Patents Assigned to Texaco Development Corp.
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Patent number: 4216098Abstract: Hydrocarbons are recovered from a subterranean hydrocarbon-bearing formation penetrated by an injection well and a production well by displacing hydrocarbons toward the production well using a drive fluid such as water thickened with a polymer comprising repeating units of vinyl sulfonic acid alkoxylated with ethylene oxide or a mixture of ethylene oxide and propylene oxide. Optionally, the drive fluid can be saturated with carbon dioxide and/or natural gas at the injection pressure.Type: GrantFiled: June 19, 1978Date of Patent: August 5, 1980Assignee: Texaco Development Corp.Inventor: Walter D. Hunter
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Patent number: 4208280Abstract: Covers a method of separating a nonionic surfactant from an anionic surfactant by use of cyclohexanone.Type: GrantFiled: February 13, 1978Date of Patent: June 17, 1980Assignee: Texaco Development Corp.Inventor: Carter G. Naylor
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Patent number: 4203910Abstract: A novel catalyst material of a boron containing substance for catalyzing the liquid phase oxidation of an olefin with an organic hydroperoxide to the corresponding oxirane is disclosed. The novel catalyst materials are characterized as binary or ternary boride compounds having the general formula M.sub.x B.sub.y or M.sub.x B.sub.y R.sub.z wherein x is an integer from 1-5; y is an integer from 1-2; z is an integer from 1-4; B is boron; M is an element selected from the groups II-A, III-B, IV-B, V-B, VI-B, VII-B, VIII, III-A, IV-A, and V-A of the Periodic Table, the rare earths, and the actinides; and R is an element different from M selected from the same group of elements in the Periodic Table as M. The preferred catalyst materials are those boron containing substances which are substantially insoluble in the reaction mixture containing the organic hydroperoxides, olefins and products.Type: GrantFiled: February 7, 1979Date of Patent: May 20, 1980Assignee: Texaco Development Corp.Inventor: Robert M. Gipson
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Patent number: 4191706Abstract: Covers certain aromatic-amine amides which comprise the reaction product of a polyoxypropylene polyamine selected from the group consisting of diamines, triamines and mixtures thereof, and having an average molecular weight of 190 to about 3000 and an isatoic anhydride of the formula: ##STR1## where R is selected from the group consisting of hydrogen, alkyl, nitro, halo, hydroxy, amino, and cyano, and n is a number of 1-4. Also covers the use of said compounds as chain-extenders in polyurethane compositions. Such chain-extenders provide for the production of polyurethane elastomers having improved tensile strength, tear strength and elongation properties.Type: GrantFiled: April 13, 1978Date of Patent: March 4, 1980Assignee: Texaco Development Corp.Inventors: Edward T. Marquis, Ernest L. Yeakey
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Patent number: 4184024Abstract: Covers novel polyols comprising the reaction product of a 2,3-morpholinedione and a polyoxypropylene polyamine. Said polyols or alkoxylated derivatives thereof may be used in preparing polyurethane or polyisocyanurate polymers, particularly those polymers in cellular or foam form.Type: GrantFiled: June 12, 1978Date of Patent: January 15, 1980Assignee: Texaco Development Corp.Inventor: Howard P. Klein
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Patent number: 4184023Abstract: Covers a method of producing a polyurethane by utilizing N-(dimethylaminopropyl)methacrylamide as a catalyst in reacting an organic polyisocyanate with an organic polyester polyol or polyether polyol in the presence of said catalyst.Type: GrantFiled: October 10, 1978Date of Patent: January 15, 1980Assignee: Texaco Development Corp.Inventor: Michael Cuscurida
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Patent number: 4181682Abstract: Covers a polymeric amine having the following structural formula: ##STR1## where x is an average number ranging from about 6 to 50, and y and z are average numbers ranging from about 1 to about 20, with the sum of y and z being from about 6 to about 40. Also covers a method of preparing said amine polymer.Type: GrantFiled: January 9, 1978Date of Patent: January 1, 1980Assignee: Texaco Development Corp.Inventors: Lewis W. Watts, Jr., Harold G. Waddill
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Patent number: 4180643Abstract: Covers a new composition of matter comprising an acrylamide or methacrylamide monomer characterized by the following structural formula: ##STR1## where R.sub.1, R.sub.2 and R.sub.5 are hydrogen or methyl, R.sub.3 and R.sub.4 are lower alkyl, n is an integer ranging from 1 to 6 and A represents an anion.Type: GrantFiled: November 16, 1978Date of Patent: December 25, 1979Assignee: Texaco Development Corp.Inventors: Philip H. Moss, Edward C. Y. Nieh
