Patents Assigned to The University of Delaware
  • Patent number: 4251287
    Abstract: A solar cell comprising a back electrical contact, amorphous silicon semiconductor base and junction layers and a top electrical contact includes in its manufacture the step of heat treating the physical junction between the base layer and junction layer to diffuse the dopant species at the physical junction into the base layer.
    Type: Grant
    Filed: October 1, 1979
    Date of Patent: February 17, 1981
    Assignee: The University of Delaware
    Inventor: Vikram L. Dalal
  • Patent number: 4251286
    Abstract: Electrical path failures in thin film photovoltaic cells are avoided by disposing at least one blocking layer in the cell to prevent undesired electrical contact which might otherwise occur between the transparent and opaque electrical contacts as well as between one of the contacts and the semiconductor which is remote from it.
    Type: Grant
    Filed: September 18, 1979
    Date of Patent: February 17, 1981
    Assignee: The University of Delaware
    Inventor: Allen M. Barnett
  • Patent number: 4059457
    Abstract: Solutions of chitin in dimethylacetamide, N-methylpyrrolidone or mixtures of these in combination with a minor proportion of lithium chloride.
    Type: Grant
    Filed: September 30, 1976
    Date of Patent: November 22, 1977
    Assignee: The University of Delaware
    Inventor: Paul Rolland Austin
  • Patent number: 4034736
    Abstract: A solar air heater is vertically disposed and composed of a plurality of parallel, horizontally disposed slats resembling a venetian blind. The slats are positioned with their upper faces facing the sun and at an acute angle relative to the horizontal such that the winter sun will produce multiple heat absorbing reflections between adjacent slat surfaces, whereas the summer sun will be reflected back, if desired, so as to impart little or no heat to the heater. Air is circulated through the heater between the slats, thereby becoming heated as it absorbs heat from the slats. This heated air is then sent into a structure, such as a room of a house, via air ducts or the like to heat the structure or is sent to such other areas as desired, the solar air heater being attached to or forming a part of the structure that is to receive the heat produced by its use.
    Type: Grant
    Filed: December 11, 1974
    Date of Patent: July 12, 1977
    Assignee: The University of Delaware
    Inventor: Maria Telkes
  • Patent number: 4031712
    Abstract: A conventional absorption refrigeration system is combined in series with a vapor compression refrigeration system to effect the improvement, which comprises compressing the vapor refrigerant from the evaporator before introducing it into the absorber and/or compressing the vapor refrigerant from the generator before introducing it into the condenser. One bypass permits direct operation as a vapor-compression refrigeration system. Bypasses also permit direct operation as an absorption system.
    Type: Grant
    Filed: December 4, 1975
    Date of Patent: June 28, 1977
    Assignee: The University of Delaware
    Inventor: Frederick Alexander Costello
  • Patent number: 4029727
    Abstract: A new method for producing high-strength films, fibers and other shaped articles from chitin has been discovered, whereby an anhydrous solution of chitin is made into the desired shape, the chitin is insolubilized with an organic non-solvent for the chitin and the resultant shaped article, if desired, is oriented, by cold drawing until its properties, such as tensile strength, are substantially enhanced. The films, fibers, and other shaped articles capable of being oriented or in oriented form, are novel and useful in such applications as food wrap and surgical sutures.
    Type: Grant
    Filed: April 16, 1975
    Date of Patent: June 14, 1977
    Assignee: The University of Delaware
    Inventors: Paul Roland Austin, Charles James Brine
  • Patent number: 4010620
    Abstract: A cooling system for air conditioning of buildings which comprises creating a cold medium by dissolving a salt in water, said salt being characterized by forming an endothermic solution, passing air through or over said cold solution to cool the air before introduction into said building, after the potential cooling effect is exhausted the salt is recovered by evaporation of the water from the solution with hot air, said hot air being at least partly heated by solar energy.
    Type: Grant
    Filed: October 8, 1975
    Date of Patent: March 8, 1977
    Assignee: The University of Delaware
    Inventor: Maria Telkes
  • Patent number: 3988358
    Abstract: Carboxylic acid esters or amides are obtained from aryl, heterocyclic, vinylic, ethynylic, and benzylic halides and substituted derivates thereof, by reacting same with an alcohol or primary or secondary amine and carbon monoxide, in the presence of a palladium catalyst and if necessary a tertiary amine at about 20.degree.-150.degree. C and from about a half to about 100 atmospheres pressure. A typical example is the conversion of bromobenzene into n-butyl benzoate at 100.degree. C and one atmosphere of carbon monoxide in the presence of tri-n-butyl-amine and a catalytic amount of PdBr.sub.2 [P(C.sub.6 H.sub.5).sub.3 ].sub.2.
    Type: Grant
    Filed: May 10, 1974
    Date of Patent: October 26, 1976
    Assignee: The University of Delaware
    Inventor: Richard F. Heck
  • Patent number: 3987802
    Abstract: Chitin, either as such or in toasted form, has been found to be an effective extender and filter for tobacco. It can be used in substantial amounts with tobacco blends without adversely affecting such physical properties as packing ability, burning rate or retention of ash. Organoleptic properties such as aroma, taste and smoothness are little affected. To the degree that chitin is used in the mixture, nicotine and noxious tars are reduced. Mixtures of chitin and tobacco represent new compositions.
