Patents Assigned to STOCKHAUSEN GMBH & CO
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Patent number: 7811458Abstract: The invention relates to a method for the accelerated dehydration of sludges in sludge disposal areas, especially of sludges from rivers and harbors, by the exclusive use of anionic polymer flocculants and the use of materials obtained according to the inventive method.Type: GrantFiled: June 4, 2009Date of Patent: October 12, 2010Assignees: Stockhausen GmbH & Co. KG, Detlef Hegeman GmbH & Co. KGInventors: Thorsten Buddenberg, Holger Herrmann, Hartmut Pawel, Otto Schroers, Wolfgang Hoeppner, Volker Hartmann
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Publication number: 20090236562Abstract: The invention relates to a method for the accelerated dehydration of sludges in sludge disposal areas, especially of sludges from rivers and harbors, by the exclusive use of anionic polymer flocculants and the use of materials obtained according to the inventive method.Type: ApplicationFiled: June 4, 2009Publication date: September 24, 2009Applicants: Stockhausen GmbH & Co., KG, Detlef Hegemann GmbH & Co KgInventors: Thorsten Buddenberg, Holger Herrmann, Hartmut Pawel, Otto Schroers, Wolfgang Hoeppner, Volker Hartmann
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Patent number: 7553423Abstract: The invention relates to a method for the accelerated dehydration of sludges in sludge disposal areas, especially of sludges from rivers and harbors, by the exclusive use of anionic polymer flocculants and the use of materials obtained according to the inventive method.Type: GrantFiled: May 28, 2004Date of Patent: June 30, 2009Assignees: Stockhausen GmbH & Co. KG, Detlef Hegemann GmbH & Co KGInventors: Thorsten Buddenberg, Holger Herrmann, Hartmut Pawel, Otto Schroers, Wolfgang Hoeppner, Volker Hartmann
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Patent number: 7241452Abstract: Random three- and four-amino acid copolymers having lengths of 14-, 35- and 50-amino acid residues are provided. Fifty-mers of FEAK were effective inhibitors of MBP 85-99 or proteolipid protein (PLP) 40–60-specific HLA-DR-2-restricted T cell clones. These copolymers efficiently suppressed EAE induced in susceptible SJL/J (H-2s) strain of mice with either whole spinal cord homogenate (WSCH) or with the encephalitogenic epitope PLP 139-151. YFAK 50-mer having a molar ratio of about y 0.8:F 0.2 inhibited binding of biotinylated MBP 85-99 epitope to HLA-DR-2 molecules more efficiently than either unlabeled MBP 85-99 or Copaxone®. YFAK and FAK copolymers efficiently suppressed EAE induced in SJL/J (H-2s) mice with the encephalitogenic epitope PLP 139-151.Type: GrantFiled: September 20, 2001Date of Patent: July 10, 2007Assignee: Stockhausen GmbH & Co. KGInventors: Marcel Veeger, Andreas Klotz, Gerda Maehse, Beatrice Haeusler, Karin Faensen
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Publication number: 20070138106Abstract: The invention relates to a method for the accelerated dehydration of sludges in sludge disposal areas, especially of sludges from rivers and harbors, by the exclusive use of anionic polymer flocculants and the use of materials obtained according to the inventive method.Type: ApplicationFiled: May 28, 2004Publication date: June 21, 2007Applicants: STOCKHAUSEN GMBH & CO, Detlef Hegemann GMBH & Co. KgInventors: Thorsten Buddenberg, Holger Herrmann, Hartmut Pawel, Otto Schroers, Wolfgang Hoeppner, Volker Hartmann
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Publication number: 20070003462Abstract: The invention relates to methods and a device for the removal of non-water soluble substances from solutions of aqueous metal extracts, by addition of at least one water-soluble cationic polyelectrolyte, containing a diallylaminoalkyl(meth)acrylamide, neutralized or quaternised with mineral acid and subsequently polymerized, preferably dimethylaminopropylacrylamide.Type: ApplicationFiled: July 31, 2006Publication date: January 4, 2007Applicant: Stockhausen GmbH & Co. KGInventor: Detlef Kuboth
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Patent number: 7078560Abstract: A process for the preparation of aminoalkyl (meth)acrylates by transesterification from C1–C4-alkyl (meth)acrylates and aminoalcohols is described, in which process the transesterification is carried out in the presence of at least one distannoxane of the general formula (1) wherein R=linear, cyclic or branched alkyl radical having from 1 to 6 carbon atoms, phenyl radical, and the radicals R may be identical or different from one another, Y=halogen, preferably Cl, Br; pseudo-halogen, preferably SCN; OH, OAc or OR, the radicals Y being identical or different from one another, as catalyst, and the use of the aminoalkyl (meth)acrylates prepared according to the process in the preparation of cationic monomers.Type: GrantFiled: November 8, 2004Date of Patent: July 18, 2006Assignee: Stockhausen GmbH & Co. KGInventors: Jochen Houben, Ralph Eickwinkel, Oliver Hoppe, Bernd Kubiak, Erich Kuester
