Abstract: What is provided is a RAFT polymerization reaction solution containing a RAFT agent represented by a specific chemical formula, water, and a water-soluble inorganic base, in which the RAFT polymerization reaction solution may further contain a polymerization initiator as an optional component, the RAFT agent has an acid group, the acid group forms a salt, and a molar ratio represented by M3/(M1+M2) is 1.0 to 10, in which the number of moles of the acid group forming the salt is indicated as M1, the number of moles of an acid group of the polymerization initiator, which may form a salt, is indicated as M2, and the number of moles of the water-soluble inorganic base is indicated as M3.

Abstract: The thermoplastic resin composition includes: a (meth)acrylic acid ester copolymer obtained by polymerizing a vinyl monomer mixture containing 50% by mass or more and less than 80% by mass of a (meth)acrylic acid ester monomer and 12-39% by mass of an aromatic vinyl monomer; a hindered amine compound having a molecular weight of 200-1800; and an ultraviolet absorber compound having a maximum absorption wavelength at 250-300 nm. The thermoplastic resin composition optionally includes a graft copolymer, and the hindered amine compound is present in an amount of 0.4-1.8 parts by mass, the ultraviolet absorber compound is present in an amount of 0.1-1.6 parts by mass, and a sum of the amounts of the hindered amine compound and the ultraviolet absorber compound is not more than 2.0 parts by mass, each relative to 100 parts by mass of a combination of the (meth)acrylic acid ester copolymer and the graft copolymer.

Abstract: A hitting sound reducing material made of a (meth)acrylic acid ester polymer (B) comprising: a polymer (b1) comprising a structural unit derived from an acrylic ester compound and a structural unit derived from a methacrylic ester compound, and having a glass transition temperature of ?15° C. to +5° C.; and a polymer (b2) comprising at least one selected from the group consisting of a structural unit derived from a methacrylic acid ester compound, a structural unit derived from an aromatic vinyl compound, and a structural unit derived from a vinyl cyanide compound, wherein the polymer (b1) has a temperature (peak temperature) indicating a peak value of a main dispersion of tan ? of ?5° C. to +20° C., and a peak intensity, which is a peak value of the intensity, of 2.055 or more.

Abstract: What is provided is a graft copolymer (A) obtained by graft-polymerizing a monomer component (a) to a rubber-based polymer, in which the monomer component (a) contains 60% to 85% by mass of a mixture (a1) of ?-methylstyrene and an aromatic vinyl compound other than ?-methylstyrene with respect to the total mass of the monomer component (a), and the rubber content of the graft copolymer (A) is 35% by mass or more with respect to the total mass of the graft copolymer (A).

Abstract: What is provided is a RAFT polymerization reaction solution containing a RAFT agent represented by a specific chemical formula, water, and a water-soluble inorganic base, in which the RAFT polymerization reaction solution may further contain a polymerization initiator as an optional component, the RAFT agent has an acid group, the acid group forms a salt, and a molar ratio represented by M3/(M1+M2) is 1.0 to 10, in which the number of moles of the acid group forming the salt is indicated as M1, the number of moles of an acid group of the polymerization initiator, which may form a salt, is indicated as M2, and the number of moles of the water-soluble inorganic base is indicated as M3.

Abstract: What is provided is a graft copolymer (A) obtained by graft-polymerizing a monomer component (a) to a rubber-based polymer, in which the monomer component (a) contains 60% to 85% by mass of a mixture (a1) of ?-methylstyrene and an aromatic vinyl compound other than ?-methylstyrene with respect to the total mass of the monomer component (a), and the rubber content of the graft copolymer (A) is 35% by mass or more with respect to the total mass of the graft copolymer (A).

Abstract: What is provided is a RAFT polymerization reaction solution containing a RAFT agent represented by a specific chemical formula, water, and a water-soluble inorganic base, in which the RAFT polymerization reaction solution may further contain a polymerization initiator as an optional component, the RAFT agent has an acid group, the acid group forms a salt, and a molar ratio represented by M3/(M1+M2) is 1.0 to 10, in which the number of moles of the acid group forming the salt is indicated as M1, the number of moles of an acid group of the polymerization initiator, which may form a salt, is indicated as M2, and the number of moles of the water-soluble inorganic base is indicated as M3.

Abstract: A thermoplastic resin composition comprising: a graft copolymer (A) obtained by polymerizing a vinyl monomer mixture (m1) in the presence of a specific alkyl (meth)acrylate rubbery polymer (a); a graft copolymer (B) obtained by polymerizing a vinyl monomer mixture (m2) in the presence of a specific alkyl (meth)acrylate rubbery polymer (b); and a vinyl copolymer (C) obtained by polymerizing a vinyl monomer mixture (m3), wherein: a proportion of a rubbery polymer contained in the thermoplastic resin composition is 21 to 28% by mass, and a proportion of particles with a particle size of 300 nm or more among all particles formed by the rubbery polymer is 1 to 11% by mass.