    Type: Grant
    Filed: March 5, 1975
    Date of Patent: October 26, 1976
    Assignee: The University of Delaware
    Inventor: Paul Rolland Austin
  • Patent number: 3987147
    Abstract: A continuous cyclic process for removing sulfur dioxide from gases produced in the combustion of fossil fuels or in chemical and metallurgical operations by means of an aqueous solution including the carbonate of an alkali metal to absorb said oxide out of said gases whereby the metal carbonate is converted into the metal sulfite. A two step recovery process is employed to reproduce the aqueous carbonate solution for reuse in the absorption step and to produce hydrogen sulfide which may be converted into elemental sulfur by well known means, if desired.
    Type: Grant
    Filed: February 21, 1974
    Date of Patent: October 19, 1976
    Assignee: The University of Delaware
    Inventor: Salvatore A. Guerrieri
  • Patent number: 3986969
    Abstract: A mixture for the storage of heat energy utilizing a heat of fusion material includes sodium sulfate decahydrate, borax as a nucleating agent, and hydrous magnesium aluminum silicate (attapulgus clay) as a homogenizing agent. This composition maintains the salt-hydrate in suspension during repeated heating and cooling cycles.A method is also disclosed for preparing the mixture which includes the steps of mixing water with the attapulgus clay, adding a nucleating agent to the initial mixture, and mixing the initial mixture, including the nucleating agent, with a heat of fusion material such as sodium sulfate decahydrate.
    Type: Grant
    Filed: February 6, 1975
    Date of Patent: October 19, 1976
    Assignee: The University of Delaware
    Inventor: Maria Telkes
  • Patent number: 3960932
    Abstract: Aldehydes are obtained from aryl, vinylic and heterocyclic halides and substituted derivatives thereof, a tertiary amine, carbon monoxide and hydrogen at from about 50.degree.-175.degree.C under from about one to 200 atmospheres pressure and with PdX.sub.2 [P(C.sub.6 H.sub.5).sub.3 ].sub.1 or 2 as a catalyst where X is acetate or a halogen. The ratios of carbon monoxide to hydrogen are not critical but the most favorable reactions are usually obtained with ratio from about 0.1 to about 10. A typical example is the conversion of p-bromoanisole to anisaldehyde in 84% yield at 150.degree.C in 18 hrs. at 1000 psig. of 1:1 CO to H.sub.2 with one mole percent of PdBr.sub.2 [P(C.sub.6 H.sub.5).sub.3 ].sub.2 as catalyst and with tri-n-butylamine as the tertiary amine.
    Type: Grant
    Filed: October 10, 1974
    Date of Patent: June 1, 1976
    Assignee: The University of Delaware
    Inventor: Richard F. Heck
  • Patent number: 3951942
    Abstract: Azo compounds especially useful for dyeing polyamide fibers on which the compounds exhibit improved fastness and dyeability properties contain a phenyl diazo component having a substituent in the 4-position and hydrogen, chlorine or bromine in the 2-position, and a tetramethyl substituted tetrahydroquinoline coupling component.
    Type: Grant
    Filed: February 21, 1974
    Date of Patent: April 20, 1976
    Assignee: The University of Delaware
    Inventors: Max A. Weaver, James M. Straley, Clarence A. Coates, Jr.
  • Patent number: 3938536
    Abstract: 1. The reduction of turbulent drag of fluids flowing through conduits such as pipelines, channels, troughs and streams, or of drag on an object which is moving relative to a fluid, which comprises adding to said fluid a mixture of soluble polymeric substances and of suspended fibers.2. Process fluids, consisting of the above-mentioned mixtures of dissolved polymers and suspended fibers, which exhibit decreased pressure losses under conditions of turbulent flow as compared to the carrier liquid but which exhibit heat or mass transfer rates which are of the same magnitude as those of the unmodified carrier liquid. That is, process fluids for which the heat transfer rate per unit of pumping power required is greater than that exhibited by the carrier fluid.
    Type: Grant
    Filed: October 11, 1974
    Date of Patent: February 17, 1976
    Assignee: The University of Delaware
    Inventors: Arthur B. Metzner, Raymond C. Vaseleski, Wei-Kuo Lee
  • Patent number: 3932586
    Abstract: A continuous cyclic process and apparatus for removing sulfur dioxide (and if present, sulfur trioxide) from gases produced in the combustion of fossil fuels or in chemical and metallurgical processes by means of an aqueous absorption solution including potassium carbonate to absorb said oxides out of said gases whereby potassium carbonate is converted into potassium sulfite (sulfate). A two component, two stage molten process is employed to recover potassium carbonate for reuse in the absorption step and to liberate hydrogen sulfide which may be converted to elemental sulfur by well known methods.
    Type: Grant
    Filed: October 12, 1973
    Date of Patent: January 13, 1976
    Assignee: The University of Delaware
    Inventor: Salvatore A. Guerrieri