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Patent number: 7052775Abstract: A process for producing cellulosic formed materials having high water retention capacity according to the dry-wet extrusion process by producing a solution of 5 to 20 wt.-% of cellulose in a hydrous tertiary amine oxide, extruding the solution, stretching the extrudate in a non-precipitating medium, and precipitating the formed materials in an aqueous or alcoholic precipitating bath, characterized by extruding a solution including 0.01 to 250 wt.-%, relative to cellulose, of at least one superabsorbent polymer having a grain size of ?100 ?m. The fibers, films, and composite materials being formed are remarkable for their high water retention capacity and are suitable in the production of hygiene products, baby or disposable diapers, sanitary towels, tampons, incontinence articles, absorbent patches, wound dressings, strappings, bandages, absorbent cloths, moisture-absorbing clothing, bed mattings, filter materials or filters, packaging materials, or cable sheathings.Type: GrantFiled: July 31, 2002Date of Patent: May 30, 2006Assignee: Stockhausen GmbH & Co. KGInventors: Waldemar Dohrn, Reiner Buettner, Ingo Notz, Georg Werner, Carmen Knobelsdorf, Edgar Herrmann, Michael Schuemann
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Patent number: 7030199Abstract: The invention relates to a process for producing water-soluble or water-swellable polymer products from acrylic acid and/or acrylic acid derivatives partially or completely neutralized with nitrogen compounds and with exceedingly low levels of residual monomers, which process is characterized by subsequent heating of the polymer product at temperatures of from 120 to 240° C. The polymers produced accordingly are suitable for use as flocculants, dispersants and absorbers.Type: GrantFiled: November 13, 1998Date of Patent: April 18, 2006Assignee: Stockhausen GmbH & Co. KGInventors: Miroslav Chmelir, Kurt Dahmen
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Patent number: 6979748Abstract: A process for the preparation of aminoalkyl (meth)acrylates by transesterification from C1-C4-alkyl (meth)acrylates and aminoalcohols is described, in which process the transesterification is carried out in the presence of at least one distannoxane of the general formula (1) wherein R=linear, cyclic or branched alkyl radical having from 1 to 6 carbon atoms, phenyl radical, and the radicals R may be identical or different from one another, Y=halogen, preferably Cl, Br; pseudo-halogen, preferably SCN; OH, OAc or OR, the radicals Y being identical or different from one another, as catalyst, and the use of the aminoalkyl(meth)acrylates prepared according to the process in the preparation of cationic monomers.Type: GrantFiled: June 1, 2001Date of Patent: December 27, 2005Assignee: Stockhausen GmbH & Co. KGInventors: Jochen Houben, Ralph Eickwinkel, Oliver Hoppe, Bernd Kubiak, Erich Kuester
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Patent number: 6958429Abstract: The invention relates to absorbent polymers based on optionally partially neutralised, monoethylenically unsaturated, acid group-carrying monomers. The surfaces of said polymers are re-cross-linked. The inventive polymers also have cyclodextrines and/or cyclodextrine derivatives which are covalently and/or ionically bonded and/or included therein.Type: GrantFiled: February 11, 2004Date of Patent: October 25, 2005Assignee: Stockhausen GmbH & Co. KGInventors: Christoph Bruhn, Edgar Herrmann, Jörg Issberner, Dagmar Kersten, Richard Mertens, Georg Werner
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Patent number: 6946189Abstract: The invention relates to a substrate provided with super-absorbent material to be manufactured by allowing suitable monomers to polymerize in the presence of a catalyst in order to obtain a polymer solution, adding a cross-linking agent to the polymer solution to obtain a pasty composition, subsequently applying the composition on or in a substrate and allowing the applied composition to dry and cross-link in order to obtain the substrate with the super-absorbent material. The pasty composition further contains other additives. The invention further relates to a method for manufacturing such a substrate. The substrates can be used as sheathing material in cables, in hygiene products such as baby napkins, sanitary towels and incontinence products, in or as packagings and packaging materials and in agricultural substrates. The invention also relates to such products.Type: GrantFiled: December 6, 1999Date of Patent: September 20, 2005Assignee: Stockhausen GmbH & Co. KGInventor: Aalbertus Pieter Kroesbergen
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Patent number: 6911572Abstract: The invention relates to absorbent polymers based on optionally partially neutralised, monoethylenically unsaturated, acid group-carrying monomers. The surfaces of said polymers are re-cross-linked. The inventive polymers also have cyclodextrines and/or cyclodextrine derivatives which are covalently and/or ionically bonded and/or included therein.Type: GrantFiled: May 28, 1999Date of Patent: June 28, 2005Assignee: Stockhausen GmbH & Co. KGInventors: Christoph Bruhn, Edgar Herrmann, Jörg Issberner, Dagmar Kersten, Richard Mertens, Georg Werner
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Patent number: 6906131Abstract: An absorbent cellulose material having an application of superabsorbent polymer adhered to the cellulose material. In particular, the cellulose material has an application of pre-superabsorbent polymer adhered to the material, wherein an aqueous solution of pre-superabsorbent polymer is applied to the cellulose material and converted to superabsorbent polymer upon subjected to heat for a sufficient time. The absorbent cellulose material has a fluid retention of greater then 2g/g.Type: GrantFiled: September 17, 2001Date of Patent: June 14, 2005Assignee: Stockhausen GmbH & Co. KGInventors: Iqbal Ahmed, Angela Marie Jones, Scott J. Smith
