Abstract: A dehydrochlorination process is disclosed. The process involves contacting RfCHClCH2Cl with a chromium oxyfluoride catalyst in a reaction zone to produce a product mixture comprising RfCCl?CH2, wherein Rf is a perfluorinated alkyl group.

Abstract: Environmentally friendly refrigerant blends utilizing blends including 2,3,3,3-tetrafluoropropene (HFO-1234yf) and fluoroethane (HFC-161). The blends have ultra-low GWP, low toxicity, and low flammability with low temperature glide or nearly negligible glide for use in a hybrid, mild hybrid, plug-in hybrid, or full electric vehicles for thermal management (transferring heat from one part of the vehicle to the other) of the passenger compartment providing air conditioning (A/C) or heating to the passenger cabin.

Abstract: The invention provides novel devices to allow for the accelerated evaluation of the impacts of light exposure on the contents of the packaging system. Through this approach and using the methods described herein, it can be determined how the components of a complete package system perform collectively to influence its photoprotective performance enabling a first ever method to quantitate these impacts. The use of this device with the methods described herein will allow for package designs to be optimized for the photoprotection performances, for the impacts of packaging production defects to be explored, and for the influence of packaging form (e.g., surface area to volume ratio) to be determined. Such device capabilities allow a first ever means to provide simulated retail, isothermal light exposures to complete package systems.

Abstract: The present application provides a process of preparing 3,3,3-trifluoroprop-1-ene, comprising reacting 3-chloro-1,1,1-trifluoropropane with a base in an aqueous solvent component in the absence of a phase transfer catalyst.

Abstract: The invention provides novel methods to place a complete package system filled with a sample into a light exposure chamber as a complete unit with periodic monitoring of the contents of the packaging system. Through this approach, it can be determined how the components of a complete package system perform collectively to influence its photoprotective performance enabling a first ever method to quantitate these impacts. In turn this will allow for package designs to be optimized for the photoprotection performances, for the impacts of packaging production defects to be explored, and for the influence of packaging form (e.g., surface area to volume ratio) to be determined. Such capabilities allow a first ever means to optimize package systems for photoprotective performance.

Abstract: Compositions, systems, and methods for introducing lubricants, and additives, that are designed to work with environmentally friendly refrigerants into vehicle heat management systems including passenger compartment air conditioning (A/C) systems are disclosed. Methods for charging lubricants and specific additives using environmentally desirable (low GWP) refrigerant or refrigerant blend compositions into an environmentally friendly system, such as a system that uses HFO-1234yf, are also disclosed.

Abstract: The present invention relates to compositions for use in refrigeration, air-conditioning, and heat pump systems wherein the composition comprises a fluoroolefin and at least one other component. The compositions of the present invention are useful in processes for producing cooling or heat, as heat transfer fluids, foam blowing agents, aerosol propellants, and fire suppression and fire extinguishing agents.

Abstract: The present invention relates to compositions for use in refrigeration, air-conditioning, and heat pump systems wherein the composition comprises a fluoroolefin and at least one other component. The compositions of the present invention are useful in processes for producing cooling or heat, as heat transfer fluids, foam blowing agents, aerosol propellants, and fire suppression and fire extinguishing agents.

Abstract: A method of producing a fluoroolefin includes contacting a compound of formula (1), RfCX1?CHCF3, with a fluorinated ethylene compound of formula (2), CX2X3?CX4X5 in the presence of a catalyst. In the compound of formula (1), Rf is a linear or branched C1-C10 perfluorinated alkyl group and Xi is H, Br, Cl, or F. In the compound of formula (2), X2, X3, X4, and X5 are each independently H, Br, Cl, or F and at least three of X2, X3, X4, and X5 are F. The resulting composition comprises a compound of formula (3), Rf(CF2)nCX6?CH(CF2)mCX7X8CFX9X10. In the compound of formula (3), X6, X7, X8, X9, and X10 are each independently H, Br, Cl, or F, and the total number of each of H, Br, Cl, and F corresponds to the total number of each of H, Br, Cl, and F provided by the compounds of formulae (1) and (2).

Abstract: The present invention is a composition of (a) a coating base selected from a water-dispersed coating, an epoxy polymer coating, an alkyd coating, a Type I urethane coating, or an unsaturated polyester coating; and (b) a fluorinated ester compound having a plurality of fluoroalkyl thioether groups, wherein the number average molecular weight of the fluorinated ester compound is ?30,000 Da; and where the fluorinated group Rf is independently a straight or branched perfluoroalkyl group of 2 to 20 carbon atoms, which is optionally interrupted by one or more CH2, CFH, ether oxygens —O—, or combinations thereof. The fluorinated ester compounds provide cleanability to the resulting coating made from the present composition.

