Abstract: There is disclosed a method of producing nano or micro-scale chemical reactor devices and novel devices produced by said method. The method of the invention uses deposited sacrificial layers to provide various channels and reservoirs of reactor devices. Reactor devices of the present invention are chemical reactor devices, electro-chemical reactor devices, or chemical/electro-chemical deivices. A fuel cell embodiment is disclosed.
Type:
Application
Filed:
June 28, 2002
Publication date:
January 16, 2003
Applicant:
THE PENN STATE RESEARCH FOUNDATION, UNIVERSITY PARK, PENNSYLVANIA
Inventors:
Stephen J. Fonash, Wook Jun Nam, Kyuhwan Chang, Henry C. Foley
Abstract: Oily hyperbranched polymers derived from ethylene, propylene, butene and/or a C5-C24 &agr;-olefin, and a method for their synthesis, are disclosed. The polymers have non-regular microstructures and are characterized by a ratio ()of methyl hydrogens centered around 0.85 ppm on the 1H-NMR spectra of the polymers relative to total aliphatic hydrogens of from about 0.40 to about 0.65 for polymers derived from ethylene or butene, and a ratio ()of from greater than 0.50 to about 0.65 for polymers derived from propylene. A method for grafting hyperbranched polymers derived from ethylene, propylene, butene and/or a C5-C24 &agr;-olefin onto aromatic rings in organic molecules and polymers, and the resulting grafted materials, are also disclosed. The hyperbranched polymers and grafted materials are useful, for example, as lubricants and lubricant additives.
Type:
Grant
Filed:
February 3, 1998
Date of Patent:
October 16, 2001
Assignee:
The Penn State Research Foundation University Park PA
Inventors:
Ayusman Sen, Jang Sub Kim, James H. Pawlow, Shahid Murtuza, Smita Kacker, Louis M. Wojcinski, III
Abstract: Impurities dissolved in a solid polymer and/or trapped in the spacial volume of the polymer can be removed quickly and efficiently in one or more relatively short pressurization/depressurization cycles, using a penetrant fluid (e.g. carbon dioxide) having at least some solubility in the polymer. Polymers with inherently slow or delayed elastic recovery at the temperature or temperatures at which the cycle is carried out (e.g. within the range of 20 to 200.degree. C.) or polymers with a high T.sub.g are the ones most efficiently treated. The penetrant is used to expand the polymer matrix, increasing its spacial volume. The pressure is then decreased rapidly, so that the impurities will migrate out of the polymer matrix before the matrix has a chance to relax or return to substantially its original volume. Each complete cycle should last seconds or minutes rather than hours.
Type:
Grant
Filed:
November 7, 1997
Date of Patent:
June 29, 1999
Assignee:
The Penn State Research Foundation University Park