Patents Assigned to The United States of America as represented by the Secretary of the Army
  • Patent number: 11459342
    Abstract: A composition having the structure of formula I: [R—Ar—(COOH)2]x[Ar—(COOH)3]2-xM32+??(I) is provided where M is Mn, Cu, Co, Fe, Zn, Cd, Ni, or Pt; R is a bromine, nitro, a primary amine, C1-C4 alkyl secondary amine, C1-C4 alkyl oxy, Br—(C1-C4 alkyl), NO2—(C1-C4 alkyl), a mercaptan, and reaction products of any of the aforementioned with acyl chlorides of the formulas: CH3(CH2)mC(O)Cl, or CH3(CH(C1-C4 alkyl)CH2)mC(O)Cl, or CH3(CH2)m-Ph-(CH2)pC(O)Cl, where Ph is a C6 phenyl or C6 phenyl with one or more hydrogens replaced with F, C1-C4 fluoroalkyl, or C1-C4 perfluoroalkyl; m is independently in each occurrence an integer of 0 to 12 inclusive; p is an integer of 0 to 36 inclusive, to form an amide, a thioamide, or an ester; Ar is a 1,3,5-modified phenyl, and 1.4>x>0. A process of synthesis thereof and the use to chemically modify a gaseous reactant are also provided.
    Type: Grant
    Filed: December 10, 2019
    Date of Patent: October 4, 2022
    Assignee: The United States of America as Represented by the Secretary of the Army
    Inventors: Gregory W Peterson, Thomas H Epps, III
  • Patent number: 11454859
    Abstract: Time delay devices for producing tunable time delays in optical signals. Cascades of the time delay devices can be used for beam steering in phased-array antennas. The time delay may be produced by selecting a time delay between an input and output of the time delay device from any of the time delay obtained by all four-port switches of the time delay device being in an OFF state and time delays obtainable by switching any one of the four-port switches to an ON state; and producing the selected time delay between the input and output of the time delay device by performing any of avoiding an application of an electrical control signal to any of electro-optic switch elements of the time delay device and applying the electrical control signal to one of the electro-optic switch elements that corresponds to a four-port coupler corresponding to the selected time delay.
    Type: Grant
    Filed: May 5, 2021
    Date of Patent: September 27, 2022
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventors: Sang-Yeon Cho, Weimin Zhou
  • Patent number: 11452967
    Abstract: The present disclosure provides novel metal-organic framework materials (MOFs) useful, for example, for gas adsorption, storage, and/or separation. Also provided are methods of making the MOFs, articles of manufacture incorporating the MOFs and methods for making these, as well as methods of using the MOFs.
    Type: Grant
    Filed: July 17, 2018
    Date of Patent: September 27, 2022
    Assignees: Zymergen Inc., The Regents of the University of Michigan, The United States of America as Represented by the Secretary of the Army
    Inventors: Adam Safir, Adam J. Matzger, Shantel Leithead, Jialiu Ma, Gregory W. Peterson, John McNamara
  • Patent number: 11454737
    Abstract: Disclosed is a method for predicting the future magnetic alignment of a runway. Extrapolating from previous historical records, the future trajectory of the Earth's eccentric geomagnetic axial pole (“ED”) is predicted. With that predicted trajectory as the basis, the future azimuthal change between the location of the ED and the location of an airfield is calculated. At the location of the airfield, a future change in the declination between true north and geomagnetic north is then calculated based on the predicted azimuthal change. The predicted change in declination then becomes the predicted change in magnetic alignment of any runway at the airfield. By predicting future changes in the magnetic alignment of a runway, preparations for changing the name of the runway can be made.
    Type: Grant
    Filed: January 10, 2019
    Date of Patent: September 27, 2022
    Assignee: UNITED STATES OF AMERICA AS REPRESENTED BY THE SECRETARY OF THE ARMY
    Inventors: Theodore A Lee, Mihan McKenna
  • Patent number: 11456485
    Abstract: Disclosed is an electrochemical cell, which may be used for advanced rechargeable batteries. The electrochemical cell comprises two or more electrodes within an electrolyte solution, where the electrolyte solution containing (i) an aliphatic or cyclic sulfone and (ii) a metal perfluoroalkylsulfonylimide salt.
