Abstract: A process of producing hydrogen cyanide from crude acetonitrile comprising contacting the crude acetonitrile with an ammoxidation catalyst at an elevated temperature in the presence of an oxygen containing gas and ammonia. Preferably, the process is performed in the absence of propylene.

Abstract: Disclosed is a process for the partial oxidation of propane to yield acrylic acid, propylene, acrolein and acetic acid by contacting propane in admixture with a molecular oxygen-containing gas in a reaction zone with an oxidic solid catalyst that1) contains the components and proportions represented by the empirical formulaBi.sub.b Mo.sub.c V.sub.v A.sub.a D.sub.d E.sub.e O.sub.xwhereinA is one or more of K, Na, Li, Cs and Tl,D is one or more of Fe, Ni, Co, Zn, Ce and La,E is one or more of W, Nb, Sb, Sn, P, Cu, Pb, B, Mg, Ca and Sr,a, d and e are each zero-10b is 0.1-10c is 0.1-20v is 0.1-10c:b is from 2:1 to 30:1v:b is from 1.5:1 to 8:1and2) is made by performing a bismuth molybdate containing composition having at least 0.67 atoms of Mo per atom of Bi, before combining with any vanadium compound.

Abstract: A method for preparing silazane polymers is disclosed which comprises reacting under transamination conditions:(A) one or more silicon amides represented by the general formula:((R.sup.1).sub.2 N).sub.a -Si(R).sub.bwherein each R is independently hydrogen or a hydrocarbon group, a is an integer from two to four, b is an integer from zero to two and the sum of a and b equals four; with(B) one or more polymers.Also, disclosed are the silazane polymers produced by this method and silicon ceramics produced from these polysilazanes.

Abstract: The invention relates to novel suppressants for unsaturated polyester styrenated resins resulting in lower emission of volatile compounds in the production of the polyester resins.

Abstract: Maleic anhydride is hydrogenated to produce 1,4-butanediol in a two-stage process. In the first stage maleic anhydride and/or maleic acid contacted with hydrogen at a temperature of about 100.degree. C. to about 350.degree. C. in the presence of a suitable hydrogenation catalyst to produce succinic anhydride and/or gamma-butyrolactone. In the second stage, the succinic anhydride and/or gamma-butyrolactone and hydrogen are contacted at a temperature of about 180.degree. C. to about 350.degree. C. in the presence of a ruthenium-containing hydrogenation catalyst to produce 1,4-butanediol.

Abstract: A process is disclosed which limits the corrosion of the materials of construction of a wet oxidation system treating wastewaters. The process is particularly useful in the wet oxidation treatment of ammonium sulfate containing wastes such as acrylonitrile wastewaters. The wastewater is mixed with an oxygen containing gas such that a substantial residual oxygen gas concentration is maintained from before the stream-gas mixture is heated for wet oxidation until after the oxidized stream-gas mixture is cooled and separated. Preferably, in the treatment of acrylonitrile waste water the shutdown procedure comprises cooling said waste stream by introducing an aqueous liquid substantially free of organic impurities and containing a basic material.

Abstract: This invention provides for a process for separating extractable organic material from a feed composition comprising an oil-in-water emulsion comprising a continuous aqueous phase, a discontinuous organic liquid phase comprising said extractable organic material, and solids dispersed in said emulsion, the process comprising the steps of:(I) mixing said feed composition with sufficient shear to convert said feed composition to a water-in-oil emulsion; and(II) contacting said water-in-oil emulsion with at least one organic solvent, said organic solvent being capable of forming with said emulsion a system comprising at least two phases and being capable of dissolving at least about ten parts of said extractable organic material per million parts of said organic solvent at the temperature wherein at least about 50% by weight of said solvent boils at atmospheric pressure; forming a system comprising at least two phases, one of said phases being an emulsion phase comprising said emulsion and the other of said phase

Abstract: Catalysts having the general formula:V.sub.1 Bi.sub.a Sb.sub.b Fe.sub.c X.sub.d Y.sub.c Z.sub.f O.sub.gwherein,X=Mo, Cu, W, Nb, Te, P, Sn, Ge, AsY=Co, Ni, Ce, La, Mn, CrZ=Alkali, alkaline earth, B, Tl and,a=0.1-10,b=0.01-20,c=0.01-5,d=0-5,e=o-3,f=0-1, and g is determined by the valance requirements of the elements present,are produced by first forming and calcining an iron-antimony oxide composition which is subsequently combined with compounds of vanadium, bismuth and other elements. The catalysts are useful in the formation of phthalonitriles from the reaction of xylenes with oxygen and ammonia at elevated temperatures.

Abstract: A process for producing a dialkyl ester (i.e. BTDE) from its corresponding dianhydride (i.e., BTDA) comprising mixing the dianhydride, an organic solvent, solid catalyst and an alcohol capable of reacting with the dianhydride stirring the solution until the dianhydride and alcohol have reacted to form the dialkyl ester, separating the dialkyl ester from the catalyst and drying the ester to form a solid paticulate product. The product has a purity of over 85%.

Abstract: A method for the treatment of fluid feedstreams comprises the steps of providing at least one wafer (200) comprising a central area (202) providing a plurality of members (18) arranged in a plurality of layers (201) and peripheral support means (203) encompassing the central area, arranged axially in a module (180) having first and second ports (185, 208); a plurality of separate bore fluid chambers (198, 199) generally encompassing the peripheral support means and communicable with the members within the central area, and a plurality of separate bore fluid ports (192, 193) communicable with the bore fluid chambers; directing the feedstream through the first port and over the wafer; and transferring materials between the central area in the wafer and the feedstream. Related methods employ other multi port apparatus (220, 240) as well as wafers (240, 280, 300, 320, 350, 410, 460) for use therein.

