Patents Assigned to TERRALITHIUM LLC
  • Patent number: 12252409
    Abstract: This invention relates to a method for the preparation of lithium carbonate from lithium chloride containing brines. The method can include a silica removal step, capturing lithium chloride, recovering lithium chloride, supplying lithium chloride to an electrochemical cell and producing lithium hydroxide, contacting the lithium hydroxide with carbon dioxide to produce lithium carbonate.
    Type: Grant
    Filed: April 10, 2023
    Date of Patent: March 18, 2025
    Assignee: TERRALITHIUM LLC
    Inventor: Stephen Harrison
  • Patent number: 12221671
    Abstract: This invention relates to treated geothermal brine compositions containing reduced concentrations of iron, silica, and manganese compared to the untreated brines. Exemplary compositions contain a concentration of manganese less than 10 mg/kg, a concentration of silica ranging from less than 10 mg/kg, and a concentration of iron less than 10 mg/kg, and the treated geothermal brine is derived from a Salton Sea geothermal reservoir.
    Type: Grant
    Filed: May 21, 2020
    Date of Patent: February 11, 2025
    Assignee: TERRALITHIUM LLC
    Inventors: Stephen Harrison, John Burba, III
  • Publication number: 20250002363
    Abstract: Provided are methods of extracting lithium from a lithium containing solution, as well as the resulting compositions. The method includes supplying a lithium containing solution to a lithium capture step, the lithium capture step being operable to capture lithium from the lithium salt containing solution. The method further includes recovering lithium from the lithium capture step to produce a lithium rich stream. In especially preferred methods, the lithium capture step is performed to increase the lithium to sodium ratio above at least 1:1. Optionally, the lithium rich stream can be purified to remove divalent ions and borate ions. The lithium rich stream is then concentrated by supplying the lithium rich stream to a reverse osmosis step to produce a concentrated lithium rich stream.
    Type: Application
    Filed: October 12, 2021
    Publication date: January 2, 2025
    Applicant: TERRALITHIUM LLC
    Inventors: Stephen Harrison, Brian J. Dougherty
  • Patent number: 12168748
    Abstract: This invention relates to treated geothermal brine compositions containing reduced concentrations of lithium, iron and silica compared to the untreated brines. Exemplary compositions contain concentration of lithium ranges from 0 to 200 mg/kg, concentration of silica ranges from 0 to 30 mg/kg, concentration of iron ranges from 0 to 300 mg/kg. Exemplary compositions also contain reduced concentrations of elements like arsenic, barium, and lead.
    Type: Grant
    Filed: August 31, 2022
    Date of Patent: December 17, 2024
    Assignee: Terralithium LLC
    Inventors: Stephen Harrison, John Burba, III
  • Publication number: 20240271026
    Abstract: This invention relates to treated geothermal brine compositions containing reduced concentrations of lithium, iron and silica compared to the untreated brines. Exemplary compositions contain concentration of lithium ranges from 0 to 200 mg/kg, concentration of silica ranges from 0 to 30 mg/kg, concentration of iron ranges from 0 to 300 mg/kg. Exemplary compositions also contain reduced concentrations of elements like arsenic, barium, and lead.
    Type: Application
    Filed: March 20, 2024
    Publication date: August 15, 2024
    Applicant: TERRALITHIUM LLC
    Inventors: Stephen Harrison, John Burba, III
  • Publication number: 20240229777
    Abstract: This invention relates to a method for producing geothermal power using geothermal brines while producing a reduced silica and iron brine having improved injectivity. The resulting compositions include a composition with reduced silica, iron, and lithium having reduced quantity of total suspended solids.
    Type: Application
    Filed: October 17, 2023
    Publication date: July 11, 2024
    Applicant: Terralithium LLC
    Inventors: Stephen Harrison, John Burba, III
  • Patent number: 12030017
    Abstract: A method of concentrating a lithium-containing aqueous solution, the method comprising: (i) providing a water-permeable structure having an inner surface and outer surface, wherein at least said outer surface is coated with a water-permeable hydrophilic polymer having a thermal stability of at least 100° C.; and (ii) flowing a lithium-containing aqueous feed solution having an initial concentration of lithium over said inner surface while said outer surface is in contact with an aqueous draw solution containing a higher overall ion concentration than said lithium-containing aqueous feed solution, to result in forward osmosis of water from said lithium-containing aqueous feed solution to said aqueous draw solution, and wherein said forward osmosis results in a lithium-containing aqueous product solution having an increased concentration of lithium relative to the initial concentration of lithium in the lithium-containing aqueous feed solution.