    Type: Grant
    Filed: April 16, 2020
    Date of Patent: September 27, 2022
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventors: Judith A. Kim, Marshall A. Schroeder, Arthur von Wald Cresce, Kang Xu, Lin Ma
  • Patent number: 11456534
    Abstract: A multi-band antenna includes an S-band substrate; an S-band annular ring on the S-band substrate; an X-band substrate in the S-band substrate; and an X-band patch located in a center of the S-band annular ring and on the X-band substrate. The S-band annular ring includes a first upper surface, the X-band patch includes a second upper surface, and the first upper surface is planar with the second upper surface. The multi-band antenna includes a second pair of concentric patch antennas arranged in an annular configuration and stacked on the first pair of antennas. The second pair of antennas are placed on the same substrate and are electromagnetically coupled to the first pair of antennas to provide an extended bandwidth capability.
    Type: Grant
    Filed: June 13, 2019
    Date of Patent: September 27, 2022
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventors: Gregory A. Mitchell, Amir I. Zaghloul
  • Patent number: 11456358
    Abstract: A maskless, patterned graphene film is produced through use of a tunable metal as a catalyst for graphene growth. The metal layer contains precisely defined textures that control the formation of the graphene film. Specifically, graphene growth can be controlled from F-LG (few layer graphene) down to 2-LG (2-layer graphene) and 1-LG (1-layer graphene). More than one texture can be created to form maskless patterns of graphene. Once the graphene layer(s) are grown, the film can be released from the metal and applied to any form and shape of rigid or flexible substrate for a variety of different applications where graphene cannot be normally grown directly.
    Type: Grant
    Filed: January 21, 2020
    Date of Patent: September 27, 2022
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventor: Eugene S. Zakar
  • Patent number: 11444700
    Abstract: A method and apparatus for measuring antenna radiation patterns comprising: an array of test antennas coupled to at least one transmitter; an antenna under test located proximate to the array of test antennas and a compressive sensing processor coupled to the antenna under test and the array of test antennas to control signals emitted and received by the antenna under test and the array of test antennas and processing the signals using compressive sensing.
    Type: Grant
    Filed: October 3, 2019
    Date of Patent: September 13, 2022
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventor: Michael L. Don
  • Patent number: 11433262
    Abstract: A dog respirator including a mask adapted to surround the dog's head and a positive pressure air supply and filter separate from the mask and adapted to be placed on the dog's body away from the dog's head. The air supply and filter may be attached to the dog's back using a harness. The respirator/mask surrounding the dog's head is connected to and receives positive-pressure filtered air from the filtered air supply so that the interior of the mask is maintained at positive pressure relative to atmospheric pressure with filtered air.
    Type: Grant
    Filed: October 29, 2019
    Date of Patent: September 6, 2022
    Assignee: The United States of America as Represented by the Secretary of the Army
    Inventors: Douglas E Wilke, Daniel E Barker
  • Patent number: 11434549
    Abstract: A sintered cemented carbide body including tungsten carbide, and a substantially cobalt-free binder including an iron-based alloy sintered with the tungsten carbide. The iron-based alloy is approximately 2-25% of the overall weight percentage of the sintered tungsten carbide and iron-based alloy. The tungsten carbide may be approximately 90 wt % and the iron-based alloy may be approximately 10 wt % of the overall weight percentage of the sintered tungsten carbide and iron-based alloy. The tungsten carbide may comprise a substantially same size before and after undergoing sintering. The iron-based alloy may be sintered with the tungsten carbide using a uniaxial hot pressing process, a spark plasma sintering process, or a pressureless sintering process. The sintered tungsten carbide and iron-based alloy has a hardness value of at least 15 GPa and a fracture toughness value of at least 11 MPa?m.