Abstract: Disclosed are compositions comprising HCFC-243db, HCFO-1233xf, HCFC-244db and/or HFO-1234yf and at least one additional compound. For the composition comprising 1234yf, the additional compound is selected from the group consisting of HFO-1234ze, HFO-1243zf, HCFC-243db, HCFC-244db, HFC-245cb, HFC-245fa, HCFO-1233xf, HCFO-1233zd, HCFC-253fb, HCFC-234ab, HCFC-243fa, ethylene, HFC-23, CFC-13, HFC-143a, HFC-152a, HFC-236fa, HCO-1130, HCO-1130a, HFO-1336, HCFC-133a, HCFC-254fb, CHF?CHCl, HFO-1141, HCFO-1242zf, HCFO-1223xd, HCFC-233ab, HCFC-226ba, and HFC-227ca. Compositions comprising HCFC-243db, HCFO-1233xf, and/or HCFC-244db are useful in processes to make HFO-1234yf. Compositions comprising HFO-1234yf are useful, among other uses, as heat transfer compositions for use in refrigeration, air-conditioning and heat pump systems.

Abstract: Compositions, systems and methods for introducing lubricants, and additives, that are designed to work with environmentally friendly refrigerants into vehicle heat management systems including passenger compartment air conditioning (A/C) systems are disclosed. Methods for charging lubricants and specific additives using environmentally desirable (low GWP) refrigerant or refrigerant blend compositions into an environmentally friendly system, such as a system that uses HFO-1234yf, are also disclosed.

Abstract: Provided is a melt molding manufacturing method wherein the mold exhibits excellent molded product releasability over a long period of time, and that can produce a molded product having a matte surface with suppressed surface gloss. The molding manufacturing method for manufacturing the molded product involves forming the melt molded product in a mold having a coating on the surface of the mold, wherein the coating is a layer of fluororesin having dispersed therein oil and filler having an average particle size of 300 nm or less.

Abstract: In accordance with the present invention refrigerant compositions are disclosed. The compositions comprise a refrigerant mixture consisting essentially of HFC-32, HFO-1234yf, and CO2. The compositions are useful in processes to produce cooling and heating, in methods for replacing refrigerant R-32, and in refrigeration, air conditioning or heat pump systems. These inventive compositions are match cooling performance for R-32 with GWP less than 400 or less than 300.

Abstract: A fluoropropene composition comprising Z-1,3,3,3-tetrafluoropropene, E-1,3,3,3-tetrafluoropropene, 1,1,3,3,3-pentafluoropropene, 2,3,3,3-tetrafluoropropene, and optionally 1,1,1,3,3-pentafluoropropane wherein the 2,3,3,3-tetrafluoropropene being present in an amount of 0.00001 to 1.0%. A method of producing the fluoropropene, methods for using the fluoropropene and the composition formed are also disclosed.

Abstract: The present invention relates to a coating composition with 10 to 100% by weight of a non-fluorinated compound mixture, which comprises at least one compound b and at least one compound a, c, or d: a) alkali metal salt of poly(meth)acrylic acid, alkali metal salt of poly(meth)acrylic acid copolymer, ammonium compound or amine salt of poly(meth)acrylic acid, ammonium compound or amine salt of poly(meth)acrylic acid copolymer, or mixtures thereof; b) silicone polyether, alkali metal salt of silicone polyether carboxylate, ammonium compound or amine salt of silicone polyether carboxylate, or mixtures thereof; c) salt of hydrolyzed ?-olefin/maleic anhydride copolymer, salt of esterified ?-olefin/maleic anhydride copolymer, ?-olefin/maleic anhydride copolymer amic acid resin or salt thereof, or mixtures thereof; or d) polycarboxylate calcium sequestrants or mixtures thereof. Such coatings exhibit improved soil and stain cleaning performance.

Abstract: The present application provides compositions comprising 1,2-dichloro-1,2-difluoroethylene (i.e., CFO-1112) and, optionally, an additional component. The present application further provides use of the compositions provided herein in cleaning, solvent, carrier fluid, and deposition applications.

Abstract: A method of synthesizing 2,3,3,3-tetrafluoropropene (1234yf) from 2-chloro-3,3,3-trifluoropropene (1233xf). The 2-chloro-3,3,3-trifluoropropene (1233xf) is reacted in the vapor phase, in the presence of a catalyst, at a temperature and pressure sufficient to selectively convert the 2-chloro-3,3,3-trifluoropropene (1233xf) to 2,3,3,3-tetrafluoropropene (1234yf) without the use of antimony-based catalysts.

Abstract: Compositions, systems and methods for introducing lubricants, and additives, that are designed to work with environmentally friendly refrigerants into vehicle heat management systems including passenger compartment air conditioning (A/C) systems are disclosed. Methods for charging lubricants and specific additives using environmentally desirable (low GWP) refrigerant or refrigerant blend compositions into an environmentally friendly system, such as a system that uses HFO-1234yf, are also disclosed.

Abstract: The present application provides a process of preparing 3,3,3-trifluoroprop-1-ene, comprising reacting 3-chloro-1,1,1-trifluoropropane with a base in an aqueous solvent component in the absence of a phase transfer catalyst.