Abstract: Building blocks are provided for on-chip chemical sensors and other highly-compact photonic integrated circuits combining interband or quantum cascade lasers and detectors with passive waveguides and other components integrated on a III-V or silicon. A MWIR or LWIR laser source is evanescently coupled into a passive extended or resonant-cavity waveguide that provides evanescent coupling to a sample gas (or liquid) for spectroscopic chemical sensing. In the case of an ICL, the uppermost layer of this passive waveguide has a relatively high index of refraction that enables it to form the core of the waveguide, while the ambient air, consisting of the sample gas, functions as the top cladding layer. A fraction of the propagating light beam is absorbed by the sample gas if it contains a chemical species having a fingerprint absorption feature within the spectral linewidth of the laser emission.

Abstract: A method for activating implanted dopants and repairing damage to dopant-implanted GaN to form n-type or p-type GaN. A GaN substrate is implanted with n- or p-type ions and is subjected to a high-temperature anneal to activate the implanted dopants and to produce planar n- or p-type doped areas within the GaN having an activated dopant concentration of about 1018-1022 cm?3. An initial annealing at a temperature at which the GaN is stable at a predetermined process temperature for a predetermined time can be conducted before the high-temperature anneal. A thermally stable cap can be applied to the GaN substrate to suppress nitrogen evolution from the GaN surface during the high-temperature annealing step. The high-temperature annealing can be conducted under N2 pressure to increase the stability of the GaN. The annealing can be conducted using laser annealing or rapid thermal annealing (RTA).

Abstract: A method for growing polycrystalline diamond films having engineered grain growth and microstructure. Grain growth of a polycrystalline diamond film on a substrate is manipulated by growing the diamond on a nanopatterned substrate having features on the order of the initial grain size of the diamond film. By growing the diamond on such nanopatterned substrates, the crystal texture of a polycrystalline diamond film can be engineered to favor the preferred <110> orientation texture, which in turn enhances the thermal conductivity of the diamond film.

Abstract: A laser architecture for selectively producing short high-energy laser pulses having octave-spanning, continuous tunability. Two oppositely chirped pulses are used in combination with a pair of tunable pulse stretcher/compressors to produce a short, high-energy, tunable, broadband pulse.

Abstract: Systems and methods are provided for implementing wideband radiators that conform to regular equilateral triangular lattices with little to no performance compromise for typical offset pairs of dual-polarized element arrangements. This general radiator family/group/configuration can be referred to as the Slant Tri-V (STV) element based on the basic characteristic set of this radiator group and relative differences to conventional array elements normally seen on rectangular or triangular lattice arrangements. The STV array element has wideband, dual-polarized operation and conforms to the most efficiently sampled array lattice for the lowest array element count possible for phased arrays.

Abstract: A substrate for 3D printing using a cold spray technique. The substrate of the present invention has a porous surface with the size of pores smaller than approximately 24.4 times the mean particle size of feedstock powders for cold spray processing and larger than or equal to approximately 6.84 times the mean particle size. Due to no adhesion of a 3D-printed part to the porous regions of the substrate, the parts fabricated by cold spray can be easily removed from the porous substrate without cutting.

Abstract: Methods for obtaining a free-standing thick (>5 ?m) epitaxial material layer or heterostructure stack and for transferring the thick epitaxial layer or stack to an arbitrary substrate. A thick epitaxial layer or heterostructure stack is formed on an engineered substrate, with a sacrificial layer disposed between the epitaxial layer and the engineered substrate. When the sacrificial layer is removed, the epitaxial layer becomes a thick freestanding layer that can be transferred to an arbitrary substrate, with the remaining engineered substrate being reusable for subsequent material layer growth. In an exemplary case, the material layer is a GaN layer and can be selectively bonded to an arbitrary substrate to selectively produce a Ga-polar or an N-polar GaN layer.

Abstract: A phased array antenna that includes a base plate; first and second spaced apart radiating elements formed by at least one conductive layer disposed on at least one dielectric layer that projects from the base plate; and a pillar disposed between the first and second spaced apart radiating elements, wherein the pillar is electrically connected to the base plate, and the first and second spaced apart radiating elements are configured to capacitively couple to the pillar.

Abstract: An apparatus including a uniplanar sonar head. The uniplanar sonar head includes at least one probe element being configured to output cooperatively a unipolar spiral probe signal. The uniplanar sonar head includes at least one reference element being configured to output a circular reference signal. The uniplanar sonar head includes an acoustic receiver comprising an input channel being configured to receive a reflected unipolar spiral probe signal and a reflected circular reference signal. The apparatus includes a plurality of amplifiers communicating with the at least one probe element, the at least one reference element, and the acoustic receiver. The apparatus includes a processor cooperating with the plurality of amplifiers. The apparatus includes a computer-readable medium storing instructions including a target-detection method, which includes determining an angular position of the target based on the plurality of acoustic echoes received via the input channel.

Abstract: A method of removing nuclear isobars from a mass spectrometric technique comprising directing ions, decelerating the ions, neutralizing a first portion of the ions, creating residual ions and a second portion of the ions, reionizing a selective portion of the ions, re-accelerating the selective reionized portion of ions, and directing the reionized portion of ions to a detector. An apparatus to remove nuclear isobars comprising a deceleration lens, an equipotential surface, an electron source to neutralize a portion of the ion beam, a deflector pair, a tunable resonance ionization laser for selective resonant reionization, and an acceleration lens.

