Abstract: The invention relates to a process for the preparation of compound(s) comprising at least one acrylate or methacrylate group, at least one linear carbonate group and at least one 5-membered cyclic carbonate group. The process comprises (A) a selective ring-opening step and (B) a (meth)acrylation step. The process is environment-friendly and compounds obtained are usable in radiation curable compositions, for example in radiation-curable inks.
Abstract: A radiation curable powder coating composition is disclosed, which comprises a blend of (meth)acryloyl group containing polyphenoxy resin, a (meth)acryloyl group containing resin other than the polyphenoxy resin and other than a (meth)acryloyl group containing amorphous polyester and, eventually, a (meth)acryloyl group containing monomer or oligomer. These powders give coatings with improved chemical resistance and flexibility.
Type:
Grant
Filed:
July 23, 2002
Date of Patent:
February 7, 2006
Assignee:
Surface Specialties, S.A.
Inventors:
Luc Moens, Kris Buysens, Daniel Maetens
Abstract: The present invention is directed towards phosphorous containing organic materials, processes for making them and uses thereof. These materials preferably impart and/or exhibit resistance to attack, for example they may be useful as flame retardant additives and/or materials. The materials are especially radiation-curable polyester polymers. The phosphorous component used has at least one P—C bond resistant to hydrolysis or transesterification. It can be bis(hydroxymethyl)isobutylphosphineoxide, bis(hydroxypropyl)isobutylphosphine oxide and trishydroxymethylphosphine oxide. In other embodiments, it is 9,10-dihydro-9-oxa-10-phosphaphenantrene-10-oxide.
Abstract: The present invention relates to powdered thermosetting compositions including a binder which comprises a carboxyl group containing amorphous isophthalic acid containing polyester, a carboxyl group containing semi-crystalline polyester, at least 10 parts by weight, based on the total weight of the binder, of a specific glycidyl group containing acrylic copolymer and a curing agent having functional groups reactive with the polyesters' carboxyl groups. The powdered thermosetting compositions are useful for the preparation of powdered paints and varnishes which give low gloss coatings having an outstanding flow, a remarkable weatherability and excellent mechanical properties.