Patents Assigned to The Dow Chemical
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Publication number: 20150018420Abstract: A method of controlling or adjusting release of an active ingredient from a dosage form comprising the active ingredient and a polysaccharide derivative has been found. The method comprises the steps of a) providing a composition comprising a polysaccharide derivative and a controlled amount of a liquid diluent, based on the dry weight of the polysaccharide derivative, b) subjecting the composition to a dry-grinding operation to provide a dry-ground polysaccharide derivative, and c) incorporating the dry-ground polysaccharide derivative and an active ingredient into a dosage form.Type: ApplicationFiled: September 3, 2014Publication date: January 15, 2015Applicants: Dow Stade Produktions GmbH & Co. OHG, The Dow Chemical CompanyInventors: Yvonne M. Goerlach-Doht, Juergen Hermanns, Nicholas S. Grasman
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Patent number: 8927745Abstract: A process for producing propylene oxide comprising reacting propene with hydrogen peroxide in the presence of a catalyst to give a mixture (G1) comprising propylene oxide, unreacted propene, and oxygen; separating propylene oxide from mixture (G1) to give a mixture (GII) comprising propene and oxygen; and adding hydrogen to mixture (GII) and reducing the oxygen comprised in mixture (GII) at least partially by reaction with hydrogen in the presence of a catalyst comprising copper in elemental and/or oxidic form on a support, wherein copper is present on the support in an amount of 30 to 80 wt.-% based on the whole catalyst and calculated as CuO.Type: GrantFiled: May 5, 2010Date of Patent: January 6, 2015Assignees: BASF SE, The Dow Chemical CompanyInventors: Philip Kampe, Peter Resch, Soo Yin Chin, Peter Bassler, Ulrich Mueller, Goetz-Peter Schindler, Hans-Georg Goebbel, Joaquim Henrique Teles, Kai Gumlich, Thomas Grassler, Christian Bartosch, Richard Jacubinas, Meinolf Weidenbach
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Publication number: 20140326423Abstract: A water-disintegratable non-woven sheet comprising fibers bound by a water-soluble cellulose ether can be produced laying fibers to a base sheet, b) contacting the base sheet with a water-based composition comprising a water-soluble cellulose ether having a viscosity of up 500 mPa·s, measured as a 2 weight percent solution in water at 20° C. using a Haake Viscotester VT550 with a cylinder system, cup MV, at 2.55 s?1, and c) drying the sheet which comprises fibers being bound by the water-soluble cellulose ether.Type: ApplicationFiled: November 20, 2012Publication date: November 6, 2014Applicant: The Dow Chemical CompanyInventors: Hans-Juergen Juhl, Imad Qashou, Anette Wagner
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Publication number: 20140329925Abstract: Embodiments of the invention include a polymer polyol dispersions. The polymer dispersions include a reaction product of a reaction system, where the reaction system includes: at least one polyol, at least one phosphorus based flame retardant having at least one active hydrogen attached to a nitrogen or oxygen atom, at least one of a co-reactant having an equivalent weight of up to 400 and at least one active hydrogen attached to a nitrogen or oxygen atom, at least one catalyst, and at least one polyisocyanate.Type: ApplicationFiled: December 17, 2012Publication date: November 6, 2014Applicants: The Dow Chemical Company, Dow Europe GmbHInventors: Paul A Cookson, Daniel Hoehener, Francois M. Casati
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Publication number: 20140308356Abstract: A granular material which has a mean particle diameter of 150 to 800 micrometers; and an unsettled bulk density of 0.1 to 0.35 g/cm3 and/or a compactibility which results in a compact with a tensile strength of at least 1.7 MPa when the granular material is subjected to a compaction pressure of 266 MPa; and wherein the main component of the granular material is a cellulose derivative or an alkylene oxide homo- or copolymer or a blend thereof is useful for preparing dosage forms with a controlled release profile.Type: ApplicationFiled: June 27, 2014Publication date: October 16, 2014Applicants: THE DOW CHEMICAL COMPANY, DCOMCO, INC.Inventors: Tim D. Cabelka, Akshay Bellare, Ka Chun A. Chan, Tina P. Dasbach, Kacee B. Ender, Karl V. Jacob, Robert E. Scheid, JR.
