Abstract: A compound (A) is represented by the formula (1): wherein R1 is a hydrogen atom or an alkali metal atom, R2 is a hydrogen atom or an alkali metal atom, R3 is a hydrogen atom or a methyl group, Z is a divalent or trivalent organic group, and the lines consisting of a solid line and a broken line bonded to Z represent a single bond or a double bond.

Abstract: An inorganic-organic composite medical material includes a two-phase co-continuous structure of an inorganic substance having open pores and an organic polymer filling the open pores, wherein the open pores have an average pore diameter of 1 nm or more and 100 nm or less, and the inorganic substance has a specific surface area of 100 m2/g or less.

Abstract: The present invention improves the long-term storage stability of an organoborane-Lewis base complex. First composite particles of the present invention include particles of an organic polymer (B), and an organoborane-Lewis base complex (A) contained in the particles. Second composite particles of the present invention include particles of an inorganic compound (B?), and an organoborane-Lewis base complex (A) adsorbed on the particles.

Abstract: The present invention improves the long-term storage stability of an organoborane-Lewis base complex. First composite particles of the present invention include particles of an organic polymer (B), and an organoborane-Lewis base complex (A) contained in the particles. Second composite particles of the present invention include particles of an inorganic compound (B?), and an organoborane-Lewis base complex (A) adsorbed on the particles.

Abstract: A compound (A) is represented by the formula (1): wherein R1 is a hydrogen atom or an alkali metal atom, R2 is a hydrogen atom or an alkali metal atom, R3 is a hydrogen atom or a methyl group, Z is a divalent or trivalent organic group, and the lines consisting of a solid line and a broken line bonded to Z represent a single bond or a double bond.

Abstract: The present invention improves the long-term storage stability of a polymerizable composition including an organoborane and a polymerizable monomer. A polymerizable composition includes (A) an organoborane, (B) an acidic group-free polymerizable monomer, and (C) a stabilizer for the organoborane (A), the composition being such that when the composition, after being allowed to stand at 45° C. for 48 hours, is analyzed with an E-type viscometer at a temperature of 25° C. and a rotational speed of 50 rpm, the ratio of the viscosity after the standing to the viscosity before the standing (viscosity after standing/viscosity before standing) is less than 100.

Abstract: A dental adhesive curable composition containing a polymerizable monomer including a polymerizable monomer represented by formula (1?) and defined amounts of an acidic group-containing polymerizable monomer, a polymerization initiator containing a peroxide and a photopolymerization initiator, and a reductant containing a sulfinic acid compound and/or a salt thereof, and a filler: wherein the R groups, n and m are defined. A dental adhesive curable kit and a mobile tooth fixing material are also provided.

Abstract: The present invention improves the long-term storage stability of an organoborane-Lewis base complex. First composite particles of the present invention include particles of an organic polymer (B), and an organoborane-Lewis base complex (A) contained in the particles. Second composite particles of the present invention include particles of an inorganic compound (B?), and an organoborane-Lewis base complex (A) adsorbed on the particles.

Abstract: A dental adhesive curable composition containing a polymerizable monomer including a polymerizable monomer represented by formula (1?) and defined amounts of an acidic group-containing polymerizable monomer, a polymerization initiator containing a peroxide and a photopolymerization initiator, and a reductant containing a sulfinic acid compound and/or a salt thereof, and a filler: wherein the R groups, n and m are defined. A dental adhesive curable kit and a mobile tooth fixing material are also provided.

Abstract: The present invention provides polymerizable monomers represented by the following general formula (1) that are useful as dental materials. In the general formula (1), Ra is a divalent C6-9 aromatic hydrocarbon group or a divalent C6-9 optionally bridged cyclic hydrocarbon group, R1 and R2 are each a hydrogen atom or a C1-3 alkyl group, R3, R4, R5 and R6 are each a hydrogen atom or a hydrocarbon group, R7 and R8 are each a hydrogen atom or a methyl group, m and n are each independently 0 to 4, and Rb and Rc are each independently a C2-6 linear alkylene or C2-6 linear oxyalkylene group optionally substituted with a C1-3 alkyl group or a (meth)acryloyloxymethylene group in place of a hydrogen atom.