    Type: Grant
    Filed: August 8, 2019
    Date of Patent: July 9, 2024
    Assignees: UT-Battelle, LLC, TERRALITHIUM LLC
    Inventors: Ramesh R. Bhave, Vishwanath Deshmane, Nicholas N. Linneen, Stephen Harrison, Mariappan Paranthaman, Bruce A. Moyer, Syed Z. Islam
  • Patent number: 11828272
    Abstract: This invention relates to a method for producing geothermal power using geothermal brines while producing a reduced silica and iron brine having improved injectivity. The resulting compositions include a composition with reduced silica, iron, and lithium having reduced quantity of total suspended solids.
    Type: Grant
    Filed: January 12, 2021
    Date of Patent: November 28, 2023
    Assignee: Terralithium LLC
    Inventors: Stephen Harrison, John Burba, III
  • Publication number: 20230322567
    Abstract: The invention generally relates to methods of removing potassium, rubidium, and/or cesium, selectively or in combination, from brines using tetrafluoroborates. Also disclosed are methods of producing potassium, rubidium, and/or cesium chlorides using ionic liquids and exchange media. This invention also generally relates to treated geothermal brine compositions containing reduced concentrations of silica, iron, and potassium compared to the untreated brines. Exemplary compositions of the treated brine contain a concentration of silica ranging from about 0 mg/kg to about 15 mg/kg, a concentration of iron ranging from about 0 mg/kg to about 10 mg/kg, and a concentration of potassium ranging from about 300 mg/kg to about 8500 mg/kg. Other exemplary compositions of the treated brines also contain reduced concentrations of elements like rubidium, cesium, and lithium.
    Type: Application
    Filed: March 16, 2023
    Publication date: October 12, 2023
    Applicant: TERRALITHIUM LLC
    Inventors: Stephen Harrison, C.V. Krishnamohan Sharma, Raghunandan Bhakta, Pei-Yu Lan
  • Publication number: 20230303401
    Abstract: This invention relates to a method for the preparation of lithium carbonate from lithium chloride containing brines. The method can include a silica removal step, capturing lithium chloride, recovering lithium chloride, supplying lithium chloride to an electrochemical cell and producing lithium hydroxide, contacting the lithium hydroxide with carbon dioxide to produce lithium carbonate.
    Type: Application
    Filed: April 10, 2023
    Publication date: September 28, 2023
    Applicant: TERRALITHIUM LLC
    Inventor: Stephen Harrison
  • Patent number: 11649170
    Abstract: This invention relates to a method for the preparation of lithium carbonate from lithium chloride containing brines. The method can include a silica removal step, capturing lithium chloride, recovering lithium chloride, supplying lithium chloride to an electrochemical cell and producing lithium hydroxide, contacting the lithium hydroxide with carbon dioxide to produce lithium carbonate.
    Type: Grant
    Filed: August 7, 2020
    Date of Patent: May 16, 2023
    Assignee: Terralithium LLC
    Inventor: Stephen Harrison
  • Publication number: 20230087180
    Abstract: This invention relates to a method for the preparation of lithium carbonate from lithium chloride containing brines. The method can include a silica removal step, capturing lithium chloride, recovering lithium chloride, supplying lithium chloride to an electrochemical cell and producing lithium hydroxide, contacting the lithium hydroxide with carbon dioxide to produce lithium carbonate.
    Type: Application
    Filed: September 21, 2022
    Publication date: March 23, 2023
    Applicant: TERRALITHIUM LLC
    Inventor: Stephen Harrison
  • Publication number: 20230085171
    Abstract: This invention relates to treated geothermal brine compositions containing reduced concentrations of lithium, iron and silica compared to the untreated brines. Exemplary compositions contain concentration of lithium ranges from 0 to 200 mg/kg, concentration of silica ranges from 0 to 30 mg/kg, concentration of iron ranges from 0 to 300 mg/kg. Exemplary compositions also contain reduced concentrations of elements like arsenic, barium, and lead.
    Type: Application
    Filed: August 31, 2022
    Publication date: March 16, 2023
    Applicant: TERRALITHIUM LLC
    Inventors: Stephen Harrison, John Burba, III
  • Patent number: 11466191
    Abstract: This invention relates to treated geothermal brine compositions containing reduced concentrations of lithium, iron and silica compared to the untreated brines. Exemplary compositions contain concentration of lithium ranges from 0 to 200 mg/kg, concentration of silica ranges from 0 to 30 mg/kg, concentration of iron ranges from 0 to 300 mg/kg. Exemplary compositions also contain reduced concentrations of elements like arsenic, barium, and lead.
