Patents Assigned to Styron Europe GmbH
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Patent number: 9908144Abstract: A coated paperboard (100) comprising: a base substrate (102) having a brightness of about 65 or less measured using TAPPI T452 and a coating (104) on at least one side of the base substrate, wherein the base substrate comprises: one or more opaque layers (114) including a white filler, wherein the opaque layer covers the base substrate so that visibility of the base substrate through the opaque layer is substantially eliminated; a barrier layer (116) covering the opaque layer; wherein the barrier layer substantially prevents aqueous fluids from contacting the opaque layer, and wherein the coated paperboard has a brightness on the side of the base substrate with the coating of about 65 or more measured using TAPPI T452, and a wet brightness drop, on the side of the base substrate with the coating, of about 30 or less, measured using the wet brightness drop test.Type: GrantFiled: June 22, 2012Date of Patent: March 6, 2018Assignee: Styron Europe GMBHInventors: Pekka Johannes Salminen, Marco Edoardo Ahtinen, Arthas Bing Yang
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Patent number: 9447219Abstract: The ductility/stiffness balance of a rubber-modified monovinylidene aromatic polymer, e.g., HIPS, is increased without increasing the rubber content of the polymer and/or changing the size of the average rubber particle by a process comprising the step of crosslinking the rubber such that the rubber-modified polymer has an optical crosslink index (OCLI) of <0.5 and an injection molded/compression molded (IM/CM) modulus ratio ?1.3.Type: GrantFiled: October 6, 2010Date of Patent: September 20, 2016Assignee: Styron Europe GMBHInventors: Gilbert C. E. Bouquet, Fredericus Slijkerman
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Publication number: 20150322098Abstract: The present invention relates to silane sulfide modifier compounds and methods of making them. The invention also relates to a silane sulfide modified macromolecular compound obtainable by reacting a living anionic elastomeric polymer and a silane sulfide modifier. The silane sulfide modified macromolecular compound may be provided in the form of a polymer composition, and the polymer composition may be vulcanized (cross-linked) by making use of and reaction with at least one vulcanization agent, resulting in a vulcanized polymer composition.Type: ApplicationFiled: September 14, 2012Publication date: November 12, 2015Applicant: STYRON EUROPE GmbHInventor: Sven THIELE
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Publication number: 20150210791Abstract: The invention describes a process for producing a diene polymer, the process comprising the following steps in this order: i) polymerizing one or more diene monomers in the presence of a catalyst composition to give a reaction mixture; ii) adding to the reaction mixture one or more alkoxysilane compounds; iii) adding S2Cl2, SCl2, SOCl2, S2Br2, SOBr2 or a mixture thereof to the reaction mixture; and iv) optionally adding a protic agent to the reaction mixture so as to deactivate the catalyst. The invention further includes polymers that are obtainable according to this process, as well as products including the polymer.Type: ApplicationFiled: February 29, 2012Publication date: July 30, 2015Applicant: STYRON EUROPE GMBHInventors: Thomas D. Ruehmer, Sven Thiele, Anke Schmudde, Dieter Bellgardt
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Publication number: 20150159014Abstract: The present invention relates to a radical scavenging and anti-yellowing composition for polymeric materials and compositions containing the same. The invention further relates to medical devices comprising a composition according to the invention and to a method of sterilizing such devices.Type: ApplicationFiled: August 28, 2012Publication date: June 11, 2015Applicant: STYRON EUROPE GMBHInventors: Bernhard Elbert, Eike Jahnke
