Patents Assigned to SUD Chemie MT S.R.L.
  • Patent number: 8574450
    Abstract: Highly pure iron oxides are prepared by reaction of metallic iron, in the form of microspheroidal particles or of scraps or cuttings, with an agitated aqueous solution of a mono- or polycarboxylic acid with a pKa of 0.5 to 6 relative to the first carboxyl and capable of decomposing, by heating in air at 200 to 350° C., to carbon dioxide and water, using 0.03 to 1.5 moles of acid per g-atoms of iron, a water/iron weight ration of 1 to 20, and by oxidation of the ferrous carboxilate to ferric salt, with an agent selected from oxygen, mixtures containing oxygen, hydrogen peroxide, organic peroxides and hydroperoxides.
    Type: Grant
    Filed: May 24, 2011
    Date of Patent: November 5, 2013
    Assignee: SUD Chemie MT S.r.l.
    Inventors: Esterino Conca, Carlo Rubini, Guido Petrini
  • Publication number: 20110251054
    Abstract: Highly pure iron oxides are prepared by reaction of metallic iron, in the form of microspheroidal particles or of scraps or cuttings, with an agitated aqueous solution of a mono- or polycarboxylic acid with a pKa of 0.5 to 6 relative to the first carboxyl and capable of decomposing, by heating in air at 200 to 350° C., to carbon dioxide and water, using 0.03 to 1.5 moles of acid per g-atoms of iron, a water/iron weight ration of 1 to 20, and by oxidation of the ferrous carboxilate to ferric salt, with an agent selected from oxygen, mixtures containing oxygen, hydrogen peroxide, organic peroxides and hydroperoxides.
    Type: Application
    Filed: May 24, 2011
    Publication date: October 13, 2011
    Applicant: SUD Chemie MT S.r.l.
    Inventors: Esterino Conca, Carlo Rubini, Guido Petrini
  • Publication number: 20090324487
    Abstract: Highly pure iron oxides are prepared by reaction of metallic iron, in the form of microspheroidal particles or of scraps or cuttings, with an agitated aqueous solution of a mono- or polycarboxylic acid with a pKa of 0.5 to 6 relative to the first carboxyl and capable of decomposing, by heating in air at 200 to 350° C., to carbon dioxide and water, using 0.03 to 1.5 moles of acid per g-atoms of iron, a water/iron weight ration of 1 to 20, and by oxidation of the ferrous carboxilate to ferric salt, with an agent selected from oxygen, mixtures containing oxygen, hydrogen peroxide, organic peroxides and hydroperoxides.
    Type: Application
    Filed: July 11, 2008
    Publication date: December 31, 2009
    Applicant: SUD Chemie MT S.r.l.
    Inventors: Esterino Conca, Carlo Rubini, Guido Petrini
  • Patent number: 7442362
    Abstract: Highly pure iron oxides are prepared by reaction of metallic iron, in the form of microspheroidal particles or of scraps or cuttings, with an agitated aqueous solution of a mono- or polycarboxylic acid with a pKa of 0.5 to 6 relative to the first carboxyl and capable of decomposing, by heating in air at 200 to 350 ° C., to carbon dioxide and water, using 0.03 to 1.5 moles of acid per g-atoms of iron, a water/iron weight ration of 1 to 20, and by oxidation of the ferrous carboxilate to ferric salt, with an agent selected from oxygen, mixtures containing oxygen, hydrogen peroxide, organic peroxides and hydroperoxides.
    Type: Grant
    Filed: April 30, 2004
    Date of Patent: October 28, 2008
    Assignee: Sud Chemie MT S.r.l.
    Inventors: Esterino Conca, Carlo Rubini, Guido Petrini
  • Patent number: 6833125
    Abstract: Oxidation catalysts for used in the full oxidation to CO2 and H2O of volatile organic compounds, such as hydrocarbons, comprising mixed oxides of copper, manganese and one or more rare-earth metals, wherein the metals can assume multiple valency states, having a percentage composition by weight, expressed as CuO, MnO and rare-earth oxides, in which the metal has the minimum value of 8-50%, 10-75% and 2-15%, respectively. The oxides are supported on inert porous inorganic oxides.
    Type: Grant
    Filed: December 8, 2003
    Date of Patent: December 21, 2004
    Assignee: SUD Chemie MT. S.r.l.
    Inventors: Alberto Cremona, Carlo Rubini, Edoardo Vogna
  • Patent number: 6818581
    Abstract: A method for denitrification of water, in which the water to be denitrified is made to flow over a porous carrier which comprises a transition metal, preferably palladium, used in an amount between 0.01 and 5% by weight on the carrier and on which denitrifying bacterial strains capable of surviving in the presence of hydrogen are made to adhere, and in which hydrogen is used as a reducing agent and the pH of the reaction is adjusted to values of 4.5 to 7.8 preferably by using carbon dioxide.
