Abstract: A sunscreen composition containing a UV-B dibenzoylmethane derivative, such as 4-(1,1-dimethylethyl)-4′-methoxydibenzoylmethane (PARSOL 1789), and a stabilizer/solubilizer for the dibenzoylmethane derivative selected from formula (I) and formula (II), and mixtures thereof:
wherein
m=5, 7, 9 or mixtures and
n=4, 6, 8 or mixtures;
wherein p1 m=5, 7 or mixtures and
n=4, 6 or mixtures.
These long branched chain alkyl hydroxybenzoates and long branched chain benzoates having a C4+ branch at the 2 position are quite effective in stabilizing the dibenzoylmethane derivative UV-B filter compounds making them more effective; effective for longer periods of time.
Abstract: A hair-treating composition containing a diester or polyester of a naphthalene dicarboxylic acid having compound formula (I) or (II), or mixtures; for imparting gloss and/or hair color stabilization:
wherein each R1, same or different, is an alkyl group having 1 to 22 carbon atoms, a diol having the structure HO—R2—OH, or a polyglycol having the structure HO—R3—(—O—R2—)m—OH, wherein R2 and R3, same or different, are each an alkylene group, sight chain or branched, having 1 to 6 carbon atoms, and wherein m and n are each 1 to about 100, or a mixture thereof. These diesters and polyesters of formula (I) or (II) are quite effective in stabilizing the dibenzoylmethane derivative UV-A filter compounds making them more effective, and effective for longer periods of time.
Type:
Grant
Filed:
January 24, 2000
Date of Patent:
September 4, 2001
Assignee:
The C.P. Hall Company
Inventors:
Craig A. Bonda, Peter J. Marinelli, Yin Z. Hessefort, Jagdish Trivedi, Gary Wentworth
Abstract: A hair-treating composition containing a diester or polyester of a naphthalene dicarboxylic acid having compound formula (I) (II) or (III), or mixtures; for imparting gloss and/or hair color stabilization:
wherein each R1, same or different, is an alkyl group having 1 to 22 carbon atoms, a diol having the structure HO—R2—OH, or a polyglycol having the structure HO—R3—(—O—R2—)m—OH, wherein R2 and R3, same or different, are each an allylene group, straight chain or branched, having 1 to 6 carbon atoms, and wherein m and n are each 1 to about 100, or a mixture thereof. These diesters and polyesters of formula (I) or (II) are quite effective in stabilizing the dibenzoylmethane derivative UV-A filter compounds making them more effective, and effective for longer periods of time.
Type:
Grant
Filed:
January 24, 2000
Date of Patent:
January 30, 2001
Assignee:
The C. P. Hall Company
Inventors:
Craig A. Bonda, Peter J. Marinelli, Yin Z. Hessefort, Jagdish Trivedi, Gary Wentworth
Abstract: A hair-treating composition containing a diester or polyester of a naphthalene dicarboxylic acid having compound formula (I) or (II), or mixtures; for imparting gloss and/or hair color stabilization: ##STR1## wherein each R.sup.1, same or different, is an alkyl group having 1 to 22 carbon atoms, a diol having the structure HO--R.sup.2 --OH, or a polyglycol having the structure HO--R.sup.3 --(--O--R.sup.2 --).sub.m --OH, wherein R.sup.2 and R.sup.3, same or different, are each an alkylene group, straight chain or branched, having 1 to 6 carbon atoms, and wherein m and n are each 1 to about 100, or a mixture thereof. These diesters and polyesters of formula (I) or (II) are quite effective in stabilizing the dibenzoylmethane derivative UV-A filter compounds making them more effective, and effective for longer periods of time.
Type:
Grant
Filed:
September 8, 1999
Date of Patent:
October 10, 2000
Assignee:
The C. P. Hall Company
Inventors:
Craig A. Bonda, Peter J. Marinelli, Yin Z. Hessefort, Jagdish Trivedi, Gary Wentworth
Abstract: A sunscreen composition containing a UV-A dibenzoylmethane derivative, such as 4-(1,1-dimethylethyl)-4'-methoxydibenzoylmethane (PARSOL.RTM. 1789), and a stabilizer for the dibenzoylmethane derivative having structure (I): ##STR1## wherein each R', same or different, is an alkyl group, straight or branched chain, having 1 to 22 carbon atoms. These diesters of structure (I) are quite effective in stabilizing the dibenzoylmethane derivative UV-A filter compounds making them more effective, and effective for longer periods of time.
