Patents Assigned to Styrolution GmbH
-
Publication number: 20150291793Abstract: Thermoplastic molding compositions comprising: a) 3 to 91.8 wt % of at least one polyamide, as component A, b) 3 to 91.8 wt % of one or more styrene copolymers B without any maleic anhydride-derived units, c) 3 to 91.8 wt % of one or more impact-modifying grafted rubbers C, d) 0.2 to 1.5 wt % of a compound of formula (I), as component D: e) 0 to 0.9 wt % of a mixture of formula (II), as component E: f) 0 to 0.9 wt % of a further stabilizer component F, g) 1 to 25 wt % of one or more styrene copolymers G, h) 1 to 30 wt % of one or more further rubbers, exhibit improved weathering resistance.Type: ApplicationFiled: September 3, 2012Publication date: October 15, 2015Applicant: STYROLUTION GMBHInventors: Rolf Minkwitz, Martin Weber, Marko Blinzler, Wenke Wollny
-
Publication number: 20150065622Abstract: Thermoplastic molding compositions comprising the following components: a) 3 to 91.7 wt % of at least one aromatic polycarbonate, as component A b) 3 to 91.7 wt % of one or more styrene copolymers, as component B c) 3 to 91.7 wt % of one or more impact-modifying grafted rubbers without olefinic double bonding in the rubber plase, as component C, and also d) 0.2 to 0.9 wt % of a compound of formula (I), as component D: e) 0 to 0.9 wt % of a mixture of formula (II), as component E: n=2 to 20 f) 0 to 0.9 wt % of a triazine stabilizer, and also, optionally further components, with the proviso that when component E amounts to 0 wt %, at least one further stabilizer is present in an amount of 0.01 to 0.9 wt %, have good weathering properties.Type: ApplicationFiled: September 3, 2012Publication date: March 5, 2015Applicant: STYROLUTION GMBHInventors: Rolf Minkwitz, Alexander Ludwig, Kerim Wewer, Rainer Huebner
-
Patent number: 8889767Abstract: The thermoplastic molding composition comprises a) as component A, from 3 to 78% by weight of one or more styrene copolymers which have no units derived from maleic anhydride, b) as component B, from 15 to 90% by weight of one or more polyamides, c) as component C, from 5 to 50% by weight of one or more impact-modifying graft rubbers without olefinic double bonds in the rubber phase, d) as component D, from 1 to 25% by weight of one or more styrene copolymers which have, based on the entire component D, from 0.5 to 5% by weight of units derived from maleic anhydride, e) as component E, from 1 to 30% by weight of one or more further rubbers based on olefinic monomers without core-shell structure, and having at least 0.1% by weight of functional monomers, f) as component F, from 0 to 50% by weight of one or more fibrous or particulate fillers, g) as component G, from 0 to 40% by weight of further additives, where the entire amount of components A to E and, if appropriate, F and G is 100% by weight.Type: GrantFiled: January 29, 2010Date of Patent: November 18, 2014Assignee: Styrolution GmbHInventors: Martin Weber, Marko Blinzler, Christian Schweiger, Christoph Schneidereit
-
Patent number: 8853319Abstract: The thermoplastic molding composition comprises: a) as component A, from 0 to 97.9% by weight of one or more (methyl)styrene-acrylonitrile copolymers which do not have any units derived from maleic anhydride, and which have an intrinsic viscosity smaller than 85 ml/g, b) as component B, from 1 to 98.9% by weight of one or more (methyl)styrene-acrylonitrile copolymers which have, based on the entire component B, from 0.5 to 5% by weight of units derived from maleic anhydride, c) as component C, from 1 to 75% by weight of glass fibers, d) from 0.1 to 20% by weight of one or more flow promoters, selected from d1) as component D1, at least one highly branched or hyperbranched polycarbonate with an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, part 2), d2) as component D2, at least one highly branched or hyperbranched polyester of AxBy type, where x is at least 1.1 and y is at least 2.Type: GrantFiled: May 6, 2010Date of Patent: October 7, 2014Assignee: Styrolution GmbHInventors: Martin Weber, Marko Blinzler, Roelef Van Der Meer
-
Patent number: 8835560Abstract: Elastomeric block copolymers having star-shaped molecular architecture, where the star-shaped molecular architecture has at least two different arms of the star, a process for producing the elastomeric block copolymers, the use of the elastomeric block copolymers for producing moldings, or as adhesive layer in multilayer foils; as seal; as adhesion promoter or thermoplastic component in wood-plastics composites; as hot-melt adhesive component; for impact-modifying thermoplastics or elastomers, or for compatibilization, and to foils, foams, thermomoldings, injection moldings, flexible tubing, or profile extrudates composed of at least one elastomeric block copolymer.Type: GrantFiled: October 27, 2011Date of Patent: September 16, 2014Assignee: Styrolution GmbHInventors: Konrad Knoll, Daniel Wagner, Andrea Colombo, Geert Verlinden
