Abstract: A method for purifying ferric chloride, the method including: 1) adding an oxidant to an aqueous solution of an iron-containing chloride for oxidation of Fe2+, to yield a ferric chloride solution; 2) adding industrial hydrochloric acid and butyl acetate to the ferric chloride solution, shaking and resting a mixture of the ferric chloride solution, the industrial hydrochloric acid, and butyl acetate for phase separation, to yield an organic phase and an aqueous phase; 3) adding a stripping agent to the organic phase, shaking, and resting a mixture of the stripping agent and the organic phase; and collecting an aqueous phase including ferric chloride; and 4) evaporating and concentrating the aqueous phase including ferric chloride, removing butyl acetate, to yield purified ferric chloride.