Abstract: The resin composition for plating of the present invention includes: a graft copolymer (A) in which a monomer component (a) including specific amounts of an aromatic vinyl compound (a1), a vinyl cyanide compound (a2), and another vinyl compound (a3) is graft-polymerized on a rubbery polymer; and a polycarbonate resin (P), wherein an amount of resin (P) is 40 to 70% by mass, based on a total mass of the resin composition, a rubber content (X) in copolymer (A) is more than 40% by mass, based on a total mass of copolymer (A), a graft ratio (Y) of copolymer (A) satisfies formula (1): 793e?0.041X?Y?515e?0.041X (1), and a rubber content (Z) in the resin composition is 10 to 18% by mass, based on a total mass of the resin composition.

Abstract: A thermoplastic resin composition comprising a graft copolymer (A), a vinyl copolymer (B), and a metal component (C), wherein: an amount of the metal component (C) is 60 ppm or more relative to a total mass of the thermoplastic resin composition, the graft copolymer (A) is a graft polymer obtained by polymerizing 80% by mass to 20% by mass of a vinyl monomer mixture (m1) including at least one type of vinyl monomer in the presence of 20% by mass to 80% by mass of a rubbery polymer (a) including a polyorganosiloxane and an alkyl (meth)acrylate polymer, the vinyl copolymer (B) is a vinyl copolymer obtained by polymerizing a vinyl monomer mixture (m2) including an alkyl (meth)acrylate monomer, and the metal component (C) is an alkali metal.

Abstract: A thermoplastic resin composition comprising: a graft copolymer (A) obtained by polymerizing a vinyl monomer mixture (m1) in the presence of a specific alkyl (meth)acrylate rubbery polymer (a); a graft copolymer (B) obtained by polymerizing a vinyl monomer mixture (m2) in the presence of a specific alkyl (meth)acrylate rubbery polymer (b); and a vinyl copolymer (C) obtained by polymerizing a vinyl monomer mixture (m3), wherein: a proportion of a rubbery polymer contained in the thermoplastic resin composition is 21 to 28% by mass, and a proportion of particles with a particle size of 300 nm or more among all particles formed by the rubbery polymer is 1 to 11% by mass.

Abstract: A thermoplastic resin composition comprising a graft copolymer (A), a vinyl copolymer (B), and a metal component (C), wherein: an amount of the metal component (C) is 60 ppm or more relative to a total mass of the thermoplastic resin composition, the graft copolymer (A) is a graft polymer obtained by polymerizing 80% by mass to 20% by mass of a vinyl monomer mixture (m1) including at least one type of vinyl monomer in the presence of 20% by mass to 80% by mass of a rubbery polymer (a) including a polyorganosiloxane and an alkyl (meth)acrylate polymer, the vinyl copolymer (B) is a vinyl copolymer obtained by polymerizing a vinyl monomer mixture (m2) including an alkyl (meth)acrylate monomer. and the metal component (C) is an alkali metal.

Abstract: The thermoplastic resin composition of the invention includes: 10% to 70% by mass of (A) a rubber-reinforced vinyl-based resin containing a rubbery part derived from an acrylic rubbery polymer and a resin pan having a structural unit derived from an aromatic vinyl compound and a structural unit derived from a cyanidated vinyl compound; 5% to 80% by mass of (B) a (meth)acrylic resin (excluding component (A)) including a (co)polymer which has a structural unit derived from an alkyl (meth)acrylate ester compound and which does not have a structural unit derived from ?-methylstyrene; and 5% to 70% by mass of (C) an ?-methylstyrene-based resin (excluding component (A)) containing a (co)polymer which has a structural unit derived from ?-methylstyrene and which does not have a structural unit derived from an alkyl (meth)acrylate ester compound based on 100% by mass of a total content of components (A) to (C).

Abstract: A thermoplastic resin composition includes a rubber-reinforced styrenic thermoplastic resin (A1) in an amount of 97 to 80 parts by mass); and a hitting sound reducing material (B) in an amount of 3 to 20 parts by mass. The hitting sound reducing material (B) is a hydrogenated copolymer derived from hydrogenation of a copolymer formed of a block portion (I) primarily including structural units derived from an aromatic vinyl-based compound, and a random portion (II) primarily including structural units derived from an aromatic vinyl-based compound and primarily including structural units derived from butadiene. The structural units in the block portion (I) and the structural units derived from an aromatic vinyl-based compound in the random portion (II) are present in 55 to 80 mass % relative to a 100 total mass % of the copolymer, and the hydrogenated copolymer has a primary dispersion peak of tan ? at 0° C. or greater.