    Type: Grant
    Filed: October 30, 2003
    Date of Patent: November 16, 2004
    Assignee: SUD Chemie MT S.r.l.
    Inventors: Antonio Pasquale, Carlo Rubini, Michele Rossi, Luigi Cavalli
  • Publication number: 20040202606
    Abstract: Highly pure iron oxides are prepared by reaction of metallic iron, in the form of microspheroidal particles or of scraps or cuttings, with an agitated aqueous solution of a mono- or polycarboxylic acid with a pKa of 0.5 to 6 relative to the first carboxyl and capable of decomposing, by heating in air at 200 to 350° C., to carbon dioxide and water, using 0.03 to 1.5 moles of acid per g-atoms of iron, a water/iron weight ration of 1 to 20, and by oxidation of the ferrous carboxilate to ferric salt, with an agent selected from oxygen, mixtures containing oxygen, hydrogen peroxide, organic peroxides and hydroperoxides.
    Type: Application
    Filed: April 30, 2004
    Publication date: October 14, 2004
    Applicant: SUD Chemie MT S.r.l.
    Inventors: Esterino Conca, Carlo Rubini, Guido Petrini
  • Publication number: 20040192978
    Abstract: Catalysts for oxychlorination of ethylene to 1,2-dichloroethane, comprising compounds of copper and magnesium supported on alumina, in which the copper, expressed as metal, is present in an amount of 7 to 12% by weight and the Mg/Cu ratio is 0.05 to 1, and wherein the ratio between the concentration of copper provided by the Al/Cu ratio at the surface and that provided by the Al/Cu ratio in the entire particle of the catalyst is from 0.8 to 1.3.
    Type: Application
    Filed: March 3, 2004
    Publication date: September 30, 2004
    Applicant: SUD Chemie MT S.R.L.
    Inventors: Francesco Casagrande, Carlo Orsenigo
  • Patent number: 6759365
    Abstract: Catalysts for the oxychlorination of ethylene to 1,2-dichloroethylene, comprising compounds of Cu and Mg supported on alumina, in which the copper content, expressed as Cu, is 2 to 8% by weight, the Mg/Cu atomic ratio is from 1.2 to 2.5, and the specific surface of the catalyst is from 30 to 130 m2/g.
    Type: Grant
    Filed: October 22, 2002
    Date of Patent: July 6, 2004
    Assignee: SUD Chemie Mt S.r.l.
    Inventors: Luigi Cavalli, Francesco Casagrande
  • Publication number: 20040118759
    Abstract: A method for denitrification of water, in which the water to be denitrified is made to flow over a porous carrier which comprises a transition metal, preferably palladium, used in an amount between 0.01 and 5% by weight on the carrier and on which denitrifying bacterial strains capable of surviving in the presence of hydrogen are made to adhere, and in which hydrogen is used as a reducing agent and the pH of the reaction is adjusted to values of 4.5 to 7.8 preferably by using carbon dioxide.
    Type: Application
    Filed: October 30, 2003
    Publication date: June 24, 2004
    Applicant: SUD Chemie MT S.R.L.
    Inventors: Antonio Pasquale, Carlo Rubini, Michele Rossi, Luigi Cavalli
  • Publication number: 20040121904
    Abstract: Oxidation catalysts usable in particular in the full oxidation to CO2 and H2O of volatile organic compounds such as hydrocarbons comprising mixed oxides of copper, manganese and one or more rare-earth metals, wherein the metals can assume multiple valency states, having a percentage composition by weight, expressed as CuO, MnO and rare-earth oxides, in which the metal has the minimum value of 8-50%, 10-75% and 2-15%. The oxides are supported on inert porous inorganic oxides.
    Type: Application
    Filed: December 8, 2003
    Publication date: June 24, 2004
    Applicant: SUD CHEMIE MT. S.R.L.
    Inventors: Alberto Cremona, Carlo Rubini, Edoardo Vogna
  • Patent number: 6683021
    Abstract: Oxidation catalysts useful in the oxidation to CO2 and H2O of volatile organic compounds such as hydrocarbons comprising mixed oxides of copper, manganese and one or more rare-earth metals, wherein the metals can assume multiple valency states, having a percentage composition by weight, expressed as CuO, MnO and rare-earth oxides, in which the metal has the minimum value of 8-50%, 10-75% and 2-15%. The oxides are supported on inert porous inorganic oxides.