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Publication number: 20150111054Abstract: A coated paperboard (100) comprising: a base substrate (102) having a brightness of about 65 or less measured using TAPPI T452 and a coating (104) on at least one side of the base substrate, wherein the base substrate comprises: one or more opaque layers (114) including a white filler, wherein the opaque layer covers the base substrate so that visibility of the base substrate through the opaque layer is substantially eliminated; a barrier layer (116) covering the opaque layer; wherein the barrier layer substantially prevents aqueous fluids from contacting the opaque layer, and wherein the coated paperboard has a brightness on the side of the base substrate with the coating of about 65 or more measured using TAPPI T452, and a wet brightness drop, on the side of the base substrate with the coating, of about 30 or less, measured using the wet brightness drop test.Type: ApplicationFiled: June 22, 2012Publication date: April 23, 2015Applicant: Styron Europe GMBHInventors: Pekka Johannes Salminen, Marco Edoardo Ahtinen, Arthas Bing Yang
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Patent number: 9000109Abstract: A process for polymerization of a polymer containing monomeric units derived from a styrene monomer and a 1,3-butadiene monomer includes polymerizing the monomeric units in the presence of an initiator, a first polar agent, and a second polar agent. The first polar agent includes a structure (I): R1?R2?N-Q-NR3?R4?; and the second polar agent comprises a structure (II): R1?, R2?, R3?, and R4? are each independently selected from the group consisting of an alkyl group and hydrogen; Q contains an alkylene group; R1 and R2 are each independently an alkyl group; and R3, R4, R5, R6, R7 and R8 are each independently selected from the group consisting of an alkyl group and hydrogen. Polymers prepared by the above process are described, as are compositions containing such a polymer, and articles containing at least one component formed from such a composition.Type: GrantFiled: March 1, 2012Date of Patent: April 7, 2015Assignee: Styron Europe GmbHInventors: Evemarie Hamann, Silvia Valenti, Karin Schmiedel
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Patent number: 8998316Abstract: An improved seating system that includes a blow molded seat back assembly that is fabricated to include a seat back comprising a double walled design having a foreword (14) and a rearward (16) wall wherein there is at least one or more sections comprising a single wall (213). Further, the blow molded seat back may include an integrated reinforcement structure.Type: GrantFiled: June 7, 2010Date of Patent: April 7, 2015Assignee: Styron Europe GmbHInventors: Padraig J. Naughton, Ashishkumar S. Lokhande, Gulub N. Malunjkar
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Publication number: 20150087768Abstract: An elastomeric polymer composition formed from a reaction product of a living anionic elastomeric polymer and sulfur containing chain end modifier with the general formula: (RO)x(R)ySi—R?—S—Z wherein O is oxygen, x is an integer selected from 1, 2 and 3; y is an integer selected from 0, 1, and 2; x+y=3, R is the same or different and is: (C1-C16) alkyl; R? is an aryl, an alkylaryl, a (C7-C16) alkyl aryl, or a (C1-C16) alkyl which may be linear or branched, saturated or unsaturated and may be substituted with: (C1-C4) alkyl, (C1-C4) alkoxy, (C7-C16) aryl, (C7-C16) aralkyl, nitrile, amine, NO2, thioalkyl; and Z is a protective group. Methods are described for making the elastomeric polymer composition, their use in preparing vulcanized elastomeric compositions, and articles made from such compositions, including pneumatic tires, tire treads, belts, and the like.Type: ApplicationFiled: September 23, 2013Publication date: March 26, 2015Applicant: STYRON EUROPE GMBHInventors: Sven Thiele, Joachim Kiesekamp, Norbert Jantsch, Thomas Knispel
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Patent number: 8981000Abstract: A polymer has at least the following characteristics: (a) a block styrene content containing 4 to 6 styrene units from about 27 to about 50 weight percent based on total styrene content in the polymer; (b) a vinyl content from about 30 to about 80 weight percent based on total amount of polymerized 1,3-butadiene; and (c) a styrene content from about 40 to about 70 weight percent based on total weight of polymer. Processes for the polymerization of such a polymer, compositions containing such a polymer, and articles containing at least one component formed from such a composition are described.Type: GrantFiled: March 1, 2012Date of Patent: March 17, 2015Assignee: Styron Europe GmbHInventors: Evemarie Hamann, Silvia Valenti, Karin Schmiedel
