Abstract: The present invention is directed at metal alloys that are capable of forming spinodal glass matrix microconstituent structure. The alloys are iron based and include nickel, boron, silicon and optionally chromium. The alloys exhibit ductility and relatively high tensile strengths and may be in the form of sheet, ribbon, wire, and/or fiber. Applications for such alloys are described.

Abstract: The present disclosure relates to an iron alloy sheet comprising ?-Fe, and/or ?-Fe phases wherein the alloy has a melting point in the range of 800 to 1500° C., a critical cooling rate of less than 105 K/s and structural units in the range of about 150 nm to 1000 nm.

Abstract: An alloy suitable for coating metal surfaces is provided in which the alloy provides a liquid melt which contains a fraction of dissolved oxide forming additives as deoxidizers. The alloyed combination of elements in the liquid melt resists compound formation thus preserving the chemical activity of the individual elements. In a coating application, the alloy may form a coating that can interact with and remove the oxide or residual oxide coating of the base metal to be coated, i.e., scrub the surface of the metal clean. This results in increased coating bond strength and the ability to bond effectively to normally difficult alloys such as stainless steel, refractory metals (W, Ti, Ta etc.), or aluminum alloys which form protective oxide layers.

Abstract: The present disclosure relates to a near metallic glass based alloy wherein the alloy includes at least 40 atomic percent iron, greater than 10 atomic percent of at least one or more metalloids, and less than 50 atomic percent of at least two or more transition metals, wherein one of said transition metals is Mo said alloy exhibits a tensile strength of 2400 MPa or greater and an elongation of greater than 2%.

Abstract: A method of forming an iron based glass forming alloy. The method may include providing a feedstock of an iron based glass forming alloy, melting the feedstock, casting the feedstock into an elongated body in an environment comprising 50% or more of a gas selected from carbon dioxide, carbon monoxide or mixtures thereof.

Abstract: A honeycomb structure and a method of forming an iron based glass forming honeycomb structure. The honeycomb structure may include at least two sheets, each having a thickness in the range of 0.01 mm to 0.15 mm, formed from an iron based glass forming alloy comprising 40 to 68 atomic percent iron, 13 to 17 atomic percent nickel, 2 to 21 atomic percent cobalt, 12 to 19 atomic percent boron, optionally 0.1 to 6 atomic percent carbon, optionally 0.3 to 4 atomic percent silicon, optionally 1 to 20 percent chromium. The sheets may be stacked, bonded together and formed into a honeycomb. The honeycomb structure may include a plurality of cells.

Abstract: Wire for cutting feedstock and a method for cutting feedstock with the wire. The wire may include an iron based alloy comprising at least 35 at % iron, nickel and/or cobalt in the range of about 7 to 50 at %, at least one non-metal or metalloid selected from the group consisting of boron, carbon, silicon, phosphorus, and/or nitrogen present in the range of about 1 to 35 at %, and one metal selected from the group consisting of copper, titanium, molybdenum, aluminum, and/or chromium present in the range of about 0 to 25 at %, wherein the wire has an aspect ratio of greater than one and exhibits metallic and/or crystalline phases of less than 500 nm in size.

Abstract: A drill pipe and a method of applying hardbanding thereto. A hardbanding alloy comprising iron and manganese present in the range of 67 to 87 weight percent (wt. %), niobium and chromium present in the range of 9 to 29 wt. %, and boron, carbon and silicon present in the range of 3 to 6.5 wt. % may be welded around at least a portion of a tool joint circumference. The hardbanding alloy may exhibit a hardness of 45 Rc to 70 Rc and a wear rate in the range of 0.08 grams to 1.60 grams of mass loss after 6,000 cycles as measured using ASTM G65-04, Procedure A.

Abstract: The present invention relates to the addition of niobium to iron based glass forming alloys. More particularly, the present invention is related to changing the nature of crystallization resulting in glass formation that may remain stable at much higher temperatures, increasing the glass forming ability and increasing devitrified hardness of the nanocomposite structure.

Abstract: A method and system of forming a micro-wire including heating metal feedstock to a liquid state within a glass tube, wherein the metal feedstock includes an iron based glass forming alloy comprising one or more of nickel and cobalt present in the range of 7 atomic percent to 50 atomic percent and one or more of boron, carbon, silicon, phosphorous and nitrogen present in the range of 1 to 35 atomic percent. Negative pressure may be provided to the interior the glass tube and the glass tube containing the metal feedstock may be drawn down. The metal feedstock in the glass tube may be cooled at a rate sufficient to form a wire exhibiting crystalline microstructures present in the range of 2 to 90 percent by volume in a glass matrix.

Abstract: A method of applying a metallic alloy overlay including providing an iron based feedstock powder including 10 to 75 weight percent iron and manganese, 10 to 60 weight percent of chromium, 1 to 30 weight percent of an interstitial element selected from boron, carbon, silicon or combinations thereof, 0 to 40 weight percent of a transition metal selected from molybdenum, tungsten or combinations thereof and 1 to 25 weight percent niobium. The method also includes providing an electrode including at least 50 weight percent iron and depositing a weld overlay with the feedstock powder and the electrode to create a metallic alloy exhibiting a grain size in the range of 1,000 ?m or less.

