Patents Assigned to Teijin Chemicals, Ltd.
  • Patent number: 6403683
    Abstract: According to the present invention, there are provided a polycarbonate resin composition which comprises (A) 40 to 92 wt % of an aromatic polycarbonate resin (component “a”), (B) 5 to 40 wt % of a styrene-based resin (component “b”), (C) 3 to 20 wt % of a phosphate-based flame retardant (component “c”), and (D) 0.1 to 30 parts by weight of a silicate filler (component “d”) based on 100 parts by weight of the total of the components “a”, “b” and “c”, and which has a chlorine compound content in terms of chlorine atoms of 100 ppm or less as well as a molded product thereof. The resin composition of the present invention can provide a molded product having excellent resistance to wet heat and flame retardancy.
    Type: Grant
    Filed: April 26, 2000
    Date of Patent: June 11, 2002
    Assignee: Teijin Chemicals Ltd
    Inventor: Hiroaki Kobayashi
  • Patent number: 6362269
    Abstract: A resin composition comprising 100 parts by weight of a resin component selected from (a) an aromatic polycarbonate resin (A-1 component) obtained by melt polymerization and, when measured for fluorescent spectrum at an exciting wavelength of 320 nm, having a relative fluorescence intensity of 4×10−3 or less at 465 nm relative to a standard substance, (b) a resin mixture of said A-1 component and a styrene-based resin (A-2 component), and (c) a resin mixture of said A-1 component and an aromatic polyester resin (A-3 component), and 5 to 200 parts by weight of a reinforcing filler. This resin composition gives a molded article superior in wet heat fatigue and various physical properties.
    Type: Grant
    Filed: June 7, 2000
    Date of Patent: March 26, 2002
    Assignee: Teijin Chemicals, Ltd.
    Inventors: Koji Ishihata, Hisanaga Shimizu, Tetsushi Ono, Makoto Takagi
  • Patent number: 6355767
    Abstract: An aromatic polycarbonate resin composition comprising: (1) 10 to 90 wt % of an aromatic polycarbonate resin (component A) which is obtained from an ester exchange reaction between a diphenol and a dicarbonate ester and has a terminal hydroxyl group concentration of 10 to 70 mol % based on 100 molt of the total of all the terminal groups; and (2) 90 to 10 wt % of a thermoplastic graft copolymer resin (component B) which is obtained by grafting a vinyl cyanide monomer component and an aromatic vinyl monomer component to a diene-based rubber, the proportion of the vinyl cyanide monomer component to the copolymer resin being 10 to 27 wt % and the amount of a vinyl cyanide monomer contained in the copolymer resin being 200 ppm or less. According to the present invention, there is provided an aromatic polycarbonate resin composition which has excellent mechanical strength, particularly falling weight impact strength and improved hydrolysis resistance under a moist heat environment.
    Type: Grant
    Filed: November 28, 2000
    Date of Patent: March 12, 2002
    Assignee: Teijin Chemicals, LTD
    Inventor: Makoto Takagi
  • Patent number: 6333437
    Abstract: A method for purifying a bromine compound by depositing the bromine compound represented by the following general formula (1) as solid particles from a crude solution containing the bromine compound: wherein (i) the crude solution is supplied into the slurry containing the particles of the bromine compound; (ii) the concentration of the particles of the bromine compound in the slurry is maintained at a predetermined range; (iii) the solvent contained in the slurry is a mixed solvent of a good solvent and a poor solvent and the ratio of the good solvent to the poor solvent is maintained at a predetermined value; and (iv) the solid particles of the bromine compound are separated from the slurry.
