Abstract: A nonaqueous electrolytic solution including an electrolyte, a nonaqueous solvent, and a compound represented by Formula (1) below. (in Formula (1), X1 and X2 each independently represent C, S, or P; n1 and n2 each independently represent 1 when X1 and X2 represent C or P and 2 when X1 and X2 represent S; n1 represents 1 or 2; n2 represents 1 or 2; Y1 and Y2 each independently represent a hydrocarbon group that may have a substituent or an —OW group (where W represents a hydrocarbon group that may have a substituent); m1 represents 1 or 2, and m2 represents 1 or 2; and Z represents a hydrocarbon group that may have a substituent, an —SiV3 group (where V represents a hydrocarbon group that may have a substituent), an organic onium, or a metal).

Abstract: A nonaqueous electrolyte secondary battery including: a positive electrode; a negative electrode; and a nonaqueous electrolyte solution is provided. The negative electrode contains a graphite and a metal compound-based material containing Si or a Si metal oxide, and the nonaqueous electrolyte solution includes at least one compound of Formula (A) and Formula (B): wherein R1 to R3 each independently represent an alkyl group having 1 to 10 carbon atoms which optionally has a substituent, or an aryl group having 6 to 18 carbon atoms which optionally has a substituent, and X represents hydrogen, an alkenyl group having 2 to 10 carbon atoms or an alkynyl group having 2 to 10 carbon atoms; and R4 to R6 each independently represent a hydrocarbon group having 1 to 20 carbon atoms which optionally has a substituent, Y represents S, NH or NR7, and R7 represents a hydrocarbon group having 1 to 20 carbon atoms.

Abstract: A nonaqueous electrolyte solution including at least an electrolyte, and a nonaqueous solvent, wherein the nonaqueous electrolyte solution contains a compound represented by the following general formula (A): wherein R1 to R3 represent optionally substituted organic groups having 1 to 20 carbon atoms, and a cyclic carbonate compound having a fluorine atom in an amount of 0.01% by mass to 50.

Abstract: A nonaqueous electrolyte solution, which contains a compound represented by the following general formula (A), and (1) at least one compound selected from the group consisting of a nitrile compound, an isocyanate compound, a difluorophosphate, a fluorosulfonate, a lithium bis(fluorosulfonyl)imide and a compound represented by the following general formula (B), or (2) a cyclic carbonate compound having a fluorine atom in an amount of 0.01% by mass to 50.0% by mass based on the total amount of the nonaqueous electrolyte solution. (In formula (A), R1 to R3 may be mutually the same or different and represent optionally substituted organic groups having 1 to 20 carbon atoms.) (In formula (B), R4, R5 and R6 respectively and independently represent an alkyl group, alkenyl group or alkynyl group having 1 to 12 carbon atoms that may be substituted with a halogen atom, and n represents an integer of 0 to 6.

Abstract: The present invention provides a process for producing a compound comprising a perfluorinated alkyl group moiety from a carbonyl compound. Typically, the process includes contacting a carbonyl compound with a silane compound in the presence of a fluorohydrogenate ionic liquid under conditions sufficient to produce a compound comprising a perfluorinated alkyl group. The silane compound includes a perfluoroalkyl group.

Abstract: The invention provides a method for producing fluorotrifluoromethylsulfonyl imide (FTFSI) by reacting non-fluorohalogenated trihalomethylsulfonyl imide (XTXSI) with hydrogen fluoride, where each X is independently a nonfluoro-halide, such as Cl, Br, or I.

Abstract: The invention provides a method for producing hydrogen bis(fluorosulfonyl)imide (HFSI) by reacting hydrogen bis(halosulfonyl)imide (HXSI) with hydrogen fluoride, where each X is independently a nonfluoro-halide, such as Cl, Br, or I.