Abstract: Olefins such as propylene and isobutylene are converted to the corresponding unsaturated nitriles, acrylonitrile, and methacrylonitrile, respectively, by reacting a mixture of the olefin, ammonia, and molecular oxygen-containing gas in the presence of a catalyst containing the oxides of bismuth, molybdenum, iron, nickel and magnesium, at least one element selected from the group comprising potassium and cesium, and optionally one element selected from the group comprising cobalt, phosphorus, manganese, tellurium, sodium, cerium, chromium, antimony and tungsten wherein the sum of cesium and potassium is at least 0.1 to 0.

Abstract: Disclosed is a process for making an .alpha., .beta.-unsaturated mononitrile by the catalytic reaction of a paraffin containing 3-5 carbon atoms with molecular oxygen and ammonia by catalytic contact of the foregoing reactants in a reaction zone with a metal oxide catalyst containing the elements indicated by the empirical formula,Cr.sub.a Mo.sub.b Te.sub.c M.sub.d O.sub.x (formula 1)whereM=one or more of Mg, Ni, Sb, Ti, La, P, Ce, Fe, Nb, W, V, and Cu, each of a, b & c is 0.1 to 10d is zero to 10a+b+c>1.5d, andx is determined by the valence requirements of the other elements present, andwherein the reactants fed to the reaction zone contain a mole ratio of said paraffin:NH.sub.3 in the range from 2.5 to 16 and a mole ratio of said paraffin:O.sub.2 in the range from 1 to 10.

Abstract: A process for adhering high nitrile resins onto a plastic material. The process comprises the steps of selecting a high nitrile resin having a nitrile content of at least about 60 percent by weight and prepared by the copolymerization of an olefinically unsaturated monovinyl nitrile and a monovinyl monomer copolymerizable therewith in the presence of a conjugated diene rubber, preparing a solution comprising from about one to 70 percent by weight of the high nitrile resin in a photopolymerizable solvent comprising from about 30 to 99 percent by weight of the solution and from about 0.

Abstract: A fiber-optic sensor is formed from three optical fibers. The distal ends of the fibers are optically linked by bonding their cores and directing their ends to mirrors. A portion of one of the fibers near the bonded point is exposed directly to the fluid to be sensed. The transmission characteristics of this fiber, the signal fiber, is then affected by the chemical constituents of the fluid. Light directed into the proximal end of one of the other fibers, the input fiber, is split between the signal fiber and the remaining fiber, the reference fiber. The ratio of the light in the signal fiber to the light in the reference fiber provides an indication of the chemical constituents that minimizes errors introduced by factors such as bends in the fibers and temperature.

Abstract: Polymers are disclosed which comprise the reaction product of (A) at least about 60 weight percent of at least one .alpha., .beta.-unsaturated polycarboxylic acid or anhydride; and (B) about 0.5 to about 40 weight percent of at least one acrylamide represented by the formula VI:CH.sup.2 .dbd.C(R.sup.5)C(O)N(R.sup.6)R.sup.7 (VI)wherein R.sup.5, R.sup.6 and R.sup.7 are each independently hydrogen or lower alkyl groups provided that at least one of R.sup.6 and R.sup.7 is a lower hydro-carbyl group, and further provided that the mixture is free of a vinyl sulfonic acid. The monomers react at elevated temperatures to form polycarboxylate scale inhibitors having a number average molecular weight of from about 400 to 10,000. The polymers have particular application in the inhibition of scales during oil field operations, but also may be employed in any environment where deposition of mineral scales is undesirable.

Abstract: A multi port apparatus (220,440) provides for the treatment of material.

Abstract: Coated reinforcement material for metal matrix composites comprising a carbon or silicon-containing reinforcement having a coating of the general formula:A.sub.100-x M.sub.xwherein A is at least one of Y, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu; M is at least one of Mo, W or Re; and x is from about 10 to about 90.

Abstract: Oxygen is separated from an oxygen-containing gas by introducing the gas into a first zone of a gas separation apparatus, the apparatus comprising first and second zones separated by a mixed metal oxide membrane, the membrane having a first surface open to the first zone, a second surface open to the second zone, and an empirical formula ofBiA.sub.x M.sub.y M'.sub.z O.sub.nwhere A is at least one of Mg, Ca, Sr, Ba, Y, Th, U, and the lanthanide elements; M is at least one of Sc, Ti, Cr, Mn, Fe, Ni, Cu and Zn; and M' is at least one of Co, Rh, Pd, Pt or Ru. The oxygen separated from the oxygen-containing gas can be recovered from the second surface of the membrane either as molecular oxygen, or it can be reacted with an oxygen-consuming substance, such as a hydrocarbon gas, which can be introduced into the second zone of the separation apparatus and brought in contact with the second surface of the membrane.

Abstract: The subject invention relates to a coated reinforcement material comprising a SiC reinforcement having a coating of at least three layers, wherein the layers are alternately A-material layers of the general formula:Al.sub.x O.sub.y N.sub.zwherein x is up to about 60 atomic % of the coating;y is from about 20 atomic % to about 55 atomic % of the coating; andz is from about 5 atomic % to about 45 atomic % of the coating, with the proviso that x+y+z=100, and B-material layers comprising a metal alloy, such that the first and last layers of the coating are A-material layers. The invention further relates to a high strength, high temperature performance composite containing the above-specified coated reinforcement.

Abstract: The flame luminosity of a methanol fuel is appreciably enhanced by the addition thereto of at least one azo dye flame luminosity enhancing agent.