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Patent number: 8957144Abstract: A polycarbonate resin composition having improved chemical resistance and solvent resistance while maintaining the impact resistance, heat resistance, thermal stability, and the like inherent to the polycarbonate resin which comprises 100 parts by weight of polycarbonate resin and 0.01 to 20 parts by weight of a specific alkyl ketene dimer, and inhibits problems such as cracking, and the like, even when solvents or various chemicals such as hand creams and detergents adhere to the molded article obtained from the resin composition.Type: GrantFiled: December 19, 2013Date of Patent: February 17, 2015Assignee: Styron Europe GmbHInventors: Tadashi Shinomiya, Keiko Sakaguchi
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Patent number: 8952100Abstract: The invention provides a method for a preparation of a polymer selected from the following: (a) modified interpolymer comprising, in polymerized form, a conjugated diene and an aromatic alpha-olefin, or (b) a modified polymer comprising, in polymerized form, a conjugated diene; and wherein said method comprising at least the following steps: polymerizing monomers comprising at least one conjugated diene monomer in at least one polymerization reactor, in the presence of at least one solvent, to form the polymer, optionally coupling a fraction of the polymer chains using at least one coupling agent, modifying the polymer with at least one modifying agent, in at least one reactor, in the presence of the at least one solvent, to form a modified polymer solution; optionally, contacting the modified polymer solution with at least one proton donating compound; contacting the modified polymer solution with water; removing the at least one solvent; contacting the removed solvent with at least one material that will reType: GrantFiled: November 11, 2009Date of Patent: February 10, 2015Assignee: Styron Europe GmbHInventors: Sven Thiele, Jochen Boehm, Norbert Jantsch, Christiane Berndt
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Patent number: 8927644Abstract: A polymer having at least the following characteristics: (a) a block styrene content with more than 4 consecutive styrene units from about 40 to about 70 weight percent based on total styrene content in the polymer; (b) a vinyl content from about 25 to about 80 weight percent based on total amount of polymerized 1,3-diene; (c) a styrene content from about 20 to about 75 weight percent based on total weight of polymer; and (d) a molecular weight distribution (Mw/Mn) of 1.5 or less.Type: GrantFiled: June 22, 2012Date of Patent: January 6, 2015Assignee: Styron Europe GmbHInventors: Evemarie Hamann, Silvia Valenti, Gabriele Holtz
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Patent number: 8927645Abstract: A polymer having at least the following characteristics: (a) a block styrene content with more than 6 consecutive styrene units from about 15 to about 35 weight percent based on total styrene content in the polymer; (b) a vinyl content from about 25 to about 80 weight percent based on total amount of polymerized 1,3-diene; and (c) a styrene content from about 35 to about 75 weight percent based on total weight of polymer; and (d) a molecular weight distribution (Mw/Mn) of 1.5 or less.Type: GrantFiled: June 22, 2012Date of Patent: January 6, 2015Assignee: Styron Europe GmbHInventors: Evemarie Hamann, Silvia Valenti, Gabriele Holtz
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Patent number: 8921502Abstract: The invention provides a first composition comprising at least the following: i) a modified polymer comprising at least one branched modified polymer macromolecule (b1) and at least one linear modified polymer macromolecule (a1), and wherein the at least one branched modified polymer macromolecule and the at least one linear modified polymer macromolecule each, independently, comprises at least one amine group selected from the group consisting of formulas (1A-1F), each as described above: and combinations thereof; and wherein the at least one branched modified polymer macromolecule further comprises one of the structures (ib1-ib4) as described above, and the at least one linear modified polymer macromolecule further comprises one of the structures (iib1) as described above (see Formula 3A).Type: GrantFiled: December 20, 2010Date of Patent: December 30, 2014Assignee: Styron Europe GmbHInventors: Sven Thiele, Sascha Rulhoff, Susanne Knoll