-
Patent number: 8759445Abstract: A mixture which comprises a) from 5 to 95% by weight of a copolymer A which comprises one or more copolymer blocks (B/S)A each composed of from 65 to 95% by weight of vinylaromatic monomers and from 35 to 5% by weight of dienes and of a glass transition temperature TgA in the range from 40° to 90° C., b) from 95 to 5% by weight of a block copolymer B which comprises at least one hard block S composed of from 95 to 100% by weight of vinylaromatic monomers and of from 0 to 5 by weight of dienes, and comprises one or more copolymer blocks (B/S)A each composed of from 65 to 95% by weight of vinylaromatic monomers and of from 35 to 5% by weight of dienes and of a glass transition temperature TgA in the range from 40° to 90° C., and comprises one or more copolymer blocks (B/S)B each composed of from 20 to 60% by weight of vinylaromatic monomers and of from 80 to 40% by weight of dienes and of a glass transition temperature TgB in the range from ?70° to 0° C.Type: GrantFiled: June 23, 2009Date of Patent: June 24, 2014Assignee: Styrolution GmbHInventors: Matthias Müller, Konrad Knoll, Christof Mehler, Helmut Steininger, Norbert Güntherberg, Daniel Wagner, Michael Schuster, Geert Verlinden, Florian Greger
-
Patent number: 8748527Abstract: The present invention relates to a mixture, comprising at least one thermoplastic polymer as component (A) and at least one photocatalytically active particle, comprising a non-porous core comprising at least one metal oxide or semimetal oxide with a diameter of from 0.1 nm to 1 ?m, and, at least to some extent surrounding the core, at least one porous outer layer comprising at least one further metal oxide or further semimetal oxide with an average layer thickness of from 0.1 to 10 nm, as component (B), to a process for the production of this mixture according to any of claims 1 to 5, via mixing of components (A) and (B), to the use of the mixture as photocatalytically active surface, to moldings, comprising this mixture, and to the use of this mixture for the production of moldings.Type: GrantFiled: February 25, 2010Date of Patent: June 10, 2014Assignee: Styrolution GmbHInventors: Leonie Felicitas Braun, Alexandra Seeber, Dirk Klingler
-
Patent number: 8657921Abstract: A shell-and-tube heat exchanger, for removing volatile substances from a polymer solution by degasification, includes a bundle of tubes arranged vertically and parallel to each other in a shell chamber through which a fluid heat-transfer medium flows. The upper end of each tube is fixed in an upper tube sheet and the lower end of each tube is fixed in a lower tube sheet, and the polymer solution flows through the tubes in the direction of gravity. One feature is that a multilayer woven wire fabric is attached to the top of the upper tube sheet. The finest meshed layer of the fabric has a mesh width of 50 ?m to 1000 ?m. The invention also relates to a method for removing volatile substances from a polymer solution by degasification in a shell-and-tube heat exchanger and use of the shell-and-tube heat exchanger.Type: GrantFiled: April 27, 2010Date of Patent: February 25, 2014Assignee: Styrolution GmbHInventors: Norbert Güntherberg, Rainer Bardon, Hartmut Heinen, Michael Sauer, Ludger Leber, Wolfgang Fischer
-
Patent number: 8648143Abstract: Processes for producing thermoplastic molding compositions, which comprise a) from 3 to 79% by weight of one or more (methyl)styrene-acrylonitrile copolymers, which have no maleic-anhydride-derived units, b) from 15 to 91% by weight of one or more polyamides, c) from 5 to 50% by weight of one or more rubbers, d) from 1 to 25% by weight of one or more compatibilizers, e) from 0 to 2% by weight of one or more low-molecular-weight compounds which comprise a dicarboxylic anhydride group, f) from 0 to 50% by weight of one or more fibrous or particulate fillers, and g) from 0 to 40% by weight of further additives, by producing a melt comprising components A, B, and C in a first step and subsequently incorporating D, Also, thermoplastic molding compositions obtainable by these processes, the use of these thermoplastic molding compositions, and moldings, fibers, and foils comprising these thermoplastic molding compositions.Type: GrantFiled: July 12, 2012Date of Patent: February 11, 2014Assignee: Styrolution GmbHInventors: Martin Weber, Marko Blinzler, Norbert Güntherberg
-
Patent number: 8575269Abstract: A mixture which contains a) a copolymer or block copolymer A comprising one or more copolymer blocks (B/S)A which are respectively composed of from 65 to 95% by weight of vinylaromatic monomers and of from 35 to 5% by weight of dienes, and whose glass transition temperature TgA is in the range from 40° to 90° C., b) a block copolymer B comprising at least one hard block S which is composed of vinylaromatic monomers, and comprising one or more copolymer blocks (B/S)B which are respectively composed of from 20 to 60% by weight of vinylaromatic monomers and of from 80 to 40% by weight of dienes, and whose glass transition temperature TgB is in the range from ?70° to 0° C., c) a polystyrene C, and its use for the production of packaging for electronics components.Type: GrantFiled: September 3, 2008Date of Patent: November 5, 2013Assignee: Styrolution GmbHInventors: Konrad Knoll, Jürgen Koch, Piyada Charoensirisomboon, Daniel Wagner
