Abstract: The present invention is drawn to UV-curable ink and coating compositions comprising cleavage type photoinitiators and acids. The acids may be inorganic or organic acids, or acids generated by a photoacid generator during UV-cure. Incorporation of the acids into the UV-curable ink and coating compositions results in a reduction of migratable photodecomposition products that are produced by cleavage type photoinitiators during UV-cure. The ink and coating compositions are particularly useful for use in applications that require low migration of low molecular weight materials, such as, for example, food packaging.
Type:
Application
Filed:
August 6, 2018
Publication date:
September 30, 2021
Applicant:
SUN CHEMICAL CORPORATION
Inventors:
Derek Ronald Illsley, Shaun Lawrence Herlihy, Andrew Boon
Abstract: The present invention provides energy-curable compositions comprising aminoacrylates produced by the Michael addition reaction of any blend of highly alkoxylated monomers with any blend of mono- and/or bireactive amines. Suitable highly alkoxylated monomers include, but are not limited to, poly(ethylene glycol) diacrylates, poly(propylene glycol) diacrylates, and ethoxylated trimethylolpropane triacrylates. The alkoxylated monomers have a degree of alkoxylation equal to or greater than 2.0 per functional group. The compositions of the present invention further comprise greater than 10% (w/w) of any blend of monomers having molecular weights of less than 1000 Daltons.
Type:
Grant
Filed:
March 14, 2017
Date of Patent:
September 21, 2021
Assignee:
Sun Chemical Corporation
Inventors:
Derek Ronald Illsley, Shaun Lawrence Herlihy, Sean Phillip Francis Mayers
Abstract: A process for preparing printed matter is disclosed which comprises applying first a UV-curable ink containing photoinitiators followed by an overprint varnish and then UV curing such as the amount of photoinitiators is less than 6% by weight of the total weight of the ink. The present invention relates to a printing process by applying first a UV-curable ink followed by an overprint varnish (OPV) and curing.
Abstract: The present invention discloses gas and moisture vapor barrier coating compositions that comprise an amine modified polyvinyl alcohol and an acetoacetate modified polyvinyl. The barrier coatings of the invention exhibit enhanced gas and moisture vapor properties. The barrier coatings of the invention maintain gas and moisture vapor properties even after repeated flexing of a coated substrate.
Type:
Grant
Filed:
August 9, 2017
Date of Patent:
September 14, 2021
Assignee:
Sun Chemical Corporation
Inventors:
Asad Aslam Khan, Michael William Leonard
Abstract: The present application is drawn to aqueous electron beam curable compositions comprising poly(alkylene oxide) containing substances, and any blend of water-soluble or water-dispersible ethylenically unsaturated monomers, oligomers and polymers.
Abstract: Described herein are printed laminates. The laminates include a first substrate having an applied layer of an ink or coating composition that includes a self-crosslinking acrylic polymer having has a glass transition temperature of 0° C. or greater, a coalescent, and water; a second substrate positioned to configure the applied layer between the first substrate and the second substrate; and an adhesive bonding the first substrate to the second substrate. Also described is a process for making such laminates. In one aspect, the applied layer of ink is a reverse printed layer, in which the applied ink layer is highly compatible with the adhesive with which it comes in contact.
Type:
Grant
Filed:
May 16, 2019
Date of Patent:
August 31, 2021
Assignee:
Sun Chemical Corporation
Inventors:
Robert Deighton, Peter Salthouse, Christine Juckes
Abstract: The present invention provides water-soluble or water-dispersible polyester resins prepared by depolymerizing a tereph-thalate plastic material in an alcoholysis/glycolysis reaction, and re-polymerizing the product by reacting with a polybasic acid and/or anhydride. The polyester resins of the invention contain 70% to 95% by weight of the terephthalate material, based on the total weight of the composition. The polyester resins of the present invention are useful as dispersants, for example in pigment preparations, and as binders in let-down varnishes, inks, coatings, etc, and as adhesion promoters in aqueous-based inks.
Type:
Application
Filed:
January 6, 2020
Publication date:
August 12, 2021
Applicant:
SUN CHEMICAL CORPORATION
Inventors:
Jürgen Dieker, Robert Deighton, Kai-Uwe W. Gaudl, Leonora Nurcaj-Dreshaj
Abstract: Described herein are alkoxylated polymers suitable for use in primers, inks or coating compositions. The alkoxylated polymers derive from a polyalkylene glycol polymer or copolymer backbone having one or more alkoxylated sites in a non-reactive form and at least one reactive terminal end, and one or more polyfunctional monomers or oligomers having two or more functional polar groups with an active hydrogen, or mixtures thereof, wherein the alkoxylated polymer is polymerized in a one step process. Primers, inks or coating compositions are further described.
Abstract: In the present invention, a solvent-based (SB) adhesive for the purpose of closing or sealing the open end of a bag, such as a plastic trash bag, liner or like, is coated to the exterior or interior surface of said bag and creates a neat, tight functional seal to said bag when twist activated.
Type:
Grant
Filed:
March 31, 2020
Date of Patent:
August 3, 2021
Assignee:
Sun Chemical Corporation
Inventors:
Paul Kurtz, Philippe Schottland, Russell Schwartz, Kohei Nakane
Abstract: Described herein are polymer-encapsulated materials and a method for encapsulating materials with polymer via emulsion polymerization. The encapsulated materials include colorants (e.g., pigments and dyes, and in particular fluorescent dyes), optical brighteners, downconverters and upconverters. The encapsulated materials are produced by the emulsion polymerization of ethylenically unsaturated monomers. The polymer-encapsulation method described herein does not require the preparation of a miniemulsion homogenized with special equipment, such as an ultrasonification device, and the resulting polymer-encapsulated materials exhibit optical properties superior to polymer-encapsulated materials prepared by processes that include the preparation of a miniemulsion prepared with such special equipment, such as an ultrasonification device.