    Type: Grant
    Filed: October 1, 2001
    Date of Patent: January 27, 2004
    Assignee: SUD Chemie MT. S.R.L.
    Inventors: Alberto Cremona, Carlo Rubini, Edoardo Vogna
  • Patent number: 6669847
    Abstract: A method for denitrification of water, in which the water to be denitrified is made to flow over a porous carrier which comprises a transition metal, preferably palladium, used in an amount between 0.01 and 5% by weight on the carrier and on which denitrifying bacterial strains capable of surviving in the presence of hydrogen are made to adhere, and in which hydrogen is used as a reducing agent and the pH of the reaction is adjusted to values of 4.5 to 7.8 preferably by using carbon dioxide.
    Type: Grant
    Filed: July 20, 2001
    Date of Patent: December 30, 2003
    Assignee: Sud Chemie MT S.r.l.
    Inventors: Antonio Pasquale, Carlo Rubini, Michele Rossi, Luigi Cavalli
  • Patent number: 6627777
    Abstract: Catalysts for the fluid-bed hydrodechlorination of carbon tetrachloride to chloroform having high catalytic stability and comprising platinum supported on microspheroidal gamma alumina, characterized in that the platinum is in the form of particles dispersed throughout the mass of the support.
    Type: Grant
    Filed: October 9, 2001
    Date of Patent: September 30, 2003
    Assignee: Sud Chemie MT S.R.L.
    Inventors: Michele Rossi, Carlo Rubini, Antonio Pasquale, Luigi Cavalli
  • Patent number: 6593269
    Abstract: Catalysts for exothermic reactions conducted in a fixed bed, comprising an inert diluent constituted by metal granules in which the metal has a thermal conductivity of more than 0.5 W/cm/K, particularly catalysts for the oxychlorination of ethylene to 1,2-dichloroethane.
    Type: Grant
    Filed: January 3, 2000
    Date of Patent: July 15, 2003
    Assignee: Sud Chemie MT S.R.L.
    Inventors: Carlo Rubini, Marinella Malentacchi
  • Publication number: 20030096700
    Abstract: Catalysts for the oxychlorination of ethylene to 1,2-dichloroethylene, comprising compounds of Cu and Mg supported on alumina, in which the copper content, expressed as Cu, is 2 to 8% by weight, the Mg/Cu atomic ratio is from 1.2 to 2.5, and the specific surface of the catalyst is from 30 to 130 m2/g.
    Type: Application
    Filed: October 22, 2002
    Publication date: May 22, 2003
    Applicant: Sud Chemie Mt S.R.L.
    Inventors: Luigi Cavalli, Francesco Casagrande
  • Publication number: 20020064492
    Abstract: Oxidation catalysts usable in particular in the full oxidation to CO2 and H2O of volatile organic compounds such as hydrocarbons comprising mixed oxides of copper, manganese and one or more rare-earth metals, wherein the metals can assume multiple valency states, having a percentage composition by weight, expressed as CuO, MnO and rare-earth oxides, in which the metal has the minimum value of 8-50%, 10-75% and 2-15%. The oxides are supported on inert porous inorganic oxides.
    Type: Application
    Filed: October 1, 2001
    Publication date: May 30, 2002
    Applicant: SUD CHEMIE MT S.R.L.
    Inventors: Alberto Cremona, Carlo Rubini, Edoardo Vogna
  • Patent number: 6184174
    Abstract: Catalysts for dehydrogenating ethylbenzene to styrene which comprise iron oxide, oxides of alkaline and alkaline-earth metals, oxides of the lanthanide series, oxides of metals of the sixth group, prepared from a paste of iron oxide impregnated with an aqueous solution of a cerium salt, treated with aqueous KOH and calcined, after drying, to preform potassium ferrate, to which the other components or precursors of the catalyst are then added.
    Type: Grant
    Filed: May 19, 1999
    Date of Patent: February 6, 2001
    Assignee: SUD Chemie MT S.R.L.
    Inventors: Carlo Rubini, Luigi Cavalli, Esterino Conca
  • Patent number: 6066589
    Abstract: Hydrogenation catalysts comprising metallic palladium supported on activated carbon, wherein less than 50% by weight of the palladium is comprised within a surface layer with a depth of up to 50 microns, the remainder being comprised in a layer between 50 and 400 microns deep. The catalysts can be used in particular in purifying terephthalic acid obtained by oxidation of p-xylene.
    Type: Grant
    Filed: May 19, 1998
    Date of Patent: May 23, 2000
    Assignee: Sud Chemie MT. S.r.l.
    Inventors: Marinella Malentacchi, Luigi Cavalli, Carlo Rubini