Patents Assigned to The Nippon Synthetic Chemical Industry Co., Ltd.
  • Publication number: 20120116008
    Abstract: The present invention provides an ink jet recording medium having an ink receiving layer excellent in the coloration resistance and water resistance; and a coating solution for forming an ink receiving layer, which exhibits a large difference in the gelation rate between at ambient temperature and under heating, and is stable at ambient temperature and swiftly gelled when heated. The present invention relates to an ink jet recording medium comprising an ink receiving layer containing an acetoacetic ester group-containing polyvinyl alcohol resin crosslinked by a glyoxylate on a supporting base; and a coating solution for forming an ink receiving layer containing an acetoacetic ester group-containing polymer compound, a glyoxylate and water.
    Type: Application
    Filed: December 24, 2009
    Publication date: May 10, 2012
    Applicant: THE NIPPON SYNTHETIC CHEMICAL INDUSTRY CO., LTD.
    Inventors: Shinichi Tanaka, Hiroyuki Ono
  • Publication number: 20120110683
    Abstract: The present invention provides a non-human animal model of myocardial infarction, which can be created by a less invasive method, shows an extremely low mortality during and after surgical induction of myocardial infarction, ensures the blood reflow after necrosis of cardiac muscles caused by blocking blood flow, and therefore, is usable in topical therapy for myocardial infarction and studies on regenerative medicine. The present invention also provides a method for creating the non-human animal model comprising administering a temporary embolic agent to a branch blood vessel of a heart coronary artery to block blood flow in the branch blood vessel; and after a definite period of time after said vascular branch blockage, administering a temporary embolic agent to the target coronary artery which is intended to induce myocardial infarction to block blood flow in the target coronary artery.
    Type: Application
    Filed: November 3, 2011
    Publication date: May 3, 2012
    Applicant: THE NIPPON SYNTHETIC CHEMICAL INDUSTRY CO., LTD.
    Inventors: Yuzo SHOMURA, Mitsuo SHIBUTANI, Taizo TANIGUCHI, Yasuo HARA
  • Patent number: 8163832
    Abstract: The invention is to provide: an aqueous emulsion which is excellent in emulsion polymerization stability when produced, and is excellent in mechanical stability, freezing stability, stability to long-term standing at high temperatures, water resistance adhesive property, and redispersibility; and a redispersible resin and adhesive where the aqueous emulsion is used. The invention relates to an aqueous emulsion comprising a polyvinyl alcohol-based resin (A) comprising a 1,2-diol component in a side chain and having an average degree of polymerization of 50 to 2,500 and a polymer (B) comprising at least one unsaturated monomer selected from an ethylenically unsaturated monomer and a diene-based monomer.
    Type: Grant
    Filed: April 25, 2006
    Date of Patent: April 24, 2012
    Assignee: The Nippon Synthetic Chemical Industry Co., Ltd.
    Inventors: Mitsuo Shibutani, Masahiro Saito
  • Publication number: 20120052225
    Abstract: Provided is an EVOH resin composition suitable for use as a multilayer structure serving as a material for molded articles, in particular, liquid container such as bags for bag-in-boxes. The EVOH resin composition has such flexibility that even when used in applications where the resin composition is repeatedly folded or deformed over a long period, the resin composition does not develop pinholes or the like, and further has excellent gas barrier properties and melt molding stability.
    Type: Application
    Filed: November 4, 2011
    Publication date: March 1, 2012
    Applicant: THE NIPPON SYNTHETIC CHEMICAL INDUSTRY CO., LTD.
    Inventors: Shouichi KANI, Noriaki KUROKAWA
  • Publication number: 20120041118
    Abstract: The present invention provides a polyvinyl alcohol-based resin (PVOH-based resin) composition having less coloration from melt processing and having high aging stability of the melt viscosity. The present invention relates to a polyvinyl alcohol-based resin composition comprising a polyvinyl alcohol-based rein having a structural unit represented by the following formula (1) and having an absorbance of 0.1 to 0.3 of 280 nm in an ultraviolet absorbance spectrum as a 4 mass % aqueous solution, a carboxylic acid and an alkaline (earth) metal salt, wherein when an aqueous solution of the polyvinyl alcohol-based resin composition is prepared so as to have a content of the polyvinyl alcohol-based resin of 4 mass %, the pH of the aqueous solution at 20° C. is from 5.5 to 7: [wherein R1, R2 and R3 independently represent a hydrogen atom or an organic group, X represents a single bond or a bonding chain, and R4, R5 and R6 independently represent a hydrogen atom or an organic group].
