Abstract: The invention provides methods for (1) reducing the fluid loss of and (2) reducing the concentration of polymer required to provide a desired degree of fluid loss control to, a well drilling and servicing fluid which contains at least one polymeric viscosifier, at least one polymeric fluid loss control additive, and a water soluble bridging agent suspended in an a liquid in which the bridging agent is not soluble, the methods comprising adding to the fluids a particulate, water soluble, ultra fine filtrate reducing agent having a particle size distribution such that at least 90% of the particles thereof are less than 10 micrometers and the average particle size is from about 3 to about 5 micrometers, the ultra fine filtrate reducing agent being insoluble in the liquid.
Type:
Grant
Filed:
March 25, 1994
Date of Patent:
May 13, 1997
Assignee:
Texas United Chemical Corporation
Inventors:
James W. Dobson, Jr., Paul D. Kayga, Jesse C. Harrison, III
Abstract: The invention provides (1) a method of increasing the thermal stability of an aqueous polysaccharide-containing fluid by adding thereto magnesia and a thiosulfate salt; (2) a drilling, completion, or workover fluid comprising an aqueous liquid, a water soluble polysaccharide, magnesia, and a thiosulfate salt; and (3) an additive for increasing the thermal stability of an aqueous polysaccharide-containing fluid which comprises magnesia and a thiosulfate salt in a weight ratio of magnesia to thiosulfate salt from about 0.15/1 to about 6.67/1. The preferred magnesia has an activity index less than 100, most preferably less than 50. The preferred thiosulfate salt is sodium thiosulfate. The preferred polysaccharide is selected from the group consisting of xanthan gum, epichlorohydrin crosslinked starch, carboxymethyl cellulose, and mixtures thereof. The preferred aqueous liquid is a saturated sodium chloride solution.
Abstract: The invention provides a process for the removal of filter cakes containing one or more polysaccharide polymers and bridging particles from the sides of a borehole in a hydrocarbon-producing formation which comprises contacting the filter cake with a novel soak solution comprising an aqueous liquid, a peroxide selected from the group consisting of alkaline earth metal peroxides, zinc peroxide, and mixtures thereof, and an acidic substance to provide the soak solution with a pH in the range from about 1 to about 8, and optionally, an activator for the peroxide, for a period of time at least sufficient to decompose the polysaccharide polymers therein to such an extent that the filter cake forms a loosely adherent mass on the sides of the borehole, and thereafter contacting the filter cake with a wash solution in which the bridging particles are soluble to remove the remaining filter cake solids from the sides of the borehole.
Abstract: Disclosed are well working and treating fluids comprising a saturated aqueous saline solution, a particulate water soluble salt which is insoluble in the saturated saline solution, xanthomonas gum, and an epichlorohydrin crosslinked hydroxypropyl starch derivative wherein the xanthomonas gum and the epichlorohydrin crosslinked hydroxypropyl starch derivative interact to synergistically enhance the suspension characteristics of the fluid and to decrease the fluid loss of the fluid.Also disclosed is an additive composition for enhancing the suspension characteristics and reducing the fluid loss of saturated brine based well treating fluids comprising specified proportions of xanthomonas gum and epichlorohydrin crosslinked hydroxypropyl starch.
Type:
Grant
Filed:
February 29, 1988
Date of Patent:
April 18, 1989
Assignee:
Texas United Chemical Corporation
Inventors:
James W. Dobson, Jr., Alan T. Mondshine, Thomas C. Mondshine