Patents Assigned to Sugai Chemical Industry Co., Ltd.
  • Patent number: 7569211
    Abstract: It is an object to provide an L-ascorbic acid derivative which can keep the L-ascorbic acid stable to heat and light and thus has a long shelf life, which is high in permeability into the skin, which can be quickly hydrolyzed by phosphatase, an enzyme that is ubiquitous in vivo, and which exhibits physiological activities that are inherent to L-ascorbic acid and beneficial to health, a method for producing such an L-ascorbic acid derivative, and a skin-whitening cosmetic material. There is provided an ascorbic acid derivative comprising an L-ascorbic acid-2-phosphate ester or a salt thereof wherein the phosphate ester has a branched alkyl group, the L-ascorbic acid-2-phosphate ester being of formula [13].
    Type: Grant
    Filed: August 9, 2007
    Date of Patent: August 4, 2009
    Assignees: Toyo Beauty Co., Ltd., Sugai Chemical Industry Co., Ltd.
    Inventors: Hiroharu Shibayama, Koichi Ueda, Hachiro Indo, Satoshi Tachibana, Hiroshi Nishikawa, Masaru Yamabe
  • Patent number: 7282597
    Abstract: It is an object to provide an L-ascorbic acid derivative which can keep the L-ascorbic acid stable to heat and light and thus has a long shelf life, which is high in permeability into the skin, which can be quickly hydrolyzed by phosphatase, an enzyme that is ubiquitous in vivo, and which exhibits physiological activities that are inherent to L-ascorbic acid and beneficial to health, a method for producing such an L-ascorbic acid derivative, and a skin-whitening cosmetic material. There is provided an ascorbic acid derivative comprising an L-ascorbic acid-2-phosphate ester or a salt thereof wherein the phosphate ester has a branched alkyl group, the L-ascorbic acid-2-phosphate ester being of formula [13].
    Type: Grant
    Filed: March 25, 2005
    Date of Patent: October 16, 2007
    Assignees: Toyo Beauty Co., Ltd., Sugai Chemical Industry Co., Ltd.
    Inventors: Hiroharu Shibayama, Koichi Ueda, Hachiro Indo, Satoshi Tachibana, Hiroshi Nishikawa, Masaru Yamabe
  • Patent number: 4824822
    Abstract: A thermosensitive recording method which comprises heat-treating compounds A and B constituting a coloring matter resulting in sublimation or evaporation to thereby bring these two compounds into contact with each other on a recording sheet, resulting in a color image on the recording sheet.
    Type: Grant
    Filed: March 28, 1988
    Date of Patent: April 25, 1989
    Assignees: Sharp Kabushiki Kaisha, Sugai Chemical Industry Co., Ltd.
    Inventors: Yoichi Yamamoto, Hironori Fujii, Toshio Oichi
  • Patent number: 4746645
    Abstract: Disclosed is a heat-sensitive recording material comprising a base sheet and a heat-sensitive record layer formed over the base sheet and comprising a colorless or pale-colored basic dye and a color developing material capable of forming a color when contacted with the dye, the heat-sensitive recording material being characterized in that the heat-sensitive record layer contains as the color developing material at least one multi-valent metal salt of a halophthalic acid derivative represented by the formula ##STR1## wherein R represents a divalent saturated or unsaturated C.sub.2 -C.sub.12 aliphatic hydrocarbon group which may optionally have a hydroxyl, C.sub.1 -C.sub.3 acyloxy or phenyl group as a substituent or a divalent saturated or unsaturated C.sub.4 -C.sub.6 aliphatic hydrocarbon group containing one or two ether bonds, X is a halogen atom and n is an integer of 1-4.
    Type: Grant
    Filed: December 16, 1986
    Date of Patent: May 24, 1988
    Assignees: Kanzaki Paper Manufacturing Company, Limited, Sugai Chemical Industry Co., Ltd.
    Inventors: Teijiro Kitao, Mitsuru Kondo, Toshitake Suzuki, Masayuki Omatsu, Hironori Fujii, Kenji Minami
  • Patent number: 4670581
    Abstract: New biphenyl compounds and a process for producing them are provided. These new compounds have an acyloxy group in the 2- or 4-position of the biphenyl and an acyl hydroxyalkyl, hydroxyalkenyl or vinyl group in the 4'-position of the biphenyl or, alternatively a hydroxyl group in the 2- or 4-position of the biphenyl and an acyl, hydroxyalkyl, hydroxyalkenyl or vinyl group in the 4'-position of the biphenyl. These compounds can be produced easily from 2- or 4-acyloxybiphenyl compounds.