Abstract: In some embodiments, the invention is a method of removing sulfur from a hydrocarbon feed using the steps of dissolving metallic sodium in a first solvent, combining the sodium/first solvent solution with a sulfur-free alkane or cycloalkane second solvent, vaporizing the first solvent from sodium/first solvent/second solvent combination to transfer the dissolved metallic sodium into the second solvent, and then combine the resultant liquid with a liquid hydrocarbon feed containing an organosulfur species. The resulting stream is combined with a hydrogen donor. The combination is heated and pressurized to form a liquid hydrocarbon product containing sodium sulfide. The liquid hydrocarbon product containing sodium sulfide is then cooled, and the sodium sulfide is extracted. The extracted sodium sulfide is then processed in a sodium sulfur cell to regenerate the sodium and recycle it to the feed.

Abstract: The present invention provides methods for producing bis(fluorosulfonyl) compounds of the formula: F—S(O)2—Z—S(O)2—F??I by contacting a nonfluorohalide compound of the formula: X—S(O)2—Z—S(O)2—X with bismuth trifluoride under conditions sufficient to produce the bis(fluorosulfonyl) compound of Formula I, where Z and X are those defined herein.

Abstract: A method for recovery of fuel-grade ethanol from dilute aqueous ethanol feed in a continuous or batch-wise process includes providing a feed tank containing a dilute aqueous ethanol liquid phase and a vapor phase, removing a portion of the vapor phase from the tank and circulating it through a membrane contactor having an inner lumen and an outer shell, recovering from the membrane contactor a feed phase substantially reduced in ethanol and a solvent phase substantially enriched in ethanol, separating an enriched ethanol phase from the solvent phase, and removing a substantial amount of water from the enriched ethanol phase to produce a fuel-grade ethanol stream. A Venturi nozzle may be used in lieu of the membrane contactor.

Abstract: Provided are a system and method for storing electrical power with an electrochemical device with a ionic liquid electrolyte having a metal coordination cation. More specifically, the device includes a positive electrode; a negative electrode; and an ionic liquid electrolyte statically disposed between the positive electrode and the negative electrode, the ionic liquid electrolyte having a metal coordination cation. The device may be structured and arranged to permit the metal in the electrolyte to undergo redox reactions such that the electrolyte functions at least in part as both an electrolyte and as an electrode. An associated method of use is also provided.

Abstract: Methods for recovery of at least one alcohol from dilute aqueous alcohol feed streams are described. The methods include steps of a) providing a source of a dilute aqueous alcohol feed stream including at least one alcohol; b) substantially removing any solids from the dilute aqueous alcohol feed stream to form a feed stream substantially devoid of solids; c) circulating the feed stream substantially devoid of solids through a liquid-liquid extraction system having multiple equilibrium stages; d) recovering a raffinate phase substantially depleted in the at least one alcohol and an extract phase substantially enriched in the at least one alcohol; e) passing the extract phase to a recovery system wherein the extract phase is subjected to microwave radiation; f) recovering the volatilized product; and g) recycling the solvent to the liquid-liquid extraction system. The microwave radiation substantially heats the alcohol but not the solvent to form a volatilized product of substantially pure alcohol.

Abstract: Methods for extracting an organic solute from a feed source using aromatic extraction solvents are described herein. Solvent modifiers such as, for example, cetyl alcohol may also be used to alter the properties of the solvent and improve the extraction. In some embodiments, the extraction solvent can be recycled after performing the extraction. In some embodiments, the organic solute may be separated from the extraction solvent after the extraction. For example, in some embodiments, the organic solute may be adsorbed on to 5 ? molecular sieve zeolites and then removed thereafter. Removal of the organic solute can take place by heating, applying a vacuum or a combination thereof. Apparatuses for extracting an organic solute from a feed source are also described herein.

Abstract: The present invention is directed to compositions and methods for the recovery of olefins from a mixture. The compositions of the present invention comprise: (1) a transition metal ion; (2) a counter anion; (3) a ligand selected from the group consisting of a bidentate ligand and a tridentate ligand, wherein the ligand comprises at least two nitrogen atoms, and wherein each of the nitrogen atoms comprises a lone pair of electrons; and (4) a polar solvent with a boiling point of at least about 200° C. The methods of the present invention comprise: (1) providing the aforementioned compositions; (2) bonding at least a portion of the olefins in a mixture to the transition metal ion in the composition to form a complex; (3) separating the complex from the mixture; and (4) recovering the olefins from the complex.