    Type: Grant
    Filed: November 9, 2017
    Date of Patent: September 6, 2022
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventors: John J. Pittari, III, Steven M. Kilczewski, Jeffrey J. Swab, Kristopher A. Darling, Billy C. Hornbuckle, Heather A. Murdoch, Robert J. Dowding
  • Patent number: 11421340
    Abstract: In one embodiment employing a vertical draw apparatus, a method of crystallization growth on a substrate surface of a substrate having a substrate material includes: mounting the substrate to a sample holder with the substrate surface facing a liquid surface of a reservoir disposed in a chamber that provides an ambient temperature; seeding the substrate surface with seed droplets; lowering the substrate surface to the liquid surface of the reservoir; independently controlling a temperature of the substrate and a temperature of the reservoir to produce a temperature difference between the substrate and the reservoir over a period of time for crystallization growth; and retracting the substrate surface from the liquid surface of the reservoir at a draw rate. The draw rate and the temperature difference are selected to grow polycrystalline laminate on the substrate surface. Consistent polycrystalline columnar microstructures are formed with appropriate seeding of the substrate surface.
    Type: Grant
    Filed: February 26, 2020
    Date of Patent: August 23, 2022
    Assignee: UNITED STATES OF AMERICA AS REPRESENTED BY THE SECRETARY OF THE ARMY
    Inventors: Emily Asenath-Smith, Garrett R. Hoch, Christopher J Donnelly, Jordan M. Hodge
  • Patent number: 11421972
    Abstract: Apparatus for generating energy and a method of operating the apparatus to generate energy, where the apparatus comprises a coil assembly of a pair of coils circumscribing a magnet assembly that is held in a first position until, upon an acceleration event, the magnet moves from the first position to a second position, which imparts inductive energy into the coils.
    Type: Grant
    Filed: May 22, 2020
    Date of Patent: August 23, 2022
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventors: Ryan R. Knight, Robert H. Wood
  • Publication number: 20220259220
    Abstract: This invention outlines a method for synthesizing a blended resin system in a one pot reaction that may utilize, for example, bio-based anhydrosugars such as isosorbide as a principle component to produce isosorbide dimethacrylate and other monomeric materials for thermosetting applications. This invention establishes a one-pot procedure for reacting a hydroxy group containing compound with methacrylic anhydride in the first step and using the by-product methacrylic acid to react with glycidyl ethers to form additional methacrylate compounds in the second step. This methodology can be formulated to produce a wide array of resin systems that have controlled ratios of hydroxy group containing compound/cross-linker/reactive diluent. Additionally, the novel resin systems may be partially to fully bio-based, promoting global sustainability and reducing costs, and when free radically polymerized have properties that meet or exceed their petroleum derived counterparts.
    Type: Application
    Filed: November 18, 2021
    Publication date: August 18, 2022
    Applicants: DREXEL UNIVERSITY, The Government of the United States of America as Represented by the Secretary of the Army
    Inventors: Joshua Matthew Sadler, John Joseph La Scala, Giuseppe R. Palmese
  • Patent number: 11402188
    Abstract: A two piece aerodynamic pusher consisting of a body and tailpiece. This pusher fits into a standard 40 mm cartridge case by means of three sabots. After the cartridge case is functioned, the combustion gases push the projectile forward and ignite a delay column located in the rear of the pusher. Upon muzzle exit, the sabots discard and the pusher continues down range as the delay column burns. Once the delay has burned, a charge located in the pusher body is ignited, pushing the payload out of the front of the projectile. The cap pops off, and the pellets are dispersed. This effectively moves the payload release point from the muzzle until a designated point down range based on the delay length.
    Type: Grant
    Filed: August 20, 2021
    Date of Patent: August 2, 2022
    Assignee: The United States of America as Represented by the Secretary of the Army
    Inventors: David Chalfant Manley, Sean Mulvihill
  • Patent number: 11402322
    Abstract: Processes, compositions, and sensors for sensing a variety of toxic chemicals based on colorimetric changes. Exemplary process for sensing a toxic chemical includes contacting a toxic chemical, or byproduct thereof, with a sorbent that includes a porous metal hydroxide or a porous mixed-metal oxide/hydroxide and a transition metal reactant suitable to react with a toxic chemical or byproduct thereof. The sorbent is contacted with the toxic chemical or byproduct thereof for a sampling time. A difference between a post-exposure colorimetric state of the sorbent and a pre-exposure colorimetric state of the sorbent is determined to thereby detect exposure to, or the presence of, the toxic chemical or byproduct thereof.