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Publication number: 20050085660Abstract: A process for the preparation of aminoalkyl (meth)acrylates by transesterification from C1-C4-alkyl (meth)acrylates and aminoalcohols is described, in which process the trans-esterification is carried out in the presence of at least one distannoxane of the general formula (1) wherein R=linear, cyclic or branched alkyl radical having from 1 to 6 carbon atoms, phenyl radical, and the radicals. R may be identical or different from one another, Y=halogen, preferably Cl, Br; pseudo-halogen, preferably SCN; OH, OAc or OR, the radicals Y being identical or different from one another, as catalyst, and the use of the aminoalkyl (meth)acrylates prepared according to the process in the preparation of cationic monomers.Type: ApplicationFiled: November 8, 2004Publication date: April 21, 2005Applicant: Stockhausen GmbH & Co. KGInventors: Jochen Houben, Ralph Eickwinkel, Oliver Hoppe, Bernd Kubiak, Erich Kuester
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Publication number: 20050074614Abstract: The invention relates to an absorbent insert for foodstuff packagings, the liquid-absorbing component of which is a superabsorbent polymer which, in a hitherto unrivaled fashion, persistently absorbs and retains large quantities of liquid even under high pressure load, protects the foodstuffs from bacterial decay, and prevents contamination of the packagingd goods by migrating soluble constituents of the polymer. This combination of properties of the superabsorbers used is expressed by the QSAP 0.3 quotient of retention according to the tea bag test+absorption against pressure (AAP) 0.3, divided by the amount of solubles (LA), which quotient is at least 20. Superabsorbers having such properties are obtained by using special combinations of crosslinkers. Furthermore, the invention relates to a process for producing said absorbent inserts and their use in foodstuff packagings, as ice substitute, and as leak-proofing means in transport packagings.Type: ApplicationFiled: September 8, 2003Publication date: April 7, 2005Applicant: Stockhausen GmbH & Co. KGInventors: Gerd Jonas, Helmut Klimmek, Frank Krause, Klaus Pfluger
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Patent number: 6863978Abstract: The present invention relates to a pulverulent polymer post-crosslinked on the surface and absorbing water or aqueous liquids, synthesised from polymerised, optionally pre-crosslinked monomers containing partially neutralised carboxyl groups. The present invention also relates to a process for the post-treatment of the aforementioned polymers and the use of a solution of at least one salt of an at least trivalent cation for restoring the gel permeability of the aforementioned polymers that have been damaged by mechanical action.Type: GrantFiled: September 27, 2002Date of Patent: March 8, 2005Assignee: Stockhausen GmbH & Co. KGInventors: Waldemar Inger, Rudiger Hose, Heinz-Peter Bohlmann
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Patent number: 6861469Abstract: The invention relates to water-in-oil polymer dispersions consisting of a continuous organic phase and water-soluble polymers finely distributed therein, wherein said polymers have a radical monomer content of less than 1,000 ppm. The invention also relates to a method for producing the inventive polymer dispersions and to their use of flocculation auxiliary agents, thickening agents and as additives for phytosanitary and anti-erosion agents.Type: GrantFiled: August 8, 2001Date of Patent: March 1, 2005Assignee: Stockhausen GmbH & Co. KGInventors: Bernd Diener, Veronika Gehler, Erich Küster, Daniel Roulands, Dieter Werhahn
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Patent number: 6841229Abstract: A superabsorbent polymer comprising a delayed absorption superabsorbent polymer having a free water absorbency property of absorbing less than about 3 grams of aqueous saline per gram of superabsorbent polymer in about 6 seconds, for a full particle size distribution of superabsorbent polymer ranging from about 40 micrometers to about 890 micrometers.Type: GrantFiled: November 21, 2002Date of Patent: January 11, 2005Assignee: Stockhausen GmbH & Co. KGInventors: Fang Sun, Bernfried A. Messner, Heather S. Jones
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Patent number: 6831142Abstract: The invention relates to absorptive, crosslinked polymers which are based on partly neutralized, monoethylenically unsaturated monomers carrying acid groups, and have improved properties, in particular in respect of their capacity for transportation of liquids in the swollen state, and which have been after-crosslinked on their surface at temperatures of at least 150° C. with a combination of polyol as after-crosslinking compound and a cation in the form of an aqueous solution.Type: GrantFiled: March 4, 2003Date of Patent: December 14, 2004Assignee: Stockhausen GmbH & Co. KGInventors: Richard Mertens, Harren Jörg