Abstract: In some embodiments, the invention is a method of removing sulfur from a hydrocarbon feed using the steps of dissolving metallic sodium in a first solvent, combining the sodium/first solvent solution with a sulfur-free alkane or cycloalkane second solvent, vaporizing the first solvent from sodium/first solvent/second solvent combination to transfer the dissolved metallic sodium into the second solvent, and then combine the resultant liquid with a liquid hydrocarbon feed containing an organosulfur species. The resulting stream is combined with a hydrogen donor. The combination is heated and pressurized to form a liquid hydrocarbon product containing sodium sulfide. The liquid hydrocarbon product containing sodium sulfide is then cooled, and the sodium sulfide is extracted. The extracted sodium sulfide is then processed in a sodium sulfur cell to regenerate the sodium and recycle it to the feed.

Abstract: The present disclosure provides processes for the recovery of olefins from a mixture. Such processes include: (1) passing the mixture to a first surface of a porous membrane, wherein the porous membrane is in a first contactor; (2) passing a complexing composition to a second surface of the porous membrane in the first contactor, wherein the complexing composition includes a metal ion that is capable of reversibly binding the olefins; (3) extracting at least a portion of the olefins from the mixture; wherein extracting includes binding the olefins to the metal ion of the complexing composition; and wherein extracting produces a mixture depleted in olefins and a complexing composition enriched in olefins; and (4) inducing a release of the olefins from the complexing composition enriched in olefins.

Abstract: Methods for recovery of at least one alcohol from dilute aqueous alcohol feed streams are described. The methods include steps of a) providing a source of a dilute aqueous alcohol feed stream including at least one alcohol; b) substantially removing any solids from the dilute aqueous alcohol feed stream to form a feed stream substantially devoid of solids; c) circulating the feed stream substantially devoid of solids through a liquid-liquid extraction system having multiple equilibrium stages; d) recovering a raffinate phase substantially depleted in the at least one alcohol and an extract phase substantially enriched in the at least one alcohol; e) passing the extract phase to a recovery system wherein the extract phase is subjected to microwave radiation; f) recovering the volatilized product; and g) recycling the solvent to the liquid-liquid extraction system. The microwave radiation substantially heats the alcohol but not the solvent to form a volatilized product of substantially pure alcohol.

Abstract: In some embodiments, the invention is a method of removing sulfur from a hydrocarbon feed using the steps of dissolving metallic sodium in a first solvent, combining the sodium/first solvent solution with a sulfur-free alkane or cycloalkane second solvent, vaporizing the first solvent from sodium/first solvent/second solvent combination to transfer the dissolved metallic sodium into the second solvent, and then combine the resultant liquid with a liquid hydrocarbon feed containing an organosulfur species. The resulting stream is combined with a hydrogen donor. The combination is heated and pressurized to form a liquid hydrocarbon product containing sodium sulfide. The liquid hydrocarbon product containing sodium sulfide is then cooled, and the sodium sulfide is extracted.

Abstract: The present invention is a method of removing sulphur from a hydrocarbon feed stream, comprising the steps of: (a) dissolving sodium in a liquid solvent to form a solution containing sodium atoms; (b) combining the liquid solution from step (a) with a liquid hydrocarbon feed containing an organosulfur component to form a combined stream at a temperature of addition and at a pressure near or above the vapor pressure of the solvent at the temperature of addition; (c) reacting the combined stream for sufficient reaction time and at sufficient reaction temperature to form a modified composition comprising one or more sulfur-containing species and less of the organosulfur species than had been present in the hydrocarbon feed; (d) extracting a portion of the sulfur-containing species from the modified composition.

Abstract: The invention is a thin film composite solid (and a means for making such) suitable for use as an electrolyte, having a first layer of a dense, non-porous conductive material; a second layer of a porous ionic conductive material; and a third layer of a dense non-porous conductive material, wherein the second layer has a Coefficient of thermal expansion within 5% of the coefficient of thermal expansion of the first and third layers.