-
Patent number: 8545953Abstract: A blow molding having capacity of at least 250 ml, having a shell which is composed of impact-resistant polystyrene and which is produced via injection stretch blow molding where an average aspect ratio of rubber particles derived from longitudinal section and an average aspect ratio of rubber particles derived from cross section measured in transmission electron micrographs is greater than 4 respectively, and a biaxial orientation of the rubber particles, given by the ratio of the aspect ratio derived from cross section to the aspect ratio derived from longitudinal section is smaller than 3.Type: GrantFiled: December 17, 2007Date of Patent: October 1, 2013Assignee: Styrolution GmbHInventors: Stefan Burgdörfer, Walter Heckmann, Hans-Jürgen Renner, Christian Schade, Hans-Dieter Schwaben
-
Patent number: 8536279Abstract: A block copolymer or graft copolymer with weight-average molar mass Mw of at least 100 000 g/mol, comprising a) at least one block S composed of from 95 to 100% by weight of vinylaromatic monomers and from 0 to 5% by weight of dienes, and b) at least one copolymer block (S/B)A composed of from 63 to 80% by weight of vinylaromatic monomers and from 20 to 37% by weight of dienes, with glass transition temperature TgA in the range from 5 to 30° C., where the proportion by weight of the entirety of all of the blocks S is in the range from 50 to 70% by weight, based on the block copolymer or graft copolymer, and also mixtures thereof, and their use.Type: GrantFiled: December 14, 2009Date of Patent: September 17, 2013Assignee: Styrolution GmbHInventors: Konrad Knoll, Jürgen Koch, Piyada Charoensirisomboon, Daniel Wagner, Geert Verlinden, Roland Weidisch
-
Patent number: 8536398Abstract: Processes suitable for purifying aromatic-containing feed streams, and processes using such purified streams are described, wherein the purification processes comprise: (a) providing a process feedstream comprising an aromatic component; and (b) bringing the process feedstream into contact with a first zeolite and a second zeolite; wherein the first zeolite has a mean pore size of 0.3 to 0.5 nm, and wherein the second zeolite has a mean pore size of 0.6 to 0.8 nm.Type: GrantFiled: September 15, 2005Date of Patent: September 17, 2013Assignee: Styrolution GmbHInventors: Rolf Henn, Ulrich Müller, Ferdinand Straub, Jürgen Dosch
-
Patent number: 8501868Abstract: The present invention relates to thermoplastic molding compositions having a mixture of (a) from 10 to 50% by weight of a methyl methacrylate polymer as component (A), from 20 to 60% by weight of a copolymer as component (B), and from 20 to 70% by weight of a graft copolymer as component (C). Component (C) is obtainable from components (c1) a core, (c2) a first graft shell, and (c3) a second graft shell. The second graft shell (c3) is obtainable via polymerization of a C1-C8-alkyl ester of methacrylic acid as component (c31) and a further vinylaromatic monomer as component (c32). Graft copolymer (C) is produced via emulsion polymerization and is isolated from the reaction mixture by precipitation resulting from shear. Also disclosed are processes for producing the molding compositions, the use of the molding compositions, and moldings obtainable from the molding compositions.Type: GrantFiled: March 25, 2011Date of Patent: August 6, 2013Assignee: Styrolution GmbHInventors: Matthias Müller, Ludger Leber, Achim Datko, Leonie Felicitas Braun, Christian Lemaire, Piyada Charoensirisomboon, Michel Pepers
-
Patent number: 8481630Abstract: The invention relates to processes for the production of moldings via shaping of thermoplastic molding compositions F with reduced formation of deposit on the shaping mold, and it is essential to the invention that the thermoplastic molding compositions F comprise an amount of from 0 mg/kg to 100 mg/kg (calculated as the total of the mg of Mg and the mg of Ca per kg of thermoplastic molding composition F and determined by means of atomic emission spectrometry using inductively coupled plasma (ICPAES)) of magnesium compounds and/or calcium compounds; the invention further relates to the use of molding compositions F in the inventive processes, and also to moldings which can be produced by the inventive processes.Type: GrantFiled: December 2, 2008Date of Patent: July 9, 2013Assignee: Styrolution GmbHInventors: Wolfgang Fischer, Moritz Ehrenstein
-