    Type: Application
    Filed: April 27, 2010
    Publication date: February 16, 2012
    Applicant: THE NIPPON SYNTHETIC CHEMICAL INDUSTRY CO., LTD.
    Inventors: Mitsuo Shibutani, Kaoru Inoue, Yuichi Takahashi
  • Publication number: 20120022217
    Abstract: Processes for manufacturing a composition of a solvolysis product of an ethylene-vinyl ester copolymer, which comprises: conducting solvolysis of an ethylene-vinyl ester copolymer (A?) and a modified ethylene-vinyl ester copolymer (B?) comprising a unit derived from a compound represented by the general formula (2) in one system to manufacture the composition of a solvolysis product of an ethylene-vinyl ester copolymer comprising a solvolysis product (A) of the ethylene-vinyl ester copolymer and a solvolysis product (B) of the modified ethylene-vinyl ester copolymer comprising a unit represented by the general formula (1), wherein a ratio of an ethylene content (B?)/(A?) of copolymer (A?) and copolymer (B?) in conducting solvolysis is 1 or more, and a blending ratio (B?)/(A?) of the ethylene-vinyl ester copolymer (A?) and the modified ethylene-vinyl ester copolymer (B?) is from 50/50 to 1/99 by weight:
    Type: Application
    Filed: July 22, 2011
    Publication date: January 26, 2012
    Applicant: THE NIPPON SYNTHETIC CHEMICAL INDUSTRY CO., LTD.
    Inventors: Yasufumi BENIYA, Keisuke FUJIMURA, Akio HARAO
  • Publication number: 20110311865
    Abstract: The present invention provides an ionic liquid useful for a lithium secondary battery, which is excellent in performance as an electrolyte material, such that the liquid has ionic conductance and a wide potential window, and is excellent in safety, as well as an electrolyte using the same. The present invention relates to an ionic liquid including a cyanophosphate-based anion represented by the following general formula (1), and an electrolyte using the same, a lithium secondary battery, and a process for producing the ionic liquid. [Chem 1] ?P(CN)nX6-n??(1) (Wherein X is a halogen atom and n is an integer of 1 to 6.
    Type: Application
    Filed: March 16, 2010
    Publication date: December 22, 2011
    Applicant: THE NIPPON SYNTHETIC CHEMICAL INDUSTRY CO., LTD.
    Inventors: Ryouta Tatsumi, Yasuhiro Aoki, Seiji Maeda, Mariko Hori, Seiichirou Hayakawa
  • Patent number: 8039114
    Abstract: It is disclosed that a resin composition comprising EVOH resin (A), polyamide resin (B) and inorganic salt (C) capable of forming a hydrate wherein the content amount of the inorganic salt (C) is in the range of 2 to 50 parts by mass based on 100 parts by mass of the EVOH resin (A), and the mass ratio ((B)/(C)) of the polyamide resin (B) to the inorganic salt (C) is in the range of 95/5 to 5/95. The resin composition exhibits excellent gas barrier property and less elution of EVOH resin even after hot water treatment, and excellent long-run processability.
    Type: Grant
    Filed: January 7, 2009
    Date of Patent: October 18, 2011
    Assignee: The Nippon Synthetic Chemical Industry Co., Ltd.
    Inventors: Hiroki Masumoto, Kouji Yamada
  • Publication number: 20110237738
    Abstract: A method of producing a vinyl alcohol resin having a water content of not higher than 10 wt % by performing a multistage dewatering process by means of a kneading machine. The method permits efficient dewatering of a highly hydrous vinyl alcohol resin to ensure easy production of a lower water content vinyl alcohol resin having a water content of not higher than 10 wt %, thereby reducing production costs.
    Type: Application
    Filed: April 22, 2011
    Publication date: September 29, 2011
    Applicant: THE NIPPON SYNTHETIC CHEMICAL INDUSTRY CO., LTD.
    Inventors: Keisuke FUJIMURA, Osamu Hommura, Yasufumi Beniya, Satoshi Matsunuma
  • Patent number: 8026302
    Abstract: A PVA resin composition is provided which is excellent in melt-formability and free from emanation of odor in a melt-forming process, and is capable of providing a product free from residual odor, a highly transparent film and a laminate film having higher interlayer adhesive strength. The resin composition comprises: (A) a polyvinyl alcohol resin having a 1,2-diol structural unit represented by the following formula (1): and having a saponification degree of 80 to 97.9 mol %; and (B) an alkylene oxide adduct of a polyvalent alcohol containing 5 to 9 moles of an alkylene oxide per 1 mole of the polyvalent alcohol.