    Type: Grant
    Filed: September 7, 2000
    Date of Patent: December 25, 2001
    Assignee: Teijin Chemicals LTD
    Inventors: Yutaka Taketani, Haruhisa Hoshimi, Akihiro Mukai, Yasuhisa Tahira, Takahiro Sato
  • Patent number: 6060527
    Abstract: A process for recovering the resin contained in optical information recording media having either a thin metal film layer or a printed coating film layer, coated on at least one side of a resin substrate,which comprises the following steps of:(1) rolling the recording media,(2) bringing the rolled recording media into contact with hot water,(3) separating the coating film peeled from the recording media,(4) grinding the resulting recording media,(5) bringing the obtained small pieces of the recording media into contact with hot water to detach the thin metal film component, and(6) separating the detached thin metal film component from the small pieces of the recording media to recover and obtain the small pieces of the recording media.With this process, the coating layer can be removed effectively from the optical information recording media and the resin component in the recording media can be selectively recovered advantageously in industry.
    Type: Grant
    Filed: October 15, 1998
    Date of Patent: May 9, 2000
    Assignee: Teijin Chemicals Ltd
    Inventors: Hiromasa Shinomiya, Hideki Nakahiro, Tomohiro Nakado
  • Patent number: 5998674
    Abstract: Method of producing a bromine compound having an aliphatic unsaturated bond which includes reacting a compound having an aliphatic unsaturated bond represented by the following general formula (1) with bromine:R.sup.1 --O--Ar.sup.1 --Y--Ar.sup.2 --O--R.sup.2 (1)to produce a bromine compound represented by the following formula (2):R.sup.3 --O--Ar.sup.1 --Y--Ar.sup.2 --O--R.sup.4 (2)wherein Ar.sup.1, Ar.sup.2 and Y are the same as defined in the above general formula (1) , and R.sup.3 and R.sup.4 are groups obtained by saturating the unsaturated groups of R.sup.1 and R.sup.2 in the above general formula (1) with bromine, respectively.The reaction is carried out in the presence of a solvent which is inactive in the reaction, and a substantial amount of the heat of reaction is removed from a reaction system by the vaporization of the solvent or bromine. A high-purity bromine compound in high yield which is useful as flame retardant, can be obtained.
    Type: Grant
    Filed: August 21, 1998
    Date of Patent: December 7, 1999
    Assignee: Teijin Chemicals, Ltd.
    Inventors: Yutaka Taketani, Haruhisa Hoshimi, Masanori Monri, Seiichi Tanabe, Yasuhiro Shimidzu
  • Patent number: 5952096
    Abstract: A spectacle lens formed from a resin composition which consists essentially of (1) 100 parts by weight of a polycarbonate resin; (2) 0.05 to 0.5 part by weight of an ultraviolet absorber (A) having a maximum absorption in a wavelenght of 300 to 345 nm when measured in a chloroform solution; and (3) 0.01 to 0.3 part by weight of an ultraviolet absorber (B) having a maximum absorption in a wavelenght of 346 to 400 nm when measured in a chloroform solution. The spectacle lens has excellent impact resistance and transparency and high absorbing power for ultraviolet light having a specific wavelength.
    Type: Grant
    Filed: January 23, 1997
    Date of Patent: September 14, 1999
    Assignee: Teijin Chemicals, Ltd.
    Inventors: Hironori Yamashita, Tsuneo Shimada
  • Patent number: 5760160
    Abstract: An aromatic polycarbonate resin granule formed of an aggregate of fine powder particles, the granule having a specific surface area of 0.05 to 2.0 m.sup.2 /g, a bulk density of 0.3 to 0.8 g/ml, and an average particle diameter of 0.2 to 5 mm. At least 90% of the fine powder particles forming the granule have a particle diameter of 50 .mu.m or less, and the content of a halogenated hydrocarbon as an organic solvent in the granule is 50 ppm or less in terms of a halogen amount. The polycarbonate granule is obtained by preparing a slurry or wet paste containing a polycarbonate, in which the amount of an organic solvent based on the total amount of the polycarbonate and the organic solvent is 10 to 65% by weight, and the amount of water based on the polycarbonate is at least 5% by weight. The above slurry or wet paste is subjected to a pulverization step to form the fine powder particles in which at least 90% have a particle diameter of 50 .mu.m or less.