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Patent number: 8785670Abstract: A continuous process for the production of propylene oxide comprising reacting propene with hydrogen peroxide in methanolic solution in the presence of a titanium silicalite-1 catalyst to obtain propylene oxide, wherein a reaction feed comprising propene, methanol and hydrogen peroxide is introduced into a reactor, said reaction feed containing potassium cations and phosphorus in the form of anions of at least one phosphorus oxyacid.Type: GrantFiled: December 6, 2011Date of Patent: July 22, 2014Assignees: BASF SE, The Dow Chemical CompanyInventors: Joaquim Henrique Teles, Kai Gumlich, Peter Bassler, Christian Bartosch, Philip Kampe, Hans-Georg Goebbel, Ulrich Mueller, Richard Jacubinas
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Publication number: 20140134364Abstract: The instant invention provides a polyethylene blend composition suitable for blown film, method of producing the same, and films made therefrom. The polyethylene blend composition suitable for blown film, according to the present invention, comprises the melt blending product of: (a) from 5 percent or less by weight of a first low density polyethylene (first LDPE) having a density in the range of from 0.915 to 0.935 g/cm3, and a melt index (I2) in the range of from greater than 0.8 to less than or equal to 5 g/10 minutes, and a molecular weight distribution (Mw/Mn) in the range of from 6 to 10; (b) from 5 to 50 percent by weight of a second low density polyethylene (second LDPE) having a density in the range of from 0.915 to 0.935 g/cm3, and a melt index (I2) in the range of from 0.Type: ApplicationFiled: July 2, 2012Publication date: May 15, 2014Applicants: DCOMCO, INC., Dow Global Technologies LLC, The Dow Chemical CompanyInventors: Lawrence J. Effler, Nilesh R. Savargaonkar, Teresa P. Karjala, Cristina Serrat, Jian Wang
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Patent number: 8609879Abstract: A method for separating acetonitrile from water, comprising (i) providing a stream S1 containing at least 95 wt.-%, based on the total weight of S1, acetonitrile and water, wherein the weight ratio of acetonitrile: water is greater than 1; (ii) adding a stream P, comprising at least 95 wt.-% C3, based on the total weight of stream P, to S1 to obtain a mixed stream S2, C3 being propene optionally admixed with propane with a minimum weight ratio of propene: propane of 7:3; (iii) subjecting S2 to a temperature of 92° C. at most and a pressure of at least 10 bar, obtaining a first liquid phase L1 essentially consisting of C3, acetonitrile, and water, and a second liquid phase L2 essentially consisting of water and acetonitrile wherein the weight ratio of acetonitrile: water in L2 is less than 1; (iv) separating L1 from L2.Type: GrantFiled: July 16, 2010Date of Patent: December 17, 2013Assignees: BASF SE, The Dow Chemical CompanyInventors: Joaquim Henrique Teles, Hans-Georg Göbbel, Peter Baβler, Philip Kampe, Kai Gumlich, Christian Bartosch, Ulrich Müller, Richard Jacubinas, Natalia Trukhan, Meinolf Weidenbach, Martin Cogswell
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Publication number: 20130175068Abstract: The disclosure provides a process for producing a material with improved break-down strength. The process includes heating a polymeric composition composed of a low density polyethylene (LDPE) and a minority amount of a high density polyethylene (HDPE). The polymeric composition is heated to at least the melting temperature of the HDPE. The process includes control-cooling the heated polymeric composition at a cooling rate from 0.1° C./min to 20° C./min, and forming a polymeric composition. The control-cooled polymeric composition has a unique morphology which improves breakdown strength. Also provided is a coated conductor with an insulating layer composed of the polymeric composition with the unique morphology. The insulating layer exhibits improved breakdown strength.Type: ApplicationFiled: September 23, 2011Publication date: July 11, 2013Applicants: DOW CHEMICAL COMPANY LTD, GNOSYS UK LTD, GNOSYS GLOBAL LTD, UNIVERSITY OF SOUTHAMPTONInventors: Simon Sutton, Theo E. Geussens, Alun Vaughan, Gary Stevens
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Publication number: 20130144073Abstract: At least one method to efficiently produce alkylene oxide from partial oxidation of hydrocarbons using a high efficiency heterogeneous catalyst in a fixed bed enclosed within a reaction vessel, and a reaction vessel constructed to facilitate the same.Type: ApplicationFiled: March 17, 2011Publication date: June 6, 2013Applicant: THE DOW CHEMICAL INVESTMENTS LLCInventors: Max M. Tirtowidjojo, Subrata Sen, Christina Zarth, Pramod D. Patil
