanker, Jacob Van der Stad
  • Patent number: 5190809
    Abstract: Disclosed is a fabric of thermoplastic fibers and continuous reinforcing fibers in which the shrinkage of the thermoplastic fibers is minimal, thus providing a product well-suited for processing as a thermoplastic composite prepreg. The thermoplastic fibers have a melting point lower than that of the reinforcing fibers, and are preheated at a temperature of from 50.degree. to 15.degree. C. below the melting point of the thermoplastic material before being processed to form the fabric.Fabrics of thermoplastic fibers and reinforcing fibers according to the present invention can be used in applications where sheets of fabrics must be drapeable, so that when subjected to cold forming they conform to the mold for the thermoforming process. Fabrics according to the present invention are especially useful in applications where the use of high-grade, fiber-reinforced plastics is advantageous.
    Type: Grant
    Filed: August 31, 1990
    Date of Patent: March 2, 1993
    Assignee: Stamicarbon B.V.
    Inventors: Roelof Marissen, Hans H. H. Hornman
  • Patent number: 5186861
    Abstract: The invention relates to a process for the preparation of an intrinsically conductive moulding compound obtained by in situ polymerization of monomers which form an intrinsically conductive polymer after polymerization, in the presence of a matrix polymer and a catalyst, the matrix polymer being dissolved in an essentially solvent free monomer, after which the solution obtained is brought into the desired form and the monomers are polymerized in situ in the presence of a catalyst.Moulding compounds obtained with the process accordingly to the invention can be used in batteries electronic components (diodes, transistors), electrical wiring, coatings and in EMI-shielding attributes.
    Type: Grant
    Filed: January 22, 1991
    Date of Patent: February 16, 1993
    Assignee: Stamicarbon B.V.
    Inventors: Ronald M. A. M. Schellekens, Hans K. Van Dijk, Marcus J. H. Bulters
  • Patent number: 5186862
    Abstract: The invention relates to a plastic granulated material containing electrically conductive fibres, the degree of dispersion of which fibres in the granulated material is 0.10 at most, the degree of dispersion being the reciprocal value of the volume fraction in % of a granule occupied by electrically conductive fibre bundles and measured according to the threshold value method.Moulding compounds produced from the granules according to the invention have very high EMI values.
    Type: Grant
    Filed: October 19, 1989
    Date of Patent: February 16, 1993
    Assignee: Stamicarbon B.V.
    Inventors: Louis C. Krijger, Jozef M. A. Jansen, Nicolaas G. M. Hoen, Laurentius W. Steenbakkers, Peter E. Froehling
  • Patent number: 5180788
    Abstract: The invention relates to graft-modified linear polyethylene with low density (<940 kg/dm.sup.3) (LLDPE), and in particular with very low density (density <915 kg/dm.sup.3) (VLDPE), grafted particularly with styrene/maleic anhydride.These polyethylenes are very good impact modifiers with a high UV resistance and a high degree of toughness and do not cause discoloration of the polyamides and polyesters modified with them. They can be prepared in a simple and economically efficient manner with a high degree of conversion.These polyethylenes are also highly suited as impact modifiers, adhesives or adhesive layers, heat-seal layers, bonding layers in composite films, compatibility enhancement agents as well as bonding promotors, or as components of such agents or layers.Graft-modified polyethylene can be prepared by converting a linear low-density polyethylene with the grafting material at at temperature higher than 110.degree. C.
    Type: Grant
    Filed: February 7, 1991
    Date of Patent: January 19, 1993
    Assignee: Stamicarbon B.V.
    Inventor: Hubertus J. Vroomans
  • Patent number: 5157064
    Abstract: The invention relates to a stabilized polyamide 4.6 composition, which includes copper in the form of a water insoluble copper salt and a halogen-substituted organic compound.
    Type: Grant
    Filed: March 27, 1990
    Date of Patent: October 20, 1992
    Assignee: Stamicarbon B.V.
    Inventor: Pieter Gijsman
  • Patent number: 5102608
    Abstract: A process for the manufacture of objects by injection molding and/or compression molding starting from polycarbonate powder. The process is suitable for, inter alia, the manufacture of carriers for optically readable information such as audio and video discs.
    Type: Grant
    Filed: January 3, 1991
    Date of Patent: April 7, 1992
    Assignee: Stamicarbon B.V.
    Inventors: Eduard J. Frencken, Martin J. P. Flinsenberg
  • Patent number: 5102594
    Abstract: The invention relates to a process for the processing of a thermoplastic polycondensation polymer by supplying the polymer in finely distributed form to a first vented extruder in which the polymer is devolatilized at a temperature below its melting temperature. The polymer is then placed in a second extruder where the polymer is transported below the melting temperature of the polymer over a first length of the screw from the inlet of the extruder, with constant evacuation of volatile components by means of a vacuum exhausting device at a vacuum of less than 10 mbar and the polymer is compressed and melted over a second length of the screw and then leaves the extruder as an end product of a semimanufacture.