    Type: Grant
    Filed: March 7, 1997
    Date of Patent: June 2, 1998
    Assignee: Teijin Chemicals Ltd.
    Inventors: Hideki Isshiki, Akiyoshi Manabe, Katsuhiro Kutsuna
  • Patent number: 5723526
    Abstract: A resin composition consisting essentially of (a) an aromatic polycarbonate resin, (b) a thermoplastic graft copolymer obtained by grafting a diene rubber component with a vinyl cyanide compound and an aromatic vinyl compound, (c) a phosphoric acid ester, (d) a polytetrafluoroethylene, (e) a talc, and (f) a composite rubber having a network structure in which a polyorganosiloxane rubber component and a polyalkyl (meth)acrylate rubber component interpenetrate each other, each in a specified amount. This resin composition has excellent fluidity and allows easy mold- processing. The molded article made therefrom is excellent in flame retardancy, stiffness, heat-resistance, impact strength and appearance.
    Type: Grant
    Filed: April 1, 1996
    Date of Patent: March 3, 1998
    Assignee: Teijin Chemicals Ltd
    Inventor: Masashi Nagasawa
  • Patent number: 5691798
    Abstract: A progressive power ophthalmic lens having a spherical distance viewing area, a progressive power portion with a decreasing radius of curvature along an umbilic meridian, and a spherical near viewing area. Power distribution functions are optimized for smooth transition along the principal directions of gaze. A statistically smoothed polynomial function of the general form Pm=b.sub.1 +b.sub.2 X+b.sub.3 X.sup.2 +. . . +b.sub.9 X.sup.8 defines the mean power at any point on the lens surface to regulate curvature variation. Thereby providing continuity of the visual field at the boundaries of the principal lens zones and creating an integrated visual field as the eye traverses the lens.
    Type: Grant
    Filed: July 27, 1995
    Date of Patent: November 25, 1997
    Assignee: Teijin Chemicals Ltd.
    Inventor: Scott W. Smith
  • Patent number: 5663277
    Abstract: An aromatic polycarbonate resin granule formed of an aggregate of fine powder particles, the granule having a specific surface area of 0.05 to 2.0 m.sup.2 /g, a bulk density of 0.3 to 0.8 g/ml, and an average particle diameter of 0.2 to 5 mm. At least 90% of the fine powder particles forming the granule have a particle diameter of 50 .mu.m or less, and the content of a halogenated hydrocarbon as an organic solvent in the granule is 50 ppm or less in terms of a halogen amount. The polycarbonate granule is obtained by preparing a slurry or wet paste containing a polycarbonate, in which the amount of an organic solvent based on the total amount of the polycarbonate and the organic solvent is 10 to 65% by weight, and the amount of water based on the polycarbonate is at least 5% by weight. The above slurry or wet paste is subjected to a pulverization step to form the fine powder particles in which at least 90% have a particle diameter of 50 .mu.m or less.
    Type: Grant
    Filed: June 23, 1995
    Date of Patent: September 2, 1997
    Assignee: Teijin Chemicals, Ltd.
    Inventors: Hideki Isshiki, Akiyoshi Manabe, Toshinori Kitachi, Yoshifumi Ikemura, Katsuhiro Kutsuna, Tatsumi Horie
  • Patent number: 5633060
    Abstract: An optical disk substrate formed substantially of an aromatic polycarbonate from an aromatic dihydroxy component containing at least 20 mol % of 1,1-bis(4-hydroxyphenyl)-3,3,5-trimethylcyclohexane,wherein:(A) the aromatic polycarbonate has a specific viscosity of 0.2 to 0.5,(B) the aromatic polycarbonate shows a water absorption percentage of 0.2 % by weight or less,(C) the aromatic polycarbonate has an oligomer content of 10 % or less, and(D) the number of undissolved particles having a diameter of 0.5 .mu.m or greater is 25,000 pieces or less per g of the polycarbonate resin, and the number of undissolved particles having a diameter of 1 .mu.m or greater is 500 pieces or less per g of the polycarbonate resin, and an optical disk from the above substrate.