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Patent number: 4180644Abstract: Covers certain aromatic-amine amides which comprise the reaction product of an alkylene polyoxypropylene diamine, triamine, or tetramine and an isatoic anhydride of the formula: ##STR1## where R" is selected from the group consisting of hydrogen, alkyl, nitro, halo, hydroxy, amino, and cyano, and n is a number of 1-4. Also covers the use of said compounds as chain-extenders in polyurethane compositions. Such chain-extenders provide for the production of polyurethane elastomers having improved tensile strength, tear strength and elongation properties.Type: GrantFiled: July 31, 1978Date of Patent: December 25, 1979Assignee: Texaco Development Corp.Inventors: Edward T. Marquis, Ernest L. Yeakey
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Patent number: 4179418Abstract: A water based epoxy resin is disclosed. The epoxy resin is useful in protective coatings. It should have little or no utility in casting, encapsulating, etc. applications because of difficulty in removal of solvent, i.e., water. The cured epoxy resin is made by curing an epoxy resin of the polyhydric phenol, polyglycidyl ether type by combining the resin with a reactive water-compatible polyamide in an aqueous medium. The polyamide is prepared from fatty acids and an aminopropyl derivative of a polyoxyalkylenepolyamine.Type: GrantFiled: March 6, 1978Date of Patent: December 18, 1979Assignee: Texaco Development Corp.Inventor: Harold G. Waddill
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Patent number: 4179552Abstract: A process for the accelerated cure of an epoxy resin is disclosed. The resulting epoxy resin may be used in protective coatings, adhesives, seamless and terrazo flooring and caulking and sealing compositions. The resulting resin is also useful, for example, in casting, potting, in escapulating, grouting and patching. The process involves mixing an epoxy resin of the polyhydric phenol, polyglycidyl ether type with a curing agent comprising the reaction product of an epoxy resin with an excess of an aminoalkylene derivative of a polyoxyalkylenepolyamine.Type: GrantFiled: March 27, 1978Date of Patent: December 18, 1979Assignee: Texaco Development Corp.Inventor: Harold G. Waddill
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Patent number: 4178426Abstract: The adhesion properties of amine-cured epoxy resins are enhanced by addition of certain polyether diureide additives in combination with specific amine curing agents. The adhesively superior epoxy resin composition comprises a vincinal polyepoxide, a curing amount of an aminopropyl ethylenediamine curing agent, and an effective amount of a polyether diureide having terminal ureido or monosubstituted ureido groups and a molecular weight of from about 2000 to about 3000.Type: GrantFiled: February 27, 1978Date of Patent: December 11, 1979Assignee: Texaco Development Corp.Inventor: Harold G. Waddill
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Patent number: 4178427Abstract: An improved curable epoxy resin composition of a vicinalpolyepoxide and an effective amount of a novel polyether urea curing agent is disclosed. The improved curable epoxy resins which are useful as coatings, castings, sealants, and adhesives show improved tensile shear strength, flexural strength, and ultimate elongation. The novel polyether urea curing agents of the instant invention are characterized by terminal primary amino groups and are formed by reaction of polyoxyalkylenepolyamines with urea, urea forming compounds, or bifunctional isocyanates.A preferred curing agent includes a mixture of a novel polyether urea formed by reaction of a polyoxypropylenepolyamine having a molecular weight of from about 200-2000 and an effective amount of urea; and another known epoxy resin curing agent such as polyoxyalkylenepolyamine in ratios of from about 5:1 to 1:5 by weight.Type: GrantFiled: February 6, 1978Date of Patent: December 11, 1979Assignee: Texaco Development Corp.Inventors: Harold G. Waddill, Heinz Schulze
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Patent number: 4175097Abstract: Covers compounds of the formula: ##STR1## where R is lower alkyl and R.sub.1 is hydrogen, alkyl or aryl and ##STR2## where R is lower alkyl and R.sub.2 is hydrogen or alkyl. Also covers a method of producing a polyurethane by utilizing said above compounds as catalysts in reacting an organic polyisocyanate with an organic polyester polyol or polyether polyol in the presence of said catalyst.Type: GrantFiled: October 21, 1977Date of Patent: November 20, 1979Assignee: Texaco Development Corp.Inventor: Edward E. McEntire