    Type: Grant
    Filed: January 10, 1984
    Date of Patent: June 2, 1987
    Assignee: Sugai Chemical Industry Co., Ltd.
    Inventor: Teiichi Tanigaki
  • Patent number: 4465878
    Abstract: A process for producing 4,4'-dihydroxydiphenyl which comprises subjecting to alkali fusion 1 mol of 4,4'-diphenyldisulfonic acid and/or potassium 4,4'-diphenyldisulfonate together with 4 to 10 mol of potassium hydroxide and 0.1 to 2 mol of potassium sulfate. Alternatively, the process may comprise subjecting to alkali fusion 4,4'-diphenyldisulfonic acid in the presence of potassium hydroxide, controlling to 20 to 25% the potassium hydroxide concentration in the reaction mixture, and separating dipotassium salt of 4,4'-dihydroxydiphenyl.
    Type: Grant
    Filed: July 21, 1982
    Date of Patent: August 14, 1984
    Assignee: Sugai Chemical Industry Co., Ltd.
    Inventors: Takeshi Hashimoto, Terumasa Akashi, Koji Nishihara
  • Patent number: 4382896
    Abstract: A process for producing 4,4'-diphenyldisulfonic acid is disclosed, which comprises the steps of adding a sulfonating agent to molten diphenyl at a temperature within a range of 130.degree. to 145.degree. C., and when crystallization commences of 4,4'-diphenyldisulfonic acid within such temperature range, cooling the reaction mixture to a temperature within a range of 115.degree. to 127.degree. C., and letting the disulfonation reaction complete while the reaction mixture is maintained within the cooled temperature range. A process for producing monopotassium 4,4'-diphenyldisulfonate is also disclosed, in which steps are taken of adding a sulfonating agent to diphenyl, then controlling the sulfuric acid concentration to 45 to 55%, and while the reaction mixture is heated to at least 140.degree. C., adding at least a stoichiometric amount of a potassium salt of an inorganic acid.
    Type: Grant
    Filed: July 21, 1982
    Date of Patent: May 10, 1983
    Assignee: Sugai Chemical Industry Co., Ltd.
    Inventors: Koji Nishihara, Takeshi Hashimoto, Shunsaku Tanaka, Katsuhiko Sato
  • Patent number: 4324742
    Abstract: A process for separating 1,6-naphthalenedisulfonic acid, 2,6-naphthalenedisulfonic acid or 2,7-naphthalenedisulfonic acid selectively from reaction mixtures obtained by disulfonation of naphthalene under different reaction conditions is disclosed. For example, a particular disulfonation reaction of naphthalene is carried out which favors the formation of a particular isomer. This reaction mixture is diluted with water to adjust the sulfuric acid concentration to 35 to 90% by weight and the temperature is maintained at 0.degree. to 80.degree. C.; 1,6-naphthalene-disulfonic acid is selectively separated at high purity.
    Type: Grant
    Filed: August 25, 1980
    Date of Patent: April 13, 1982
    Assignee: Sugai Chemical Industry Co., Ltd.
    Inventors: Hironory Fujii, Thuyoshi Nagashima, Nobuyori Shibamoto
  • Patent number: 4060559
    Abstract: A process for preparing o-phenylphenol by dehydrogenating at least one of cyclohexanone dimer and o-cyclohexylphenol in the presence of a catalyst, characterized in that the catalyst comprises a metal oxide carrier, and at least one of alkali metal salts of sulfur-oxygen acids and at least one of platinum and palladium supported by the carrier.
    Type: Grant
    Filed: May 3, 1976
    Date of Patent: November 29, 1977
    Assignee: Sugai Chemical Industry Co., Ltd.
    Inventors: Hideo Goto, Nobuyori Shibamoto, Shunsaku Tanaka
  • Patent number: 3937664
    Abstract: An oil-filled electrical device comprising a casing, an electrical device element in the casing and an insulating oil consisting essentially of one or more 2-diphenylalkylether having the structural formula of ##SPC1##Wherein R is the alkyl group expressed as C.sub.n H.sub.2n.sub.+1 wherein R is 1.ltoreq.n423.8.
    Type: Grant
    Filed: March 25, 1974
    Date of Patent: February 10, 1976
    Assignees: Nissin Electric Co., Ltd., Sugai Chemical Industry Co., Ltd.
    Inventors: Fumio Tanimoto, Mineaki Nishimatsu, Sadayoshi Mukai, Kaname Ishida