    Type: Grant
    Filed: July 27, 2009
    Date of Patent: September 27, 2011
    Assignee: The Nippon Synthetic Chemical Industry Co., Ltd.
    Inventors: Mitsuo Shibutani, Norihito Sakai
  • Publication number: 20110227248
    Abstract: The present invention provides a polyvinyl alcohol film which has a width of 3 m or more, an in-plane retardation value of 30 nm or less and a fluctuation of in-plane retardation value of 15 nm or less.
    Type: Application
    Filed: May 26, 2011
    Publication date: September 22, 2011
    Applicant: THE NIPPON SYNTHETIC CHEMICAL INDUSTRY CO. LTD
    Inventors: Hideki OONO, Akihiko CHIGAMI, Seiichirou HAYAKAWA
  • Publication number: 20110178222
    Abstract: Provided is a composite of saponified product of an ethylene-vinyl ester-based copolymer from which films excellent in gas barrier properties and film rigidity and highly inhibited from having fish eyes are obtained. It is a process for producing a composite of saponified product of an ethylene-vinyl ester-based copolymer, which comprises: mixing a composition (a) containing a saponified product of ethylene-vinyl ester-based copolymer (A1) and having a moisture content of 50% by weight or higher with a water-swellable layered inorganic compound (B) to obtain a composition (C); and mixing the composition (C) in the state of having a moisture content of 10% by weight or higher and less than 60% by weight with a saponified product of ethylene-vinyl ester-based copolymer (A2).
    Type: Application
    Filed: July 2, 2008
    Publication date: July 21, 2011
    Applicant: THE NIPPON SYNTHETIC CHEMICAL INDUSTRY CO., LTD.,
    Inventor: Shouichi Kani
  • Publication number: 20110166292
    Abstract: The present invention provides a composition of a solvolysis product of an ethylene-vinyl ester copolymer excellent in productivity and formability, which has a small absolute value of melting peak, even in the case where two or more kinds of solvolysis products of ethylene-vinyl ester copolymers are blended.
    Type: Application
    Filed: December 25, 2008
    Publication date: July 7, 2011
    Applicant: THE NIPPON SYNTHETIC CHEMICAL INDUSTRY CO., LTD.
    Inventors: Yasufumi Beniya, Keisuke Fujimura, Akio Harao
  • Publication number: 20110135950
    Abstract: The present invention provides a resin composition which is excellent in gas-barrier properties after a hot-water treatment and excellent in handling properties without increasing viscosity of the resin composition in a melt-kneading step at forming. The invention provides a resin composition containing a thermoplastic resin (A) and a partially dehydrated product or completely dehydrated product (B) of hydrated carboxylic acid salt.
    Type: Application
    Filed: August 7, 2009
    Publication date: June 9, 2011
    Applicant: THE NIPPON SYNTHETIC CHEMICAL INDUSTRY CO., LTD.,
    Inventors: Shinji Okamoto, Hiroki Masumoto, Kouji Yamada, Tomonori Yoshida
  • Patent number: 7928166
    Abstract: There is disclosed a polyvinyl alcohol having a 1,2-glycol bond in a side chain, and a process for preparing the polyvinyl alcolnol wherein there is no generation of dimethyl carbonate hence no need of a process of eliminating dimethyl carbonate in the recovering process of waste liquid after hydrolysis. Also, even when an introduction amount of 1,2-glycol bonds is increased, there is no deterioration of solubility in a hydrolyzing solution (methanol) of a copolymer (paste) before hydrolysis. Further, water-insolubility is not lowered even in experiencing thermal history. Specifically, there is provided a polyvinyl alcohol having a 1,2-glycol bond in a side chain obtained by hydrolyzing a copolymer of a vinyl ester monomer and a compound shown in the formula (1) wherein the hydrolysis degree of the polyvinyl alcohol is at least 60% by mol.
    Type: Grant
    Filed: August 18, 2004
    Date of Patent: April 19, 2011
    Assignee: The Nippon Synthetic Chemical Industry Co., Ltd.