    Type: Grant
    Filed: June 16, 1995
    Date of Patent: May 27, 1997
    Assignee: Teijin Chemicals, Ltd.
    Inventors: Toshimasa Tokuda, Kuniyuki Hayashi, Tatsumi Horie
  • Patent number: 5599897
    Abstract: There is provided an aromatic polycarbonate obtained by reacting a carbonate precursor substance with a dihydric phenol comprising mainly 2,2-bis(4-hydroxyphenol)-1,1,1,3,3,3-hexafluoropropane having specific characteristics. This aromatic polycarbonate has the following characteristics. That is, with respect to 5 wt % solution of the aromatic polycarbonate in methylene chloride, after being filtered through a filter having a pore diameter of 0.1 .mu.m, the light transmittance at 400 nm measured by using a quartz cell having an optical path length of 250 mm, is 85% or more in terms of light transmittance per cm of the polymer; and when 0.7 g of the aromatic polycarbonate is dissolved in 100 ml of methylene chloride, the specific viscosity of the thus obtained solution measured at 20.degree. C., is in the range of 0.160 to 0.418.
    Type: Grant
    Filed: May 25, 1995
    Date of Patent: February 4, 1997
    Assignees: Furukawa Electric Co., Ltd., Teijin Chemicals, Ltd.
    Inventors: Masaki Nishiguchi, Toshimasa Tokuda
  • Patent number: 5556904
    Abstract: There is provided an aromatic polycarbonate copolymer obtained by reacting a dihydric phenol component comprising mainly 2,2-bis(4-hydroxyphenyl)-1,1,1,3,3,3-hexafluoropropane and 9,9-bis(4-hydroxyphenyl)fluorene or 1,1-bis(4-hydroxyphenyl)-1-phenylethane in a prescribed ratio with a carbonate precursor substance. This aromatic polycarbonate copolymer has a specific viscosity in a limited range. The aromatic polycarbonate copolymer is excellent in optical characteristics, transparency, hydrolysis resistance, heat resistance, oxidation resistance, and heat stability and good in moldability, and is suitable for a plastic optical waveguide that is small in transmission loss and excellent in heat resistance.
    Type: Grant
    Filed: January 17, 1995
    Date of Patent: September 17, 1996
    Assignees: The Furukawa Electric Co. Ltd, Teijin Chemicals Ltd.
    Inventors: Masaki Nishiguchi, Toshimasa Tokuda
  • Patent number: 5496913
    Abstract: There is provided an aromatic polycarbonate obtained by reacting a carbonate precursor substance with a dihydric phenol comprising mainly 2,2-bis(4-hydroxyphenol)-1,1,1,3,3,3-hexafluoropropane having specific characteristics. This aromatic polycarbonate has the following characteristics. That is, with respect to 5 wt % solution of the aromatic polycarbonate in methylene chloride, after being filtered through a filter having a pore diameter of 0.1 .mu.m, the light transmittance at 400 nm measured by using a quartz cell having an optical path length of 250 mm, is 85% or more in terms of light transmittance per cm of the polymer; and when 0.7 g of the aromatic polycarbonate is dissolved in 100 ml of methylene chloride, the specific viscosity of the thus obtained solution measured at 20.degree. C., is in the range of 0.160 to 0.418.
    Type: Grant
    Filed: October 25, 1993
    Date of Patent: March 5, 1996
    Assignees: Furukawa Electric Co., Ltd, Teijin Chemicals Ltd.