Type:
Grant
Filed:
January 24, 2000
Date of Patent:
October 3, 2000
Assignee:
The C. P. Hall Company
Inventors:
Craig A. Bonda, Peter J. Marinelli, Yin Z. Hessefort, Jagdish Trivedi, Gary Wentworth
Abstract: A cosmetic formulation, particularly a transparent cosmetic formulation, containing a diester or polyester of a naphthalene dicarboxylic acid having formula (I), (II), or (III), or mixtures: ##STR1## wherein each R.sup.1, same or different, is an alkyl group having 1 to 22 carbon atoms, a diol having the structure HO--R.sup.2 --OH, or a polyglycol having the structure HO--R.sup.3 --(--O--R.sup.2 --).sub.m --OH, wherein R.sup.2 and R.sup.3, same or different, are each an alkylene group, straight chain or branched, having 1 to 6 carbon atoms, and wherein m and n are each 1 to about 100, or a mixture thereof.
Type:
Grant
Filed:
November 30, 1999
Date of Patent:
September 5, 2000
Assignee:
The C.P. Hall Company
Inventors:
Craig A. Bonda, Peter J. Marinelli, Yin Z. Hessefort, Jagdish Trivedi, Gary Wentworth
Abstract: A sunscreen composition containing a UV-A dibenzoylmethane derivative, such as 4-(1,1-dimethylethyl)-4'-methoxydibenzoylmethane (PARSOL.RTM. 1789), and a stabilizer for the dibenzoylmethane derivative having formula (I) or (II), or mixtures: ##STR1## wherein each R.sup.1, same or different, is an alkyl group having 1 to 22 carbon atoms, a diol having the structure HO--R.sup.2 --OH, or a polyglycol having the structure HO--R.sup.3 --(--O--R.sup.2 --).sub.m --OH, wherein R.sup.2 and R.sup.3, same or different, are each an alkylene group, straight chain or branched, having 1 to 6 carbon atoms, and wherein m and n are each 1 to about 100, or a mixture thereof. These diesters and polyesters of formula (I) or (II) are quite effective in stabilizing the dibenzoylmethane derivative UV-A filter compounds making them more effective, and effective for longer periods of time.
Type:
Grant
Filed:
March 25, 1999
Date of Patent:
November 30, 1999
Assignee:
The C.P. Hall Company
Inventors:
Craig A. Bonda, Peter J. Marinelli, Yin Z. Hessefort, Jagdish Trivedi, Gary Wentworth
Abstract: A sunscreen composition containing a UV-A dibenzoylmethane derivative, such as 4-(1,1-dimethylethyl)-4'-methoxydibenzoylmethane (PARSOL.RTM. 1789), and a stabilizer/solubilizer for the dibenzoylmethane derivative having formula (I): ##STR1## These long branched chain alkyl salicylates having a C.sub.4 branch at the 2 position are quite effective in stabilizing the dibenzoylmethane derivative UV-B filter compounds making them more effective; effective for longer periods of time.
Abstract: A sunscreen composition containing a UV-A dibenzoylmethane derivative, such as 4-(1,1-dimethylethyl)-4'-methoxydibenzoylmethane (PARSOL.RTM. 1789), and a stabilizer/solubilizer for the dibenzoylmethane derivative having formula (I): ##STR1## wherein m=5, 7, 9 or mixtures andn=4, 6, 8 or mixtures;These long branched chain alkyl salicylates having a C.sub.4.sup.+ branch at the 2 position are quite effective in stabilizing the dibenzoylmethane derivative UV-B filter compounds making them more effective; effective for longer periods of time.
Abstract: A sunscreen composition containing a UV-B dibenzoylmethane derivative, such as 4-(1,1-dimethylethyl)-4'-methoxydibenzoylmethane (PARSOL 1789), and a stabilizer/solubilizer for the dibenzoylmethane derivative selected from formula (I) and formula (II), and mixtures thereof: ##STR1## wherein m=5, 7, 9 or mixtures and n=4, 6, 8 or mixtures; ##STR2## wherein m=5, 7 or mixtures and n=4, 6 or mixtures.These long branched chain alkyl hydroxybenzoates and long branched chain benzoates having a C.sub.4.sup.+ branch at the 2 position are quite effective in stabilizing the dibenzoylmethane derivative UV-B filter compounds making them more effective; effective for longer periods of time.