Abstract: The present invention improves the long-term storage stability of a polymerizable composition including an organoborane and a polymerizable monomer. A polymerizable composition includes (A) an organoborane, (B) an acidic group-free polymerizable monomer, and (C) a stabilizer for the organoborane (A), the composition being such that when the composition, after being allowed to stand at 45° C. for 48 hours, is analyzed with an E-type viscometer at a temperature of 25° C. and a rotational speed of 50 rpm, the ratio of the viscosity after the standing to the viscosity before the standing (viscosity after standing/viscosity before standing) is less than 100.

Abstract: Provided are dental polymerizable monomer compositions that can give cured products having high toughness and high rigidity, and dental compositions containing such dental polymerizable monomer compositions and cured products thereof having high mechanical properties.

Abstract: Provided are dental polymerizable monomers that can give cured products having high toughness and high rigidity, dental polymerizable monomer compositions containing the polymerizable monomers, and dental compositions containing the dental polymerizable monomer compositions, and cured products thereof having high mechanical properties. The dental polymerizable monomer (A) which includes a urethane acrylate obtained from an appropriately rigid diisocyanate and an appropriately flexible hydroxyacrylate is used to prepare a dental polymerizable monomer composition containing the dental polymerizable monomer, and a dental composition containing the dental polymerizable monomer composition.

Abstract: The present invention provides polymerizable monomers represented by the following general formula (1) that are useful as dental materials. In the general formula (1), Ra is a divalent C6-9 aromatic hydrocarbon group or a divalent C6-9 optionally bridged cyclic hydrocarbon group, R1 and R2 are each a hydrogen atom or a C1-3 alkyl group, R3, R4, R5 and R6 are each a hydrogen atom or a hydrocarbon group, R7 and R8 are each a hydrogen atom or a methyl group, m and n are each independently 0 to 4, and Rb and Rc are each independently a C2-6 linear alkylene or C2-6 linear oxyalkylene group optionally substituted with a C1-3 alkyl group or a (meth)acryloyloxymethylene group in place of a hydrogen atom.

Abstract: Provided are dental polymerizable monomer compositions that can give cured products having high toughness and high rigidity, and dental compositions containing such dental polymerizable monomer compositions and cured products thereof having high mechanical properties.

Abstract: Provided are dental polymerizable monomers that can give cured products having high toughness and high rigidity, dental polymerizable monomer compositions containing the polymerizable monomers, and dental compositions containing the dental polymerizable monomer compositions, and cured products thereof having high mechanical properties. The dental polymerizable monomer (A) which includes a urethane acrylate obtained from an appropriately rigid diisocyanate and an appropriately flexible hydroxyacrylate is used to prepare a dental polymerizable monomer composition containing the dental polymerizable monomer, and a dental composition containing the dental polymerizable monomer composition.

Abstract: The present invention provides a dental material, a dental material composition and a dental restorative material that exhibit small polymerization shrinkage particularly during curing and are producible at low cost on the industrial scale. The dental material of the present invention includes a specific urethane (meth)acrylic compound represented by Formula (1) described below.

Abstract: The present invention provides a novel compound and a composition including the compound that exhibit small polymerization shrinkage particularly during curing and are producible at low cost on the industrial scale.

Abstract: An easily removable dental curable composition which prevents the fall or leakage of a temporary prosthetic appliance or a root canal filling material which is easily removed by bonding and adhering it to tooth, shows such high flowability that its operation is easy, has a long working time and excellent X-ray contrast properties and sealability and can be easily removed as required, and a filling kit. The dental curable composition comprises (A) a polymerizable monomer mixture containing a polymerizable monomer having an acid group in the molecule and (B) a polymerization initiator, wherein the component (A) contains (A?) a long-chain polymerizable monomer having a structure with a chain length of 17 or more atoms and/or the composition further comprises (D1) a soft resin material.

Abstract: The present invention provides a dental polymerizable composition which has excellent handling property by the brush-dip technique and the bulk-mix technique, particularly excellent handling property by the brush-dip technique, contains few air bubbles, is excellent in color tone, polishability, mechanical properties and the discoloration resistance of a cured product at the time of curing and is used for many purposes such as the repair of a denture base or artificial tooth, a tooth crown prosthetic restoration and a temporary prosthetic restoration which is used until a bridge is completed when it is a two-composition type self-curing resin. The dental polymerizable composition comprises three different types of (meth)acrylate polymer particles, each having specific particle size characteristics and specific molecular weight characteristics.