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Publication number: 20120280176Abstract: A composition for removing mercaptan from a gas stream containing at least one acid gas in addition to a mercaptan, the composition comprising a physical and/or chemical solvent for H2S and an inclusion compound for the mercaptan. A process of treating gas stream using the composition. The inclusion compound is selected from the group consisting of, cyclodextrin, cryptand, calixarene, cucurbituril. The chemical solvent may be monoethanolamine (MEA), diethanolamine (DEA), triethanolamine (TEA, diisopropylamine (DIPA), diglycolamine (DGA) and methyldiethanolamine (MDEA). Examples of useful physical solvents include cyclotetramethylene sulfone (sulfolane) and its derivatives, aliphatic acid amides, NMP (n-methylpyrrolidone), N-alkylated pyrrolidones and corresponding piperidone, methanol and mixtures of dialkethers of polyethylene glycols. The method copirses scrubbing preferably the natural gas with an aqueous solution comprising the above compounds followed by a stripping regeneration step.Type: ApplicationFiled: July 13, 2012Publication date: November 8, 2012Applicant: DOW CHEMICAL COMPANYInventor: Stephen A. Bedell
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Patent number: 8197645Abstract: The present invention relates to a process for separating at least one propylene glycol from a mixture (M) comprising water and said propylene glycol, said process comprising (I) evaporating the mixture in at least two evaporation and/or distillation stages at decreasing operating pressures of the evaporators and/or distillation columns obtaining mixture (M?) and mixture (M?); (II) separating the mixture (M?) obtained in (I) in at least one further distillation step, obtaining a mixture (M-I) comprising at least 70 wt.-% of water and a mixture (M-II) comprising less than 30 wt.-% of water.Type: GrantFiled: December 13, 2006Date of Patent: June 12, 2012Assignees: BASF Aktiengesellschaft, The Dow Chemical CompanyInventors: Armin Diefenbacher, Hans-Georg Goebbel, Stefan Bitterlich, Hartwig Voss, Henning Schultz, Anna Forlin, Renate Patrascu
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Publication number: 20120142950Abstract: A continuous process for the production of propylene oxide comprising reacting propene with hydrogen peroxide in methanolic solution in the presence of a titanium silicalite-1 catalyst to obtain propylene oxide, wherein a reaction feed comprising propene, methanol and hydrogen peroxide is introduced into a reactor, said reaction feed containing potassium cations and phosphorus in the form of anions of at least one phosphorus oxyacid.Type: ApplicationFiled: December 6, 2011Publication date: June 7, 2012Applicants: The Dow Chemical Company, BASF SEInventors: Joaquim Henrique TELES, Kai Gumlich, Peter Bassler, Christian Bartosch, Philip Kampe, Hans-Georg Göbbel, Ulrich Müller, Richard Jacubinas
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Patent number: 8187685Abstract: The invention includes a composition comprising from 40 to 98 weight percent of at least one GPPS, from 0 to 98 weight percent of at least one HIPS, from 0.5 to 10 weight percent at least one styrene block copolymer, from 0.5 to 10 weight percent of at least one polypropylene wherein the combination of GPPS, HIPS, polypropylene and styrene block copolymer make up at least about 90 percent of the composition as well as a film made of the composition, an envelope window patch comprising the film, an envelope comprising the window patch, and a process for making the film.Type: GrantFiled: July 23, 2007Date of Patent: May 29, 2012Assignee: Dow Chemical Technologies LLCInventors: Nichole E. Nickel, Eric K. Lee, Stephen J. Skapik, III, Donald J. Gromacki, Robert A. Gunther, James P. Maher
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Publication number: 20120065413Abstract: A process for producing propylene oxide comprising reacting propene with hydrogen peroxide in the presence of a catalyst to give a mixture (G1) comprising propylene oxide, unreacted propene, and oxygen; separating propylene oxide from mixture (G1) to give a mixture (GII) comprising propene and oxygen; and adding hydrogen to mixture (GII) and reducing the oxygen comprised in mixture (GII) at least partially by reaction with hydrogen in the presence of a catalyst comprising copper in elemental and/or oxidic form on a support, wherein copper is present on the support in an amount of 30 to 80 wt.-% based on the whole catalyst and calculated as CuO.Type: ApplicationFiled: May 5, 2010Publication date: March 15, 2012Applicants: The Dow Chemical Company, BASF SEInventors: Philip Kampe, Peter Resch, Soo Yin Chin, Peter Bassler, Ulrich Mueller, Goetz-Peter Schindler, Hans-Georg Goebbel, Joaquim Henrique Teles, Kai Gumlich, Thomas Grassler, Christian Bartosch, Richard Jacubinas, Meinolf Weidenbach