Abstract: The present disclosure relates to a wire and a method of forming a wire including an iron based glass forming alloy including iron present in the range of 43.0 to 68.0 atomic percent, boron present in the range of 12.0 to 19.0 atomic percent, nickel present in the range of 15.0 to 17.0 atomic percent, cobalt present in the range of 2.0 to 21.0 atomic percent, optionally carbon present in the range of 0.1 to 6.0 atomic percent and optionally silicon present in the range of 0.4 to 4.0 atomic percent, wherein said wire has a thickness of 140 ?m or less and wherein said wire includes spinodal glass matrix microconstituents. The wire may be used in abrading a substrate.

Abstract: An aspect of the present disclosure relates to an alloy composition, which may include 52 atomic percent to 68 atomic percent iron, 13 to 21 atomic percent nickel, 2 to 12 atomic percent cobalt, 10 to 19 atomic percent boron, optionally 1 to 5 atomic percent carbon, and optionally 0.3 to 16 atomic percent silicon. The alloy may include 5 to 95% by volume of one or more spinodal microconstituents, wherein the microconstituents exhibit a length scale less than 50 nm in a glass matrix.

Abstract: The present disclosure relates to a glass forming alloy. The glass forming alloy may include 43.0 atomic percent to 68.0 atomic percent iron, 10.0 atomic percent to 19.0 atomic percent boron, 13.0 atomic percent to 17.0 atomic percent nickel, 2.5 atomic percent to 21.0 atomic percent cobalt, optionally 0.1 atomic percent to 6.0 atomic percent carbon, and optionally 0.3 atomic percent to 3.5 atomic percent silicon. Furthermore, the glass forming alloy includes between 5% to 95% by volume one or more spinodal glass matrix microconstituents which include one or more semi-crystalline or crystalline phases at a length scale less than 50 nm in a glass matrix. In addition, the glass forming alloy is capable of blunting shear bands through localized deformation induced changes under tension.

Abstract: The present disclosure relates to an iron based alloy composition that may include iron present in the range of 45 to 70 atomic percent, nickel present in the range of 10 to 30 atomic percent, cobalt present in the range of 0 to 15 atomic percent, boron present in the range of 7 to 25 atomic percent, carbon present in the range of 0 to 6 atomic percent, and silicon present in the range of 0 to 2 atomic percent, wherein the alloy composition exhibits an elastic strain of greater than 0.5% and a tensile strength of greater than 1 GPa.

Abstract: This application deals with glass forming iron based alloys which when produced as a metallic glass or mixed structure comprising metallic glass and nanocrystalline phases, results in extraordinary combinations of strength and ductility. Specifically, high strain up to 97% and high strength up to 5.9 GPa has been measured. Additionally, consistent with the amorphous structure high elasticity up to 2.6% has been observed. Thus, the new alloys developed result in structures and properties which yield high elasticity corresponding to a metallic glass, high plasticity corresponding to a ductile crystalline metal, and high strength as may be observed in nanoscale materials.

Abstract: The present invention relates to the addition of niobium to iron based glass forming alloys and iron based Cr—Mo—W containing glasses. More particularly, the present invention is related to changing the nature of crystallization resulting in glass formation that may remain stable at much higher temperatures, increasing the glass forming ability and increasing devitrified hardness of the nanocomposite structure.

Abstract: A method is provided for forming a metallic overlay having enhanced toughness. The metallic overlay may be a weld, a metallic coating, or similar application. The method includes applying a glass forming metallic alloy to a substrate while the alloy is in a molten or semi-molten state. At the interface of the metallic alloy overlay and the substrate the substrate metal becomes at least partially molten and combines with the alloy to form metallurgical bonds. When the metallic alloy cools it experiences a high relative degree of thermal contraction. The metallurgical bonds between the substrate and the alloy constrain the contraction of the alloy at the interface with the substrate. This results in the inducement of compressive stresses in the metallic alloy overlay. The induced compressive stresses inhibit the formation of cracks in the overlay and/or mitigation of the effects of any cracks in the overlay.

Abstract: The present disclosure relates to a near metallic glass based alloy wherein the alloy includes at least 40 atomic percent iron, greater than 10 atomic percent of at least one or more metalloids, and less than 50 atomic percent of at least two or more transition metals, wherein one of said transition metals is Mo said alloy exhibits a tensile strength of 2400 MPa or greater and an elongation of greater than 2%.

Abstract: The present disclosure relates to a method of spray cladding a wear plate. The method may include melting an alloy including glass forming chemistry, pouring the alloy through a nozzle to form an alloy stream, forming droplets of the alloy stream, and forming a coating of the alloy on a base metal. The base plate may exhibit a first hardness H1 of Rc 55 or less and the alloy coated base plate may exhibit a hardness H2, wherein H2>H1. In addition, the coating may exhibit nanscale or near-nanscale microstructural features in the range of 0.1 nm to 1,000 nm. Furthermore, the alloy coated base plate may exhibit a toughness of greater than 60 ft-lbs.