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Patent number: 8915643Abstract: Apparatus (1) for admixing additives to a medium to be pumped, comprising at least one gear pump (2) for pumping a medium to be pumped, said gear pump (2) comprising at least one shaft (3) having a first driving torque; at least one injector (5) for introducing an additive into a medium to be pumped; at least one screw conveyor (6) for mixing said additive with said medium to be pumped, said screw conveyor having a second driving torque, and, characterized in that, the shaft (3) and the screw conveyor (6) are functionally connected, such that the first driving torque and the second driving torque are coupled.Type: GrantFiled: June 3, 2014Date of Patent: December 23, 2014Assignee: Styron Europe GmbHInventors: Luc Bosiers, Rodolfo Salmang-Frohard
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Patent number: 8912296Abstract: Provided is a process for preparing polystyrene having a weight average molecular weight (Mw) in the range of 120,000-160,000 g/mol, a polydispersity in the range of 4-6 and a melt flow rate of at least 40 g/10 minutes by feeding styrene into a reaction system through which the styrene passes as a component of a reaction mixture as it is polymerized, the reaction system including an initial reaction zone (100) and a downstream reaction zone (200), comprising the steps of: polymerizing styrene in the initial reaction zone to form polystyrene having a Mw of greater than 300,000 g/mol and a polydispersity in the range 1.5-2.5, 10-30 wt. % of the styrene fed to the initial reaction zone being polymerized there, —and polymerizing styrene remaining in the reaction mixture in the downstream reaction zone, a chain transfer agent being mixed with the reaction mixture at the commencement of this reaction zone and optionally at one or more additional locations within this reaction zone.Type: GrantFiled: December 13, 2012Date of Patent: December 16, 2014Assignee: Styron Europe GmbHInventors: Gilbert Bouquet, Ulrich Reifert, Nicolaas M. A. Hermans
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Patent number: 8895684Abstract: The invention provides a first composition comprising at least the following: i) a modified polymer comprising at least one branched modified polymer macromolecule (b1) and at least one linear modified polymer macromolecule (a1), and wherein the at least one branched modified polymer macromolecule and the at least one linear modified polymer macromolecule each, independently, comprises at least one amine group selected from the group consisting of formulas (1A-1F), each as described above Formula 1A, Formula 1B, Formula 1C, Formula 1D, Formula 1E, Formula 1F, and combinations thereof; and wherein the at least one branched modified polymer macromolecule further comprises one of the structures (ib1-ib4) as described above, and the at least one linear modified polymer macromolecule further comprises one of the structures (iib1-iib2) as described above.Type: GrantFiled: December 20, 2010Date of Patent: November 25, 2014Assignee: Styron Europe GmbHInventors: Sven Thiele, Sascha Rulhoff
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Publication number: 20140322490Abstract: A floor mat includes a plurality of projections integrally formed and extending from a lower surface. At least some of the projections have a straight axis and a cross section perpendicular to the straight axis that decreases from the base to the tip of the projection. The at least some projections have a height measured along the axis and a width corresponding to its largest dimension measured parallel to a plane of the lower surface such that the ratio of the width to the height of the projection is greater than 1.Type: ApplicationFiled: July 29, 2011Publication date: October 30, 2014Applicant: STYRON EUROPE GMBHInventors: Mark Vreys, Berend J.G. Hoek
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Publication number: 20140309369Abstract: The present invention relates to a process for preparing a polymer latex that includes comprising polymerizing one or more ethylenically unsaturated aromatic monomers and one or more conjugated diene monomers in the presence of a hydroperoxide chain transfer agent and sulfur-containing chain transfer agent, wherein the sulfur-containing chain transfer agent is added after the hydroperoxide chain transfer agent. It further relates to the polymer latex thus obtained, to a composition comprising the polymer latex and to the use of the polymer latex or polymer latex composition in a carpet backing, paper coating, or fiber fabric pre-impregnation process.Type: ApplicationFiled: August 23, 2012Publication date: October 16, 2014Applicant: STYRON EUROPE GMBHInventors: Bernard Fouchet, Etienne Lazarus, Nicolas Tissier, Ursula Seiler, Donato Ventresca