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Patent number: 4172847Abstract: A process for treating methylene-bridged polyphenylpolyamine mixtures prepared by the silica-alumina catalyzed condensation reaction of aniline and formaldehyde to obtain substantially pure low functionality Diaminodiphenylmethanes having increased 4,4'-positional isomer content and a higher functionality methylene-bridge polyphenylpolyamine mixture having a narrow molecular weight range is disclosed. A methylene-bridge polyphenylpolyamine mixture, prepared by the condensation reaction of aniline and formaldehyde carried out in the presence of a silica-alumina cracking catalyst, containing at least about 75 weight percent diaminodiphenylmethanes based upon the weight of the mixture and having a 4,4'-positional isomer content in the diamine portion of above about 65%, based upon the weight of the diamine portion, is admixed at a temperature of from about room temperature to about 150.degree. C. with a material capable of forming a solution with the mixture at the temperature employed.Type: GrantFiled: November 11, 1974Date of Patent: October 30, 1979Assignee: Texaco Development Corp.Inventors: Edward T. Marquis, Heinz Schulze
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Patent number: 4169177Abstract: Resistance to thermal shock of certain anhydride cured epoxy resins is unexpectedly enhanced by addition of a diamide of a polyoxyalkylenepolyamine-urea condensate. This superior resistance does not appreciably compromise heat deflection properties. The resins comprise a vicinal polyepoxide, a curing amount of a certain bicyclic anhydride and an effective amount of a diamide of a polyoxyalkylenepolyamine-urea condensate having a molecular weight of from about 4000 to 4500.Type: GrantFiled: March 30, 1978Date of Patent: September 25, 1979Assignee: Texaco Development Corp.Inventors: Harold G. Waddill, Heinz Schulze
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Patent number: 4167498Abstract: A process for the water based cure of an epoxy resin is disclosed. The resulting epoxy resin is useful in protective coatings. The epoxy system of the patent application should be useful in coating formulations. It should have little or no utility in casting, encapsulating, etc. applications because of difficulty in removal of solvent, i.e., water. The process involves curing an epoxy resin of the polyhydric phenol, polyglycidyl ether type by combining the resin with a reactive water-compatible polyamide in an aqueous medium. The polyamide is prepared from fatty acids and an aminopropyl derivative of a polyoxyalkylenepolyamine.Type: GrantFiled: December 27, 1977Date of Patent: September 11, 1979Assignee: Texaco Development Corp.Inventor: Harold G. Waddill
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Patent number: 4162931Abstract: Novel thermoplastic adhesive components, prepared from inexpensive and readily available synthetic materials, having melting points between about 20.degree. C. to about 180.degree. C. and broad ranges of hardness, flexibility and compatibility are disclosed. The novel thermoplastic compounds useful in adhesive formulations are comprised of a resinous polyamide reaction product of a polyoxypropylene polyamine having an average molecular weight of from about 190 to about 3,000 and being selected from diamines, triamines, or mixtures thereof, piperazine and an aliphatic or aromatic dicarboxylic acid, ester or anhydride having from about 4 to about 20 carbon atoms per molecule. The resinous polyamide reaction product is prepared by mixing and reacting the polyoxypropylene polyamine, piperazine, and dicarboxylic acid materials in a total amine:acid molar ratio within the range of from about 0.25:1.0 to about 4.0:1.0 at a temperature of from about 175.degree. C. to about 270.degree. C.Type: GrantFiled: November 14, 1977Date of Patent: July 31, 1979Assignee: Texaco Development Corp.Inventors: Ernest L. Yeakey, Harold G. Waddill
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Patent number: 4156760Abstract: Covers a method of producing a polyurethane by utilizing aminoimide compounds as catalysts in reacting an organic polyisocyanate with an organic polyester polyol or polyether polyol in the presence of said catalyst. Said aminoimides have the formula: ##STR1## where R.sub.1 and R.sub.2 are independently alkyl, or when taken together are selected from the group consisting of morpholino and piperazino, R.sub.3 is selected from the group consisting of --CH.sub.2 CH.sub.2 --, --CH.sub.2 CH.sub.2 CH.sub.2 -- and ##STR2## AND N IS A NUMBER OF 1-6.Type: GrantFiled: August 16, 1978Date of Patent: May 29, 1979Assignee: Texaco Development Corp.Inventor: Robert L. Zimmerman
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Patent number: 4154724Abstract: Novel polyether polyureides useful in the manufacture of plastics, sealants, molds, foams and coatings. The novel composition comprises a ureido-terminated polyoxyalkylene prepared by reacting a primary amine-terminated polyoxyalkylene with urea at temperatures in the range from about 120.degree. C. to about 150.degree. C. in a molar ratio of about one mole of urea for each terminal primary amino group.Type: GrantFiled: June 28, 1976Date of Patent: May 15, 1979Assignee: Texaco Development Corp.Inventor: Heinz Schulze