Abstract: A plasticized polyvinyl chloride (PVC) resin composition and method of plasticizing and decreasing the hydrophobicity of said PVC resin for adherence of aqueous coating compositions, such as water-based inks, by incorporating into the PVC resin a polymeric plasticizer for PVC, a monomeric diacid plasticizer, comprising primarily a C.sub.5, C.sub.4 or C.sub.3 diacid plasticizer, or mixtures, in a ratio of polymeric/monomeric plasticizers of 5/95 to 95/5, preferably 90/10 to 60/40, and at least about 0.1%, based on the weight of the PVC resin, of a metal salt additive, wherein the metal salt is an oxide or a hydroxide and has an oxidation state of plus two, three or four, preferably calcium oxide and/or calcium hydroxide. The monomeric/polymeric plasticizer combination together with the metal salt additive(s) unexpectedly decreases the hydrophobicity of the PVC surface for strong adherence of water-based inks and coatings thereto.
Type:
Grant
Filed:
December 3, 1996
Date of Patent:
July 7, 1998
Assignee:
The C.P. Hall Company
Inventors:
Steven P. Hopper, Kimberly L. Stefanisin, Ronald D. Svoboda
Abstract: The present invention is a composition comprising a linear saturated polyester and from 0.5 to 30 percent by weight of thee polyester of at least one ester of an ethoxylated polyfunctional alcohol having a molecular weight of from 500 to about 1,500. The ester is of an ethoxylated aromatic alcohol and a carboxylic acid wherein the ethoxylated aromatic alcohol has the formulaHO (R O).sub.n --R.sup.1 --(OR).sub.n --OHwherein, R is the same or different hydrocarbon radical of from 2 to 4 carbon atoms, n can be the same or a different integer of from 2 to 15; and R.sup.1 is an aromatic radical preferably derived from an aromatic dialcohol, most preferably bisphenol A. The ethoxylated aromatic alcohol has greater than 20 carbon atoms. The acid is a carboxylic acid of from 1 to 25 and preferably 3 to 10 carbon atoms, and from 1 to 10 carboxyl groups. Preferably the acid has from 3 to 10 carbon atoms and one carboxyl group.
Type:
Grant
Filed:
March 13, 1989
Date of Patent:
July 2, 1991
Assignees:
Allied-Signal Inc., The C.P. Hall Company
Inventors:
John C. Haylock, Harold W. Tuller, Nicholas Vanderkooi, Jr.
Abstract: Waste streams from adipic acid manufacture containing nitric, succinic, glutaric and adipic acids and valuable catalytic metal as salts are treated with alcohols, thereby separating, as esters, succinic and glutaric acids which would contaminate pure adipic acid on recycling, and allowing the re-use of the resulting stream containing nitric acid and metal catalytic salts.
Abstract: Aliphatic alcohols, esters of such alcohols and aliphatic dicarboxylic acids, mixtures of such alcohols and esters and mixtures of such alcohols and esters with aliphatic carboxylic acids are used as additives in the vulcanization of rubbers.
Abstract: Aqueous bleed streams containing soluble aliphatic dicarboxylic acids from the nitric acid oxidation of organic materials and production of dicarboxylic acids, are processed to neutralize or remove nitric acid and also catalysts, if desired, and are then reacted with polyfunctional amines to form polyamides useful in numerous commercial applications.
Abstract: An energy-conserving method for the manufacture of polyaminoamides is described which involves the reaction of a polycarboxylate ester with a mono and/or polyalkylene polyamine in the presence of 0 to about 5% by weight water by heating approximately stoichiometric proportions of the two reactants to the temperature at which the amidification reaction becomes self-sustaining, then utilizing the exothermic heat of reaction to sustain the reaction at a desired temperature. During the reaction, the heat of reaction is used to vaporize an alcohol reaction product and remove the alcohol from the reaction vessel and from further contact with the reaction vessel contents.
Abstract: Aliphatic alcohols, esters of such alcohols and aliphatic dicarboxylic acids, mixtures of such alcohols and esters and mixtures of such alcohols and esters with aliphatic carboxylic acids are used as additives in the vulcanization of rubbers.
Abstract: Diphenyl phthalates are purified by crystallizing them from dipolar-aprotic solvents or solutions of solvents containing such solvents. The phthalate solutions are advantageously, but not necessarily, treated in a carbon column in hydrocarbon solvent without dipolar-aprotic solvents present to remove part of the color and impurities, and then dipolar-aprotic solvents are added to the solution before crystallization to aid in the final removal of color and impurities.