Patent number: 8481624Abstract: The invention relates to a process for the preparation of thermoplastic molding materials comprising A) from 39 to 99% by weight of at least one thermoplastic polymer, B) from 1 to 60% by weight of a flameproofing component comprising B1) an expandable graphite, and C) from 0 to 60% by weight of further additives, the percentages by weight being based in each case on the total weight of the components A) to C) and together giving 100% by weight, by mixing melts of the components A), B) and, if present, C) in a screw extruder, the screw extruder comprising at least one metering zone, one plasticating zone, one homogenization zone and one discharge zone in this sequence along the conveying direction, wherein the metering of the expandable graphite B1) into the screw extruder is effected at a point behind which—viewed in the conveying direction—the extruder screw comprises substantially no shearing elements, and thermoplastic molding materials which can be prepared by these processes, the use of said theType: GrantFiled: September 23, 2008Date of Patent: July 9, 2013Assignee: Styrolution GmbHInventors: Maarten Pieter Bram Staal, Norbert Güntherberg, Piyada Charoensirisomboon, Hartmut Heinen, Norbert Nieβner, Walter Heckmann
-
Patent number: 8470911Abstract: A process is proposed for coagulation of an aqueous polymer dispersion, which comprises, during or after the coagulation, converting the dissolved coagulation salt into an insoluble form.Type: GrantFiled: April 3, 2007Date of Patent: June 25, 2013Assignee: Styrolution GmbHInventors: Chris Dearmitt, Graham Edmund McKee, Konrad Mitulla
-
Patent number: 8440764Abstract: The present invention relates to a molding composition comprising (A) a copolymer containing at least one ?,?-unsaturated monocarbonitrile and at least one aromatic vinyl monomer, (B) a graft rubber with an average particle size of from 100 to 280 nm, composed of at least one ?,?-unsaturated monocarboxylic ester, and at least one graft shell composed of at least one aromatic vinyl monomer and of at least one ?,?-unsaturated monocarbonitrile, (C) a graft rubber with an average particle size of from 410 to 1000 nm, composed of at least one ?,?-unsaturated monocarboxylic ester, and at least one graft shell composed of at least one aromatic vinyl polymer and of at least one ?,?-unsaturated monocarbonitrile, and wherein the ratio by weight of component (B) to component (C) is from 3:1 to 1:1. The invention also relates to the process of producing the molding composition and its use.Type: GrantFiled: May 6, 2011Date of Patent: May 14, 2013Assignee: Styrolution GmbHInventor: Norbert Nieβner
-
Patent number: 8217104Abstract: A mixture which comprises a) from 25 to 75% by weight of a block copolymer A which comprises at least one hard block S composed of vinylaromatic monomers and comprises one or more soft blocks BA in each case composed of from 0 to 5% by weight of vinylaromatic monomers and from 95 to 100% by weight of dienes, where the proportion by weight of the hard blocks S in the block copolymer A is from 65 to 90% by weight; b) from 5 to 25% by weight of a block copolymer B which comprises at least one hard block S composed of vinylaromatic monomers and comprises one or more copolymer blocks (B/S)B in each case composed of from 20 to 60% by weight of vinylaromatic monomers and from 80 to 40% by weight of dienes, where the proportion by weight of the hard blocks S in the block copolymer B is from 25 to 70% by weight; c) from 0 to 70% by weight of polystyrene or of a block copolymer C other than A and B, and d) from 0 to 6% by weight of a plasticizer D, where the entirety of components A) to D) gives 100% by weight, andType: GrantFiled: June 13, 2007Date of Patent: July 10, 2012Assignee: Styrolution GmbHInventors: Jennifer Stewart, Peter Merkel, Daniel Wagner, Konrad Knoll, Jürgen Koch
-
Patent number: 8168719Abstract: The present invention relates to thermoplastic molding compositions comprising a mixture composed of (A) at least one methyl methacrylate polymer, (B) at least one copolymer, obtainable via polymerization of a mixture, composed of (B1) at least one vinylaromatic monomer, and (B2) at least one vinyl cyanide, as monomers, (C) at least one graft polymer, obtainable from a core, and a first graft shell, and a second graft shell, (D) at least one polybutyl acrylate whose molar mass is from 1700 to 4000 g/mol (determined as Mw by means of gel permeation chromatography), and (E) if appropriate conventional additives, as component (E), to a process for preparation of these thermoplastic molding compositions, to the use of this thermoplastic molding composition for production of moldings, and also to the use of styrene-methyl methacrylate copolymers whose molar mass is from 1700 to 4000 g/mol (determined as Mw by means of gel permeation chromatography) for improvement of flowability and for reduction of the dependencyType: GrantFiled: April 23, 2008Date of Patent: May 1, 2012Assignee: Styrolution GmbHInventors: Martin Weber, Achim Datko, Ludger Leber