Abstract: A graft copolymer (B) produced by graft polymerization of a vinyl monomer mixture (m1) including an alkyl (meth)acrylate ester onto a copolymer (A), the copolymer (A) being a copolymer of an alkyl (meth)acrylate ester (Aa) and a (meth)acrylate ester (Ab) including an aromatic hydrocarbon group. A thermoplastic resin composition including the graft copolymer (B), a copolymer (C) that is the product of a polymerization reaction of a vinyl monomer mixture (m2) including an alkyl (meth)acrylate ester, and a molded article produced by molding the thermoplastic resin composition. Provided are the graft copolymer with which a thermoplastic resin composition excellent in terms of transparency, impact resistance, weather resistance, and flowability may be produced, a thermoplastic resin composition including the graft copolymer, and the molded article produced by molding the thermoplastic resin composition.

Abstract: A thermoplastic resin composition includes a resin component (A) in an amount of 97 to 80 parts by mass; and a hitting sound reducing material (B) in an amount of 3 to 20 parts by mass. The hitting sound reducing material (B) is a hydrogenated copolymer derived from hydrogenation of a copolymer formed of a block portion (I) primarily including structural units derived from an aromatic vinyl-based compound, and a random portion (II) primarily including structural units derived from an aromatic vinyl-based compound and derived from butadiene. The structural units derived from an aromatic vinyl-based compound in the block portion (I) and derived from an aromatic vinyl-based compound in the random portion (II) are present in a total content of 55 to 80 mass % relative to a 100 total mass % of the copolymer, and the hydrogenated copolymer has a primary dispersion peak of tan ? at 0° C. or greater.

Abstract: A thermoplastic resin composition including 7% to 64% by mass of rubber-containing graft copolymer (A), 2% to 35% by mass of thermoplastic elastomer (B), 0.5% to 90% by mass of another thermoplastic resin (C), and 0.5% to 20% by mass of inorganic compound (D) (total (A)-(D) is 100% by mass). The copolymer (A) is a graft copolymer in which 35 to 80 parts by mass of rubber-like polymer (a1) is graft-polymerized with 20 to 65 parts by mass of vinyl-based monomer mixture (a2) containing an aromatic-vinyl-based monomer and a vinyl-cyanide-based monomer. The content of polymer (a1) in the total 100% by mass of the components (A)-(D) is 2% to 35% by mass, and a difference between the content of the polymer (a1) in the total 100% by mass of the component (A) to the component (D) and the content of the elastomer (B) is within 15% by mass.

Abstract: A thermoplastic resin composition including a graft copolymer (B) produced by graft polymerization of a vinyl monomer mixture (m1) including an alkyl (meth)acrylate ester, a vinyl cyanide compound, and an aromatic vinyl compound onto a copolymer (A) produced by copolymerizing an alkyl (meth)acrylate ester (a) and a (meth)acrylate ester (b) including an aromatic hydrocarbon group at a specific ratio and a copolymer (C) that is a product of a polymerization reaction of a vinyl monomer mixture (m2) including an alkyl (meth)acrylate ester. The graft copolymer (B) includes at least a graft copolymer (B) having a specific volume-average particle size. The copolymer (A) has a specific volume-average particle size and a specific particle size distribution.

Abstract: The resin composition for plating of the present invention includes: a graft copolymer (A) in which a monomer component (a) including specific amounts of an aromatic vinyl compound (a1), a vinyl cyanide compound (a2), and another vinyl compound (a3) is graft-polymerized on a rubbery polymer; and a polycarbonate resin (P), wherein an amount of resin (P) is 40 to 70% by mass, based on a total mass of the resin composition, a rubber content (X) in copolymer (A) is more than 40% by mass, based on a total mass of copolymer (A), a graft ratio (Y) of copolymer (A) satisfies formula (1): 793e?0.041X?Y?515e?0.041X (1), and a rubber content (Z) in the resin composition is 10 to 18% by mass, based on a total mass of the resin composition.

Abstract: The coating resin composition contains a thermoplastic resin including (A) a rubber-reinforced vinyl-based resin having a rubbery portion derived from a rubbery polymer and a resin portion having a structural unit derived from an aromatic vinyl compound and (B) an olefin-based resin modified with a polar functional group containing an oxygen atom. The composition may further contain a polycarbonate resin.