Abstract: A composition having a gadolinium-, samarium-, or lanthanum-substituted porous cerium oxide and copper or gold nanoparticles. The composition can be exposed to electromagnetic radiation to form reactive oxygen species in the composition to decompose organophosphonate compounds. The composition may be made by forming a mixture of a cerium salt; a gadolinium, samarium, or lanthanum salt; and an epoxide; forming gel from the mixture; and drying the gel to form an aerogel, a xerogel, or an ambigel. Copper or gold nanoparticles are added or formed at any point in the method.

Abstract: This disclosure concerns a method of making a ligand for Quantum Dot functionalization, a method of making a functionalized Quantum Dot (QD) with a ligand, and a method of making a transparent luminescent quantum dot thiol-yne nanocomposite with tailorable optical, thermal, and mechanical properties. The prepolymer solution and functionalized Quantum Dot can be used in additive manufacturing.

Abstract: Disclosed is a composition having nanoparticles or particles of a refractory metal, a refractory metal hydride, a refractory metal carbide, a refractory metal nitride, or a refractory metal boride, an organic compound consisting of carbon and hydrogen, and a nitrogenous compound consisting of carbon, nitrogen, and hydrogen. The composition, optionally containing the nitrogenous compound, is milled, cured to form a thermoset, compacted into a geometric shape, and heated in a nitrogen atmosphere at a temperature that forms a nanoparticle composition comprising nanoparticles of metal nitride and optionally metal carbide. The nanoparticles have a uniform distribution of the nitride or carbide.

Abstract: An optical apparatus and method of using same. The optical apparatus includes a vortex optical isolator including an axis. The vortex optical isolator includes a first amplitude mask defining a first limiting aperture and aligned with the axis. The first limiting aperture includes a first radius. The vortex optical isolator includes a first lens aligned with the axis. The vortex optical isolator includes a vortex phase mask aligned with the axis. The vortex optical isolator includes a second lens aligned with the axis. The vortex optical isolator includes a second amplitude mask defining a second limiting aperture aligned with the axis. The second limiting aperture includes a second radius sufficiently smaller than the first radius so as to block reverse light traveling through the optical apparatus. The apparatus includes a standard light source configured to transmit forward light through the vortex optical isolator.

Abstract: A method of cleaving includes providing a substrate. Optionally, the substrate includes ?-gallium oxide, hexagonal zinc sulfide, or magnesium selenide. The substrate includes at least one natural cleave plane and a crystallinity. The substrate is cleaved along a first natural cleave plane of the at least one natural cleave plane. The cleaving the substrate along the first natural cleave plane includes the following. A micro-crack is generated in the substrate while maintaining the crystallinity adjacent to the micro-crack by generating a plurality of phonons in the substrate, the micro-crack comprising a micro-crack direction along the first natural cleave plane. The micro-crack is propagated along the first natural cleave plane while maintaining the crystallinity adjacent to the micro-crack. Optionally, generating a micro-crack in the substrate by generating a plurality of phonons in the substrate includes generating the plurality of phonons by electron-hole recombination.

Abstract: Disclosed are methods of making porous zinc electrodes. Taken together, the steps are: forming a mixture of water, a soluble compound that increases the viscosity of the mixture, an insoluble porogen, and metallic zinc powder; placing the mixture in a mold to form a sponge; optionally drying the sponge; placing the sponge in a metal mesh positioned to allow air flow through substantially all the openings in the mesh; heating the sponge in an inert atmosphere at a peak temperature of 200 to 420° C. to fuse the zinc particles to each other to form a sintered sponge; and heating the sintered sponge in an oxygen-containing atmosphere at a peak temperature of 420 to 700° C. to form ZnO on the surfaces of the sintered sponge. The heating steps burn out the porogen.

Abstract: The application of melanin to fabric improves resistance to chemical pass-through, with possible application in protective garments, shelters, and filtration materials.

Abstract: A liquid crystal-based non-mechanical beam steering device that permits steering in the mid-wave infrared and has a chalcogenide waveguide. The waveguide core, the subcladding, or both comprise a chalcogenide glass. The liquid crystal-based non-mechanical beam steering device has a tapered subcladding and a liquid crystal layer.

Abstract: Systems and methods are provided for feature detection such that users can apply advanced machine learning and artificial intelligence (AI) without the need for a deep understanding of existing algorithms and techniques. Embodiments of the present disclosure provide systems and methods than enable easy access to a suite of machine learning algorithms and techniques, an intuitive interface for training an AI to recognize image features based on geometric “correct and refine” recursion, and real-time visualizations of training effectiveness.

Abstract: A process for synthesizing Cu2-xS/PbS core/shell nanocrystals. Pb-oleate is mixed with 1-octadecene and heated to 60° C. Cu2-xS core solution and bis(trimethylsilyl)sulfide stock solution are added and the mixture is stirred at 60° C. for 6 minutes to form the PbS shell around the Cu2-xS nanocrystal cores. The flask is cooled and acetonitrile and toluene is added and the mixture is centrifuged to precipitate and remove the Cu2-xS/PbS core/shell nanocrystals from the reaction mixture. The reaction also produces homogeneously nucleated PbS nanocrystals, which are removed from the Cu2-xS/PbS core/shell reaction mixture via size-selective precipitation. By tailoring the amounts of Pb-oleate and bis(trimethylsilyl)sulfide stock solution in the reaction vessel, while maintaining their molar ratio of 1.5:1 and the number of Cu2-xS cores in the reaction, Cu2-xS/PbS core/shell nanocrystals having a predetermined shell thickness of PbS, and thus a predetermined level of chemical stability, can be obtained.