    Inventor: Mitsuo Shibutani
  • Patent number: 7915341
    Abstract: An ethylene-vinyl alcohol copolymer and a molded article thereof are disclosed. The ethylene-vinyl alcohol copolymer has improved stretching properties and provides the molded article with excellent gas barrier properties, appearance and strength. The ethylene-vinyl alcohol copolymer comprises the structural unit of formula (1): (wherein X represents any binding chain excluding an ether bond, each of R1 to R4 represents independently any substituent and n represents 0 or 1.).
    Type: Grant
    Filed: December 17, 2004
    Date of Patent: March 29, 2011
    Assignee: The Nippon Synthetic Chemical Industry Co., Ltd.
    Inventors: Mitsuo Shibutani, Takamasa Moriyama, Kaoru Inoue, Shinta Miyazumi, Ikko Matsui
  • Publication number: 20110020626
    Abstract: The present invention provides a resin composition of a saponified ethylene-vinyl ester copolymer can provide a molded product including layer of the resin composition with less thickness variation and excellent gas-barrier properties, even if the layer is subjected to stretch forming such as deep drawing forming and vacuum-pressure forming where the layer is applied with different tension from side to side thereof in short time. The resin composition comprises an EVOH resin having ethylene content of 20 to 60 mol % and a PVA having 1,2-diol structural unit in a side chain. The present invention also provides a multilayer structure using the resin composition.
    Type: Application
    Filed: April 10, 2009
    Publication date: January 27, 2011
    Applicant: THE NIPPON SYNTHETIC CHEMICAL INDUSTRY CO., LTD.
    Inventors: Shinji Okamoto, Kouji Yamada
  • Publication number: 20100314791
    Abstract: An ethylene-vinyl alcohol copolymer (EVOH) composition preparation process is provided, which comprises the steps of: feeding an EVOH alcohol solution into a tower type apparatus, the EVOH alcohol solution comprising 100 parts by weight of an EVOH and not less than 300 parts by weight of an alcohol having a carbon number of not greater than 4; bringing the EVOH alcohol solution into contact with water, and feeding out a part of the alcohol together with water from the apparatus to provide an EVOH water/alcohol mixture solution comprising 100 parts by weight of the EVOH, 10 to 200 parts by weight of the alcohol and 50 to 200 parts by weight of water; bringing the EVOH water/alcohol mixture solution into contact with water in an agitator container with stirring, and feeding out a part or all of the alcohol together with water from the container to provide an EVOH composition comprising 100 parts by weight of the EVOH, less than 10 parts by weight of the alcohol and 20 to 100 parts by weight of water.
    Type: Application
    Filed: December 22, 2008
    Publication date: December 16, 2010
    Applicant: THE NIPPON SYNTHETIC CHEMICAL INDUSTRY CO., LTD.
    Inventors: Keisuke Fujimura, Yasufumi Beniya, Akio Harao, Yoshiharu Nagao, Shinji Okamoto
  • Patent number: 7838609
    Abstract: A polyvinyl alcohol type resin, which renders possible preparation of a packaging material having high gas barrier property under a high humidity condition even as a monolayer film, is provided. The polyvinyl alcohol (PVA) type resin of the invention has at least a PVA structural unit and also has an alicyclic structural unit in the main chain. A monolayer film containing this PVA type resin and a laminate containing at least one layer comprising this PVA type resin can be used as a packaging material which shows high gas barrier property even under a high humidity condition.
    Type: Grant
    Filed: February 21, 2007
    Date of Patent: November 23, 2010
    Assignee: The Nippon Synthetic Chemical Industry Co., Ltd.
    Inventors: Mark Pucci, Mariko Hori
  • Publication number: 20100261830
    Abstract: This invention provides an aqueous emulsion, which comprises a polyvinyl alcohol-based resin, as the dispersant, and a polymer comprising a structural unit derived from an ethylenically unsaturated monomer, as the dispersoid, from which a film having excellent transparency can be obtained, and which is excellent in mechanical stability, chemical stability, freezing stability and storage stability, and a method for producing the same, and relates to an aqueous emulsion which has an average particle size of the dispersoid of from 100 to 450 ?m and an apparent grafting efficiency of the polyvinyl alcohol-based resin of from 65 to 75% based on the dispersoid, and a method for producing the same.
    Type: Application
    Filed: November 26, 2008
    Publication date: October 14, 2010
    Applicant: THE NIPPON SYNTHETIC CHEMICAL INDUSTRY CO., LTD.
    Inventors: Mitsuo Shibutani, Masahiro Saito, Shusaku Mandai, Takaaki Murahashi