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Patent number: 8134018Abstract: The invention relates to a process for the epoxidation of an olefin comprising (a) reacting the olefin with hydrogen peroxide in the presence of methanol as solvent in at least two reaction stages to obtain a mixture (M-a) comprising olefin oxide, unreacted olefin, methanol and water, wherein between at least two reaction stages, olefin oxide is separated by distillation; (b) separating unreacted olefin from the mixture (M-a) by distillation to obtain a mixture (M-bi) comprising at least 80 wt.-% of olefin and a mixture (M-bii) comprising methanol, water and at least 7 wt.-% of olefin oxide; (c) separating olefin oxide from the mixture (M-bii) in at least one distillation stage to obtain a mixture (M-ci) comprising at least 99 wt.-% of olefin oxide and a mixture (M-cii) comprising water and at least 55 wt.-% of methanol; (d) separating methanol from the mixture (M-cii) in at least one distillation stage to obtain a mixture (M-di) comprising at least 85 wt.-% of methanol and up to 10 wt.Type: GrantFiled: January 9, 2006Date of Patent: March 13, 2012Assignees: BASF SE, The Dow Chemical CompanyInventors: Hans-Georg Goebbel, Henning Schultz, Peter Schultz, Renate Patrascu, Malte Schulz, Meinolf Weidenbach
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Patent number: 7973183Abstract: The present invention relates to a continuous process for the preparation of an olefin oxide wherein an olefin is reacted with a hydroperoxidein the presence of a catalyst, and wherein the reaction which is carried out in at least three reactors operated in parallel is controlled by specifically adjusting the catalyst loads in the reactors.Type: GrantFiled: April 24, 2008Date of Patent: July 5, 2011Assignees: BASF SF, The Dow ChemicalInventors: Hans-Georg Goebbel, Peter Bassler, Joaquim Henrique Teles, Peter Rudolf, Ulrich Mueller, Anna Forlin, Malte Schulz, Meinolf Weidenbach
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Publication number: 20110130579Abstract: A process for the preparation of a catalyst for the use in a hydrocarbon conversion reaction, said catalyst containing a titanium zeolite and carbonaceous material, the catalyst containing said carbonaceous material in an amount of from 0.01 to 0.5% by weight based on the total weight of titanium zeolite contained in the catalyst, the process comprising (i) preparing a catalyst containing the titanium zeolite and (ii) depositing carbonaceous material on the catalyst according to (i) in an amount of from 0.01 to 0.5% by weight based on the total weight of titanium zeolite contained in the catalyst by contacting said catalyst, prior to using the catalyst in said hydrocarbon conversion reaction, with a fluid containing at least one hydrocarbon in an inert atmosphere, to obtain the carbonaceous material containing catalyst, wherein in (ii), the catalyst is not contacted with an oxygen containing gas.Type: ApplicationFiled: November 26, 2010Publication date: June 2, 2011Applicants: BASF SE, The Dow Chemical CompanyInventors: Ulrich MÜLLER, Peter Rudolf, Georg Krug, Rainer Senk
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Publication number: 20110120309Abstract: The present invention relates processes of removal of acidic gases from a gas stream, comprising the steps of a) contacting a wash solution stream with said gas stream containing acidic gases to be removed to allow absorption of the acidic gases into the wash solution stream; b) withdrawing wash solution enriched with acidic gases from said wash solution stream at a first withdrawal level; c) cooling said withdrawn wash solution; and d) reintroducing said cooled wash solution to the wash solution stream at a first reintroduction level to form a mixed wash solution stream, said first reintroduction level being upstream of said first withdrawal level. The present invention also relates to systems for removal of acidic gases from a gas stream.Type: ApplicationFiled: November 24, 2009Publication date: May 26, 2011Applicants: ALSTOM TECHNOLOGY LTD, THE DOW CHEMICAL COMPANYInventors: Barath Baburao, Craig Schubert
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Publication number: 20110065939Abstract: A method for separating acetonitrile from water, comprising (i) providing a stream S1 containing at least 95 wt.-%, based on the total weight of S1, acetonitrile and water, wherein the weight ratio of acetonitrile:water is greater than 1; (ii) adding a stream P, comprising at least 95 wt.-% C3, based on the total weight of stream P, to S1 to obtain a mixed stream S2, C3 being propene optionally admixed with propane with a minimum weight ratio of propene:propane of 7:3; (iii) subjecting S2 to a temperature of 92° C. at most and a pressure of at least 10 bar, obtaining a first liquid phase L1 essentially consisting of C3, acetonitrile, and water, and a second liquid phase L2 essentially consisting of water and acetonitrile wherein the weight ratio of acetonitrile:water in L2 is less than 1; (iv) separating L1 from L2.Type: ApplicationFiled: July 16, 2010Publication date: March 17, 2011Applicants: BASF SE, The Dow Chemical CompanyInventors: Joaquim Henrique Teles, Hans-Georg Göbbel, Peter Baßler, Philip Kampe, Kai Gumlich, Christian Bartosch, Ulrich Müller, Richard Jacubinas, Natalia Trukhan, Meinolf Weidenbach, Martin Cogswell