    Inventors: Masaki Nishiguchi, Toshimasa Tokuda
  • Patent number: 5494171
    Abstract: Fine particles which electrostatically adhere to synthetic resin pellets are separated from the pellets by bringing the pellets/fine particles mixture into contact with an ionized gas. The ionized gas eliminates the electrostatic adhesion between the synthetic resin pellets and the fine particles. The resulting fine particles may thereafter be readily separated from the pellets and the freed fine particles may be withdrawn in a gas stream. Removal of the fine particles to less than 40 ppm is possible. Apparatus for carrying out the method is also described as is a system for stocking synthetic resin pellets using the described apparatus.
    Type: Grant
    Filed: March 22, 1994
    Date of Patent: February 27, 1996
    Assignee: Teijin Chemicals Ltd.
    Inventors: Akira Kazamoto, Yoshiaki Oishi
  • Patent number: 5478874
    Abstract: A flame-retardant aromatic polycarbonate resin composition has excellent flame retardancy and high transparency without impairing excellent properties inherent to an aromatic polycarbonate resin, and is free from corroding a molding machine or a processing machine, the flame-retardant resin composition comprising 100 parts by weight of an aromatic polycarbonate resin, 0.01 to 1 part by weight of (a) a perfluoroalkane-sulfonic acid alkali salt and 0.02 to 2 parts by weight of (b) a halogenated triaryl phosphate of the formula [1], ##STR1## wherein each of Ar.sup.1, Ar.sup.2 and Ar.sup.3 is independently an aromatic hydrocarbon, and at least one halogen atom is substituted on ring-forming carbon of each aromatic hydrocarbon group.
    Type: Grant
    Filed: March 3, 1995
    Date of Patent: December 26, 1995
    Assignee: Teijin Chemicals Ltd.
    Inventors: Masahiro Miyouga, Shinichi Souda
  • Patent number: 5475786
    Abstract: There is provided an aromatic polycarbonate copolymer obtained by reacting a dihydric phenol component comprising mainly 2,2-bis(4-hydroxyphenyl)-1,1,1,3,3,3-hexafluoropropane and 9,9-bis(4-hydroxyphenyl)fluorene or 1,1-bis(4-hydroxyphenyl)-1-phenylethane in a prescribed ratio with a carbonate precursor substance. This aromatic polycarbonate copolymer has a specific viscosity in a limited range. The aromatic polycarbonate copolymer is excellent in optical characteristics, transparency, hydrolysis resistance, heat resistance, oxidation resistance, and heat stability and good in moldability, and is suitable for a plastic optical waveguide that is small in transmission loss and excellent in heat resistance.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: December 12, 1995
    Assignees: The Furukawa Electric Co., Ltd., Teijin Chemicals, Ltd.
    Inventors: Masaki Nishiguchi, Toshimasa Tokuda
  • Patent number: 5463013
    Abstract: A modified aromatic polycarbonate resin containing at least one substituted phenyloxy group of the formula (I) in an amount of at least 5 mol % of the total amount of terminals, ##STR1## wherein: X is a halogen atom or a monovalent aliphatic hydrocarbon group having 1 to 10 carbon atoms,p is an integer of 0 to 4, and ##STR2## The present invention provide a modified aromatic polycarbonate resin of which the melt fluidity and electric properties are improved without impairing the excellent properties inherent to a polycarbonate resin such as transparency, heat resistance and dimensional stability.
    Type: Grant
    Filed: April 26, 1994
    Date of Patent: October 31, 1995
    Assignee: Teijin Chemicals, Ltd.
    Inventors: Toshimasa Tokuda, Ikkoh Furukawa, Masayoshi Miyauchi
  • Patent number: 5444114
    Abstract: According to the present invention there is provided a thermoplastic resin composition comprising an aromatic polycarbonate resin, potassium titanate and an organic acid. This resin composition can be advantageously used for molding large parts for precision machines and large parts for automobiles.
    Type: Grant
    Filed: March 15, 1994
    Date of Patent: August 22, 1995
    Assignee: Teijin Chemicals, Ltd.
    Inventors: Hisanaga Shimizu, Shinji Takeshita, Kazuo Kitamura