    Type: Grant
    Filed: January 10, 1990
    Date of Patent: April 7, 1992
    Assignee: Stamicarbon B.V.
    Inventors: Rudolf J. H. Burlet, Jozef M. H. Lemmens
  • Patent number: 5103003
    Abstract: The invention relates to 3-(1,3-oxazolidinyl)-s-triazine and the preparation thereof by the reaction of the corresponding N-(2-hydroxethyl)melamine with formaldehyde. Di- and tri-3-(1,3-oxazolidinyl)-s-triazine in particular can be used with advantage as cross-linking agents in polymerization reactions in which no volatile reaction products may be formed.
    Type: Grant
    Filed: March 29, 1990
    Date of Patent: April 7, 1992
    Assignee: Stamicarbon B.V.
    Inventor: Veronika M. L. J. Aarts
  • Patent number: 5102742
    Abstract: The invention relates to a resin composition for substantially solvent-free paint compositions. The resin composition is a reaction product on the basis ofA) one or more polyalcohols entirely or partly esterified with unsaturated fatty acids,B) an unsaturated compound with fewer than 20 carbon atoms andC) one or more compounds with at least one copolymerizable terminal ethylene group,the molar ratio of A) and C) is between 0.8:1.2 and 1.2:0.8 and the amount of copolymerizable unsaturated compound C) being substantially the same before and after the reaction of A) and C).
    Type: Grant
    Filed: July 26, 1991
    Date of Patent: April 7, 1992
    Assignee: Stamicarbon B.V.
    Inventors: Adriaan Hoflan, Dick A. Pons
  • Patent number: 5101036
    Abstract: The invention relates to a process for the preparation of N-hydroxy-alpha-amino acids and the derivatives thereof by reacting a derivative of an alpha-amino acid with an aromatic aldehyde to form a Schiff base, oxidizing the Schiff base to an oxaziridine and converting the oxaziridine into the corresponding N-hydroxy-alpha-amino acid derivative and, if so desired, converting that derivative into the acid or a different derivative, in which an alpha-amino acid amide is used as starting material.
    Type: Grant
    Filed: September 20, 1990
    Date of Patent: March 31, 1992
    Assignee: Stamicarbon B.V.
    Inventors: Johan Kamphuis, Wilhelmus H. J. Boesten
  • Patent number: 5096972
    Abstract: The invention relates to a graft copolymer obtainable by reacting a rubbery base polymer, which has been provided with hydroperoxide groups via photo-oxidation, with one or more radical-polymerizable graft monomers, the graft copolymer being based upon 90-20 parts of a rubbery base polymer containing at least 4 (four) hydroperoxide groups per rubber chain and 80-10 parts of one or more of the graft monomers.
    Type: Grant
    Filed: November 2, 1989
    Date of Patent: March 17, 1992
    Assignee: Stamicarbon B.V.
    Inventors: Herman A. J. Schepers, Rene H. M. Seevens
  • Patent number: 5096986
    Abstract: The subject invention relates to a process for preparing a polymer substantially formed from ethylene modified with at least one linear .alpha.,.omega.-diene. In particular, the process involves reacting ethylene with the at least one diene in an inert dispersant. The reaction is carried out in the presence of a magnesium, aluminum, and titanium- and/or vanadium-containing catalyst at a polymerization temperature of at least 135.degree. C. The at least one diene utilized has at least 7 carbon atoms, two non-conjugated double bonds, and is at least 0.001 mole % but less than 0.1 mole % of the total polymer. Furthermore, the at least one diene must be present in an amount small enough such that the activation energy of the viscous flow of the polymer formed is not significantly influenced by the presence of the diene.
    Type: Grant
    Filed: June 2, 1989
    Date of Patent: March 17, 1992
    Assignee: Stamicarbon B.V.
    Inventors: Georges G. Evens, Johannes Tijssen, Luc M. C. Coosemans
  • Patent number: 5093386
    Abstract: A liquid photocurable plastic composition is disclosed which comprises:(a) from 14% to 70% by weight of a polyurethane (meth)acrylate having a polyoxyalkylene structure in the backbone of the polyurethane, said polyurethane (meth)acrylate containing 0.8 to 8 weight percent of ethylenic unsaturation, from 50% to 98% by weight of the polyoxyalkylene structure, and having a number average molecular weight of 1,000 to 7,000;(b) from 5% to 40% by weight of a polyurethane (meth)acrylate having at least 15% by weight of a tricyclodecane structure in the backbone of the polyurethane and a number average molecular weight of from 500 to 1,000;(c) a reactive diluent; and(d) a polymerization initiator.
    Type: Grant
    Filed: March 5, 1991
    Date of Patent: March 3, 1992
    Assignee: Stamicarbon B.V.
    Inventors: Timothy E. Bishop, Tohru Ohtaka, Osamu Ishikawa, Masanobu Takahashi, Katsutoshi Igarashi