    Type: Grant
    Filed: October 1, 2020
    Date of Patent: October 11, 2022
    Assignee: Terralithium LLC
    Inventors: Stephen Harrison, John Burba, III
  • Publication number: 20220105466
    Abstract: Systems, methods and apparatuses to concentrate lithium containing solutions using forward osmosis units are provided, which, for example, can include providing at least one forward osmosis unit having at least one lithium containing solution chamber having at least one first inlet and at least one first outlet, at least one brine chamber having at least one second inlet and at least one second outlet, and at least one selectively permeable membrane positioned between the at least one lithium containing solution chamber and the at least one brine chamber, and conveying a lithium containing solution through the at least one lithium containing solution chamber and a concentrated brine solution through the at least one brine chamber, said conveying causing water from the lithium containing solution to be drawn through the at least one selectively permeable membrane and into the concentrated brine solution, such that a concentrated lithium containing solution exits through the first outlet and a less concentrated
    Type: Application
    Filed: December 15, 2021
    Publication date: April 7, 2022
    Applicant: Terralithium LLC
    Inventors: Stephen Harrison, Dennis L. Howe, Brian J. Dougherty
  • Patent number: 11235282
    Abstract: Systems, methods and apparatuses to concentrate lithium containing solutions using forward osmosis units are provided, which, for example, can include providing at least one forward osmosis unit having at least one lithium containing solution chamber having at least one first inlet and at least one first outlet, at least one brine chamber having at least one second inlet and at least one second outlet, and at least one selectively permeable membrane positioned between the at least one lithium containing solution chamber and the at least one brine chamber, and conveying a lithium containing solution through the at least one lithium containing solution chamber and a concentrated brine solution through the at least one brine chamber, said conveying causing water from the lithium containing solution to be drawn through the at least one selectively permeable membrane and into the concentrated brine solution, such that a concentrated lithium containing solution exits through the first outlet and a less concentrated
    Type: Grant
    Filed: November 19, 2019
    Date of Patent: February 1, 2022
    Assignee: Terralithium LLC
    Inventors: Stephen Harrison, Dennis L. Howe, Brian J. Dougherty
  • Publication number: 20220010408
    Abstract: Provided are methods of extracting lithium from a lithium containing solution, as well as the resulting compositions. The method includes supplying a lithium containing solution to a lithium capture step, the lithium capture step being operable to capture lithium from the lithium salt containing solution. The method further includes recovering lithium from the lithium capture step to produce a lithium rich stream. In especially preferred methods, the lithium capture step is performed to increase the lithium to sodium ratio above at least 1:1. Optionally, the lithium rich stream can be purified to remove divalent ions and borate ions. The lithium rich stream is then concentrated by supplying the lithium rich stream to a reverse osmosis step to produce a concentrated lithium rich stream.
    Type: Application
    Filed: September 17, 2021
    Publication date: January 13, 2022
    Applicant: TERRALITHIUM LLC
    Inventors: Stephen Harrison, Brian J. Dougherty
  • Patent number: 11174532
    Abstract: Provided are methods of extracting lithium from a lithium containing solution, as well as the resulting compositions. The method includes supplying a lithium containing solution to a lithium capture step, the lithium capture step being operable to capture lithium from the lithium salt containing solution. The method further includes recovering lithium from the lithium capture step to produce a lithium rich stream. In especially preferred methods, the lithium capture step is performed to increase the lithium to sodium ratio above at least 1:1. Optionally, the lithium rich stream can be purified to remove divalent ions and borate ions. The lithium rich stream is then concentrated by supplying the lithium rich stream to a reverse osmosis step to produce a concentrated lithium rich stream.
    Type: Grant
    Filed: March 8, 2019
    Date of Patent: November 16, 2021
    Assignee: Terralithium LLC
    Inventors: Stephen Harrison, Brian J. Dougherty
  • Publication number: 20210155840
    Abstract: This invention relates to treated geothermal brine compositions containing reduced concentrations of lithium, iron and silica compared to the untreated brines. Exemplary compositions contain concentration of lithium ranges from 0 to 200 mg/kg, concentration of silica ranges from 0 to 30 mg/kg, concentration of iron ranges from 0 to 300 mg/kg. Exemplary compositions also contain reduced concentrations of elements like arsenic, barium, and lead.
    Type: Application
    Filed: October 1, 2020
    Publication date: May 27, 2021
    Applicant: TERRALITHIUM LLC
    Inventors: Stephen Harrison, John Burba, III
  • Publication number: 20210140412
    Abstract: This invention relates to a method for producing geothermal power using geothermal brines while producing a reduced silica and iron brine having improved injectivity. The resulting compositions include a composition with reduced silica, iron, and lithium having reduced quantity of total suspended solids.
    Type: Application
    Filed: January 12, 2021
    Publication date: May 13, 2021
    Applicant: Terralithium LLC
    Inventors: Stephen Harrison, John Burba, III