Type:
Application
Filed:
August 17, 2017
Publication date:
July 15, 2021
Applicant:
SUN CHEMICAL CORPORATION
Inventors:
Xiaobo Zhu, Juanita Parris, Ralph Arcurio, Mohammad S. Farahat
Abstract: It is an object of the present technology to overcome the disadvantages of conventional chlorination of a copper phthalocyanine which produces copper phthalocyanine, wherein the number of chlorines is less than than or equal to 4. The pigments described herein contain less chlorine than standard commercial grades of tetrachlorinated (or greater) copper phthalocyanine pigments while achieving similar color space, chromaticity, fastness properties, and color travel in automotive waterborne and solvent borne systems. The inventive pigments are more advantageous from a toxicity and environmental perspective, and allow the manufacturer to produce pigments in a safe and economical manner.
Type:
Grant
Filed:
December 9, 2019
Date of Patent:
July 13, 2021
Assignee:
Sun Chemical Corporation
Inventors:
Pamela M. Visintin, Russell J. Schwartz
Abstract: The present invention provides waterborne polyurethane coating compositions. When applied to a substrate, the coating compositions of the present invention have good adhesion, transparency, scratch resistance, mar resistance, hardness, solvent resistance, water resistance, and dishwashing resistance. The coating compositions are suitable for application to any suitable substrate, including glass.
Type:
Grant
Filed:
January 17, 2018
Date of Patent:
July 13, 2021
Assignee:
Sun Chemical Corporation
Inventors:
Yongping Zha, Philippe Schottland, Robert Mateuszczyk
Abstract: Electron beam curable compositions comprising poly(alkylene oxide) containing substances, and any blend of ethylenically unsaturated monomers and oligomers. The poly(alkylene oxide) components of the said substances may include poly(ethylene glycol)s, poly(propylene glycol)s and higher poly(alkylene oxide)s, as well as poly(alkoxylated) alcohols and amines, and the substances are essentially free of any ethylenically unsaturated groups.
Abstract: The present invention provides a photo-substrate for printing of lenticular images that comprises a lenticular lens array, and an energy-reactive material adhered to the backside of the lenticular lens array. According to the methods of the present invention, the lenticular image is printed directly through the lenticular lens array onto the energy-reactive material, using, for example, collimated light or laser. The photo-substrate of the present invention can be adapted for large scale or industrial production to print lenticular images on a wide array of substrates, including such things as packaging and clothing.
Type:
Application
Filed:
January 13, 2021
Publication date:
June 24, 2021
Applicant:
SUN CHEMICAL CORPORATION
Inventors:
Bo SUN, Jerome MOYER, Philippe SCHOTTLAND, Danny RICH
Abstract: Water based, energy curable ink jet compositions that have good insulating properties are described herein. The inventive water based energy curable ink jet compositions include a water soluble or water dispersible component polymerizable by free radical polymeration upon exposure to polymerizing radiation, wherein the cured ink jet compositions have good insulating properties, exhibited for example, by its breakdown voltage. Also described are electronic devices including ink jet-printed layers of the ink jet compositions.
Type:
Application
Filed:
February 4, 2021
Publication date:
June 17, 2021
Applicant:
SUN CHEMICAL CORPORATION
Inventors:
Michael George PICKRELL, Derek Ronald ILLSLEY
Abstract: Described herein is a printing ink or coating composition that includes: (a) one or more elastomeric polyurethane resins with amine functionality having a glass transition temperature of about ?45° C. to about ?70° C.; (b) one or more acrylic resins based on a methacrylate/styrene co-polymer with a glass transition temperature of about 45° C. to about 110° C.; (c) one or more nitrocellulose binders; (d) one or more solvents; and (e) optionally, one or more waxes and/or one or more colorants. The inks and coating compositions are well suited for printing onto shrink sleeve label substrates, such as by flexographic and gravure printing. The inks and coatings provide exceptional printability and resistance to chemicals, to softening, to re-wetting, and to set-off.
Type:
Grant
Filed:
April 5, 2017
Date of Patent:
June 15, 2021
Assignee:
Sun Chemical Corporation
Inventors:
David Jason Rimmer, Nicholas Matthew Crandon
Abstract: Described herein are free radically polymerizable aqueous inkjet compositions that include water, a water-soluble or water-dispersible component polymerizable by free radical polymeration, and one or more water-soluble organic solvents in compliance with following Formula I: ?(Xn·Hn·Bn)????(I), where ? is 2,000,000. The variables of the formula are defined herein. Also described are printed articles that include the inkjet compositions of the disclosure. The inkjet compositions dry rapidly while remaining fluid during printing, thereby avoiding clogging in the print head.
Abstract: The present invention discloses an energy curable, single phase, aqueous composition comprising water, an ethylenically unsaturated oligomer, and an ethylenically unsaturated resin containing neutralized acidic or basic functional groups. Advantageously, in certain embodiments, the compositions contain greater than 25 wt. % water at less than 60 wt. % resin in the total composition.
Type:
Grant
Filed:
July 25, 2019
Date of Patent:
June 8, 2021
Assignee:
Sun Chemical Corporation
Inventors:
Jean Do Turgis, Richard M. Jones, Kai-Uwe Gaudl, Mikhail Laksin, Subhankar Chatterjee, Neil Young, Volker Linzer, John Rooney
Abstract: The present invention provides digital printing inks comprising one or more acrylamides. Particularly preferred are inks containing diacetone acrylamide. The inks of the invention show good cure speed, blocking resistance, tack free cure, stability and resistance to blocking, and adhesion to the substrate. The inks of the invention are useful for replacing the currently used inks containing odiferous and toxic components.