    Type: Grant
    Filed: July 29, 2020
    Date of Patent: August 2, 2022
    Assignee: The United States of America as Represented by the Secretary of the Army
    Inventors: Jennifer R Soliz, Darren K Emge, Ian J Pardoe, Gregory W Peterson
  • Patent number: 11402185
    Abstract: A projectile having a spin stabilized gyroscopically stable flight path due to a base flange. With the base flange, the aerodynamic overturning moment about the center of gravity is reduced to increase the gyroscopic stability factor for stable flight. In one application, a medium-caliber untethered human electro-muscular incapacitation (HEMI) projectile has improved effectiveness due to its stable flight from launch to targets. Other applications for damping resulted in significant improvement in ground dispersion of 40 mm projectiles. The increased stability and increased aerodynamic damping reduce coning motion during flight which ensures that the projectile arrives at the target with greater accuracy, and with its nose oriented for effective incapacitation of the target.
    Type: Grant
    Filed: October 8, 2019
    Date of Patent: August 2, 2022
    Assignee: The United States of America as Represented by the Secretary of the Army
    Inventors: Brian Wong, Marco Duca, Thomas Presutti, Eric Skoglund, Nicholas Grossman, Anthony Farina
  • Patent number: 11394471
    Abstract: A method and apparatus for detecting RF power comprising an input port configured to receive a high-power RF signal, at least one diamond chip attenuator, coupled to the input port, configured to attenuate the high-power RF signal, and an RF detector integrated circuit, coupled to the at least one diamond chip attenuator, configured to convert the attenuated RF signal into an output indicium representing a power level of the high-powered RF signal.
    Type: Grant
    Filed: March 24, 2021
    Date of Patent: July 19, 2022
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventors: Mark A. Govoni, John T. Clark
  • Patent number: 11385169
    Abstract: Processes, compositions, and sensors for sensing a variety of toxic chemicals based on colorimetric changes. Exemplary process for sensing a toxic chemical includes contacting a toxic chemical, or byproduct thereof, with a sorbent that includes a porous metal hydroxide or a porous mixed-metal oxide/hydroxide and a transition metal reactant suitable to react with a toxic chemical or byproduct thereof. The sorbent is contacted with the toxic chemical or byproduct thereof for a sampling time. A difference between a post-exposure colorimetric state of the sorbent and a pre-exposure colorimetric state of the sorbent is determined to thereby detect exposure to, or the presence of, the toxic chemical or byproduct thereof.
    Type: Grant
    Filed: July 30, 2020
    Date of Patent: July 12, 2022
    Assignee: The United States of America as Represented by the Secretary of the Army
    Inventors: Jennifer R Soliz, Darren K Emge, Ian J Pardoe, Gregory W Peterson
  • Patent number: 11386243
    Abstract: A method for screening a large design space of compositions with possible application as binders in cermet and powder metallurgy applications allows rapid elimination of large portions of the design space from contention so that resource intensive procedures, such as computationally intensive modeling techniques and experimental testing, can be focused on potential binder compositions with a high likelihood of being used successfully. The method relies on parameters such as surface tension, contact angle, viscosity, a special capillary metric that is used to characterize capillary behavior, and melting point, which are relatively easy to calculate or determine, to screen out large portions of the design space. Exemplary binder compositions are obtained using the method.
    Type: Grant
    Filed: March 12, 2019
    Date of Patent: July 12, 2022
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventors: Heather A. Murdoch, Kristopher A. Darling
  • Patent number: 11387103
    Abstract: Semiconductor nanofibers are produced at room temperature in a pressure vessel. A semiconductor wafer and metal catalyst are introduced into the pressure vessel. The pressure vessel is filled with a background gas. A nanofiber growth element is introduced into the pressure vessel. For example, the semiconductor may be ablated by a laser. The semiconductor is retained in the pressure vessel for a prolonged period of time until nanofiber growth appears.
    Type: Grant
    Filed: April 30, 2020
    Date of Patent: July 12, 2022
    Assignee: The United States of America as Represented by the Secretary of the Army
    Inventors: Jeffrey Warrender, Quentin Hudspeth